Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions

Revision as of 13:18, 17 May 2023

Missing investigation

This page about a publication or dataset does not currently include an investigation. Please add any experiments detailed in the publication or performed to obtain this dataset.

Investigation

Catalyst

[Fe(pabop)Cl2][CLO4]

Photosensitizer

Sacrificial electron donor

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/jacs.5b06535
Authors	Lingjing Chen, Zhenguo Guo, Xi-Guang Wei, Charlotte Gallenkamp, Julien Bonin, Elodie Anxolabéhère-Mallart, Kai-Chung Lau, Tai-Chu Lau, Marc Robert,
Submitted	12.08.2015
Published online	19.08.2015
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page

@@ Line 1: / Line 1: @@
 {{#doiinfobox: 10.1021/jacs.5b06535}}
 [[Category:Photocatalytic CO2 conversion to HCOOH]]
-{{BaseTemplate}}
+{{BaseTemplate}}{{MissingInvestigation}}
+==== Investigation ====
+==== Catalyst ====
+<chemform smiles="C1C2C(C)=N3[Fe+3]([Cl-])([Cl-])456N(CCN4CCN5CC3)=C(C)C(N=26)=CC=1.Cl([O-])(=O)(=O)=O" inchi="1S/C15H23N5.ClHO4.2ClH.Fe/c1-12-14-4-3-5-15(20-14)13(2)19-11-9-17-7-6-16-8-10-18-12;2-1(3,4)5;;;/h3-5,16-17H,6-11H2,1-2H3;(H,2,3,4,5);2*1H;/q;;;;+3/p-3/b18-12+,19-13+;;;;" inchikey="XTLBRFNUSVMBAM-DQIPMIPLSA-K" height="200px" width="300px" float="none">
+  -INDIGO-05172314152D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 28 32 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 7.50985 -3.90007 0.0 0
+M  V30 2 C 9.24015 -3.89959 0.0 0
+M  V30 3 C 8.37664 -3.39997 0.0 0
+M  V30 4 C 9.24015 -4.90053 0.0 0
+M  V30 5 C 7.50985 -4.90502 0.0 0
+M  V30 6 N 8.37882 -5.40003 0.0 0
+M  V30 7 C 6.64382 -5.40502 0.0 0
+M  V30 8 N 6.64382 -6.40502 0.0 0
+M  V30 9 C 5.7778 -4.90502 0.0 0
+M  V30 10 C 10.1062 -5.40053 0.0 0
+M  V30 11 N 10.1062 -6.40053 0.0 0
+M  V30 12 C 10.9722 -4.90053 0.0 0
+M  V30 13 N 7.375 -7.625 0.0 0
+M  V30 14 N 9.275 -7.6 0.0 0
+M  V30 15 C 6.1028 -7.18002 0.0 0
+M  V30 16 C 6.45907 -7.70882 0.0 0
+M  V30 17 C 7.875 -8.49102 0.0 0
+M  V30 18 C 8.775 -8.46603 0.0 0
+M  V30 19 C 10.2409 -7.70882 0.0 0
+M  V30 20 C 10.5312 -7.21656 0.0 0
+M  V30 21 Fe 8.35 -6.5 0.0 0 CHG=3
+M  V30 22 Cl 7.64289 -5.79289 0.0 0 CHG=-1
+M  V30 23 Cl 9.05711 -5.79289 0.0 0 CHG=-1
+M  V30 24 Cl 12.6 -2.85 0.0 0
+M  V30 25 O 12.6 -3.85 0.0 0
+M  V30 26 O 13.6 -2.85 0.0 0
+M  V30 27 O 11.6 -2.85 0.0 0
+M  V30 28 O 12.6 -1.85 0.0 0 CHG=-1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 5 7
+M  V30 8 2 7 8
+M  V30 9 1 7 9
+M  V30 10 1 4 10
+M  V30 11 2 10 11
+M  V30 12 1 10 12
+M  V30 13 1 8 15
+M  V30 14 1 13 16
+M  V30 15 1 16 15
+M  V30 16 1 13 17
+M  V30 17 1 14 18
+M  V30 18 1 17 18
+M  V30 19 1 14 19
+M  V30 20 1 11 20
+M  V30 21 1 20 19
+M  V30 22 10 6 21
+M  V30 23 10 13 21
+M  V30 24 10 14 21
+M  V30 25 10 11 21
+M  V30 26 10 8 21
+M  V30 27 10 21 22
+M  V30 28 10 21 23
+M  V30 29 2 24 25
+M  V30 30 2 24 26
+M  V30 31 2 24 27
+M  V30 32 1 24 28
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Photosensitizer ====
+<chemform smiles="C1C=C2C3C=CC=CN=3[Ir]3(C4=CC=CC=C4C4=CC=CC=N43)3(C4=CC=CC=C4C4N3=CC=CC=4)C2=CC=1" inchi="1S/3C11H9N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-9H;" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-05172314172D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 37 45 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.28485 -3.02507 0.0 0
+M  V30 2 C 6.01515 -3.02459 0.0 0
+M  V30 3 C 5.15164 -2.52497 0.0 0
+M  V30 4 C 6.01515 -4.02553 0.0 0
+M  V30 5 C 4.28485 -4.03002 0.0 0
+M  V30 6 C 5.15382 -4.52503 0.0 0
+M  V30 7 C 5.15382 -5.52503 0.0 0
+M  V30 8 C 6.0204 -7.0227 0.0 0
+M  V30 9 N 6.02066 -6.02506 0.0 0
+M  V30 10 C 5.15389 -7.52375 0.0 0
+M  V30 11 C 4.28385 -6.02809 0.0 0
+M  V30 12 C 4.29031 -7.02814 0.0 0
+M  V30 13 C 6.85985 -1.65007 0.0 0
+M  V30 14 C 8.59015 -1.64959 0.0 0
+M  V30 15 C 7.72664 -1.14997 0.0 0
+M  V30 16 C 8.59015 -2.65053 0.0 0
+M  V30 17 C 6.85985 -2.65502 0.0 0
+M  V30 18 N 7.72882 -3.15003 0.0 0
+M  V30 19 C 9.45618 -3.15053 0.0 0
+M  V30 20 C 11.1865 -3.14889 0.0 0
+M  V30 21 C 10.3226 -2.64984 0.0 0
+M  V30 22 C 11.1871 -4.14983 0.0 0
+M  V30 23 C 9.45685 -4.15548 0.0 0
+M  V30 24 C 10.3262 -4.64991 0.0 0
+M  V30 25 N 9.33485 -5.87507 0.0 0
+M  V30 26 C 11.0652 -5.87459 0.0 0
+M  V30 27 C 10.2016 -5.37497 0.0 0
+M  V30 28 C 11.0652 -6.87553 0.0 0
+M  V30 29 C 9.33485 -6.88002 0.0 0
+M  V30 30 C 10.2038 -7.37503 0.0 0
+M  V30 31 C 8.46882 -7.38002 0.0 0
+M  V30 32 C 7.6051 -8.87933 0.0 0
+M  V30 33 C 8.46921 -8.38073 0.0 0
+M  V30 34 C 6.73792 -8.37944 0.0 0
+M  V30 35 C 7.59818 -6.87813 0.0 0
+M  V30 36 C 6.73534 -7.38375 0.0 0
+M  V30 37 Ir 7.8 -4.975 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 6 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 2 15 13
+M  V30 15 2 16 14
+M  V30 16 1 13 17
+M  V30 17 1 14 15
+M  V30 18 2 17 18
+M  V30 19 1 18 16
+M  V30 20 1 16 19
+M  V30 21 2 21 19
+M  V30 22 2 22 20
+M  V30 23 1 19 23
+M  V30 24 1 20 21
+M  V30 25 2 23 24
+M  V30 26 1 24 22
+M  V30 27 2 27 25
+M  V30 28 2 28 26
+M  V30 29 1 25 29
+M  V30 30 1 26 27
+M  V30 31 2 29 30
+M  V30 32 1 30 28
+M  V30 33 1 29 31
+M  V30 34 2 33 31
+M  V30 35 2 34 32
+M  V30 36 1 31 35
+M  V30 37 1 32 33
+M  V30 38 2 35 36
+M  V30 39 1 36 34
+M  V30 40 10 4 37
+M  V30 41 10 9 37
+M  V30 42 10 18 37
+M  V30 43 10 23 37
+M  V30 44 10 25 37
+M  V30 45 10 35 37
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Sacrificial electron donor ====

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions

Revision as of 13:18, 17 May 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions

Revision as of 13:18, 17 May 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics