Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid: Difference between revisions

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DOI 10.1021/jacs.0c03097
Authors Kenji Kamada, Jieun Jung, Taku Wakabayashi, Keita Sekizawa, Shunsuke Sato, Takeshi Morikawa, Shunichi Fukuzumi, Susumu Saito,
Submitted 27.05.2020
Published online 26.05.2020
Licenses https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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{{#doiinfobox: 10.1021/jacs.0c03097}}
{{#doiinfobox: 10.1021/jacs.0c03097}}
[[Category:Photocatalytic CO2 conversion to HCOOH]]
[[Category:Photocatalytic CO2 conversion to HCOOH]]
{{BaseTemplate}}
{{BaseTemplate}}{{MissingInvestigation}}
 
==== Investigation ====
 
==== Catalyst ====
<chemform smiles="C(C1C(C)=CC(C)=CC=1C)1C=C2CP([Ir+3]([H-])([Cl-])34P(C5CCCCC5)(C5CCCCC5)CC5C=C(C6C(C)=CC(C)=CC=6C)C=C(C(C=1)=N23)N=54)(C1CCCCC1)C1CCCCC1.[B-](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1" inchi="1S/C54H74N2P2.C24H20B.ClH.Ir.H/c1-37-27-39(3)53(40(4)28-37)43-31-45(35-57(47-19-11-7-12-20-47)48-21-13-8-14-22-48)55-51(33-43)52-34-44(54-41(5)29-38(2)30-42(54)6)32-46(56-52)36-58(49-23-15-9-16-24-49)50-25-17-10-18-26-50;1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;;/h27-34,47-50H,7-26,35-36H2,1-6H3;1-20H;1H;;/q;-1;;+3;-1/p-1" inchikey="BEUJVGCRFICSDD-UHFFFAOYSA-M" height="200px" width="300px" float="none">
  -INDIGO-05172314302D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 86 99 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 3.76897 -3.39299 0.0 0
M  V30 2 C 5.44044 -3.84035 0.0 0
M  V30 3 C 4.73567 -3.13426 0.0 0
M  V30 4 N 5.18138 -4.80719 0.0 0
M  V30 5 C 3.50888 -4.36369 0.0 0
M  V30 6 C 4.22012 -5.06674 0.0 0
M  V30 7 C 6.83474 -3.84129 0.0 0
M  V30 8 C 8.50596 -3.39299 0.0 0
M  V30 9 C 7.54256 -3.13388 0.0 0
M  V30 10 C 8.76503 -4.35982 0.0 0
M  V30 11 N 7.09484 -4.81199 0.0 0
M  V30 12 C 8.06232 -5.06523 0.0 0
M  V30 13 C 3.9613 -6.03267 0.0 0
M  V30 14 P 4.66841 -6.73977 0.0 0
M  V30 15 C 8.32114 -6.03116 0.0 0
M  V30 16 P 7.61404 -6.73827 0.0 0
M  V30 17 C 8.61404 -6.73827 0.0 0
M  V30 18 C 9.11405 -7.6043 0.0 0
M  V30 19 C 10.114 -7.6043 0.0 0
M  V30 20 C 10.614 -6.73827 0.0 0
M  V30 21 C 10.114 -5.87223 0.0 0
M  V30 22 C 9.11401 -5.87223 0.0 0
M  V30 23 C 7.87286 -7.70419 0.0 0
M  V30 24 C 7.16575 -8.41132 0.0 0
M  V30 25 C 7.42456 -9.37724 0.0 0
M  V30 26 C 8.39049 -9.63603 0.0 0
M  V30 27 C 9.0976 -8.9289 0.0 0
M  V30 28 C 8.83878 -7.96299 0.0 0
M  V30 29 C 3.06187 -2.68588 0.0 0
M  V30 30 C 1.3901 -2.23963 0.0 0
M  V30 31 C 2.09535 -2.94525 0.0 0
M  V30 32 C 1.64851 -1.27262 0.0 0
M  V30 33 C 3.32132 -1.715 0.0 0
M  V30 34 C 2.6096 -1.01243 0.0 0
M  V30 35 C 9.21307 -2.68588 0.0 0
M  V30 36 C 9.65931 -1.01411 0.0 0
M  V30 37 C 8.9537 -1.71936 0.0 0
M  V30 38 C 10.6263 -1.27253 0.0 0
M  V30 39 C 10.1839 -2.94533 0.0 0
M  V30 40 C 10.8865 -2.23361 0.0 0
M  V30 41 C 4.28631 -1.45274 0.0 0
M  V30 42 C 1.83659 -3.91119 0.0 0
M  V30 43 C 0.940254 -0.566672 0.0 0
M  V30 44 C 10.4462 -3.91033 0.0 0
M  V30 45 C 11.3323 -0.564267 0.0 0
M  V30 46 C 7.98775 -1.4606 0.0 0
M  V30 47 C 3.66841 -6.73977 0.0 0
M  V30 48 C 3.16839 -5.87374 0.0 0
M  V30 49 C 2.1684 -5.87374 0.0 0
M  V30 50 C 1.66842 -6.73977 0.0 0
M  V30 51 C 2.16844 -7.60581 0.0 0
M  V30 52 C 3.16843 -7.60581 0.0 0
M  V30 53 C 4.40959 -7.7057 0.0 0
M  V30 54 C 3.44365 -7.96453 0.0 0
M  V30 55 C 3.18483 -8.93045 0.0 0
M  V30 56 C 3.89195 -9.63754 0.0 0
M  V30 57 C 4.85789 -9.3787 0.0 0
M  V30 58 C 5.11671 -8.41278 0.0 0
M  V30 59 Ir 6.15 -5.875 0.0 0 CHG=3
M  V30 60 Cl 6.15 -6.875 0.0 0 CHG=-1
M  V30 61 H 6.15 -4.875 0.0 0 CHG=-1
M  V30 62 B 15.9 -5.15 0.0 0 CHG=-1
M  V30 63 C 15.9 -6.15 0.0 0
M  V30 64 C 16.7666 -7.64766 0.0 0
M  V30 65 C 16.7668 -6.65003 0.0 0
M  V30 66 C 15.9001 -8.14871 0.0 0
M  V30 67 C 15.03 -6.65306 0.0 0
M  V30 68 C 15.0365 -7.65311 0.0 0
M  V30 69 C 14.9 -5.15 0.0 0
M  V30 70 C 13.4023 -6.01658 0.0 0
M  V30 71 C 14.4 -6.01684 0.0 0
M  V30 72 C 12.9013 -5.15007 0.0 0
M  V30 73 C 14.3969 -4.28003 0.0 0
M  V30 74 C 13.3969 -4.28649 0.0 0
M  V30 75 C 15.9 -4.15 0.0 0
M  V30 76 C 15.0334 -2.65234 0.0 0
M  V30 77 C 15.0332 -3.64997 0.0 0
M  V30 78 C 15.8999 -2.15129 0.0 0
M  V30 79 C 16.77 -3.64694 0.0 0
M  V30 80 C 16.7635 -2.64689 0.0 0
M  V30 81 C 16.9 -5.15 0.0 0
M  V30 82 C 18.3977 -4.28342 0.0 0
M  V30 83 C 17.4 -4.28316 0.0 0
M  V30 84 C 18.8987 -5.14993 0.0 0
M  V30 85 C 17.4031 -6.01997 0.0 0
M  V30 86 C 18.4031 -6.01351 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 1 2 7
M  V30 14 1 6 13
M  V30 15 1 13 14
M  V30 16 1 12 15
M  V30 17 1 15 16
M  V30 18 1 16 17
M  V30 19 1 17 22
M  V30 20 1 17 18
M  V30 21 1 18 19
M  V30 22 1 19 20
M  V30 23 1 20 21
M  V30 24 1 21 22
M  V30 25 1 16 23
M  V30 26 1 23 28
M  V30 27 1 23 24
M  V30 28 1 24 25
M  V30 29 1 25 26
M  V30 30 1 26 27
M  V30 31 1 27 28
M  V30 32 1 1 29
M  V30 33 2 31 29
M  V30 34 2 32 30
M  V30 35 1 29 33
M  V30 36 1 30 31
M  V30 37 2 33 34
M  V30 38 1 34 32
M  V30 39 1 8 35
M  V30 40 2 37 35
M  V30 41 2 38 36
M  V30 42 1 35 39
M  V30 43 1 36 37
M  V30 44 2 39 40
M  V30 45 1 40 38
M  V30 46 1 33 41
M  V30 47 1 31 42
M  V30 48 1 32 43
M  V30 49 1 39 44
M  V30 50 1 38 45
M  V30 51 1 37 46
M  V30 52 1 14 47
M  V30 53 1 47 52
M  V30 54 1 47 48
M  V30 55 1 48 49
M  V30 56 1 49 50
M  V30 57 1 50 51
M  V30 58 1 51 52
M  V30 59 1 14 53
M  V30 60 1 53 58
M  V30 61 1 53 54
M  V30 62 1 54 55
M  V30 63 1 55 56
M  V30 64 1 56 57
M  V30 65 1 57 58
M  V30 66 10 4 59
M  V30 67 10 11 59
M  V30 68 10 16 59
M  V30 69 10 14 59
M  V30 70 10 59 60
M  V30 71 10 59 61
M  V30 72 1 62 63
M  V30 73 2 65 63
M  V30 74 2 66 64
M  V30 75 1 63 67
M  V30 76 1 64 65
M  V30 77 2 67 68
M  V30 78 1 68 66
M  V30 79 1 62 69
M  V30 80 2 71 69
M  V30 81 2 72 70
M  V30 82 1 69 73
M  V30 83 1 70 71
M  V30 84 2 73 74
M  V30 85 1 74 72
M  V30 86 1 62 75
M  V30 87 2 77 75
M  V30 88 2 78 76
M  V30 89 1 75 79
M  V30 90 1 76 77
M  V30 91 2 79 80
M  V30 92 1 80 78
M  V30 93 1 62 81
M  V30 94 2 83 81
M  V30 95 2 84 82
M  V30 96 1 81 85
M  V30 97 1 82 83
M  V30 98 2 85 86
M  V30 99 1 86 84
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>
 
==== Photosensitizer ====
 
==== Sacrificial electron donor ====

Revision as of 13:32, 17 May 2023


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This page about a publication or dataset does not currently include an investigation. Please add any experiments detailed in the publication or performed to obtain this dataset.

Investigation

Catalyst

[Ir(mesbpy-(PCy2)2)][BPh4]

Photosensitizer

Sacrificial electron donor

Investigations