Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions

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DOI 10.1021/jacs.8b10619
Authors Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani,
Submitted 27.11.2018
Published online 27.11.2018
Licenses http://pubs.acs.org/page/policy/authorchoice_termsofuse.html,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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{{BaseTemplate}}
{{BaseTemplate}}


==== Investigation ====
==== Catalyst====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
 
==== Catalyst ====
<chemform smiles="C([*])1C=C2C3N([Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe">
<chemform smiles="C([*])1C=C2C3N([Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe">
   -INDIGO-05052316132D
   -INDIGO-05052316132D
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</chemform>
</chemform>


==== Photosensitizer ====
====Photosensitizer ====
<chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56N7C8C9N5=C(CCCCP6(C5C=CC=CC=5)C5C=CC=CC=5)C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56P(C7C=CC=CC=7)(C7C=CC=CC=7)CCCCC(C=1)=N5C=2C=3N=46" inchi="1S/2C56H50N2P2.2Cu/c2*1-7-23-43(24-8-1)53-41-45(27-19-21-39-59(47-29-11-3-12-30-47)48-31-13-4-14-32-48)57-55-51(53)37-38-52-54(44-25-9-2-10-26-44)42-46(58-56(52)55)28-20-22-40-60(49-33-15-5-16-34-49)50-35-17-6-18-36-50;;/h2*1-18,23-26,29-38,41-42H,19-22,27-28,39-40H2;;" inchikey="LDRCBPXXVZRETI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56N7C8C9N5=C(CCCCP6(C5C=CC=CC=5)C5C=CC=CC=5)C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56P(C7C=CC=CC=7)(C7C=CC=CC=7)CCCCC(C=1)=N5C=2C=3N=46" inchi="1S/2C56H50N2P2.2Cu/c2*1-7-23-43(24-8-1)53-41-45(27-19-21-39-59(47-29-11-3-12-30-47)48-31-13-4-14-32-48)57-55-51(53)37-38-52-54(44-25-9-2-10-26-44)42-46(58-56(52)55)28-20-22-40-60(49-33-15-5-16-34-49)50-35-17-6-18-36-50;;/h2*1-18,23-26,29-38,41-42H,19-22,27-28,39-40H2;;" inchikey="LDRCBPXXVZRETI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-03312316052D
   -INDIGO-03312316052D
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M  END
M  END
</chemform>
</chemform>
====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}


==== Sacrificial electron donor ====
==== Sacrificial electron donor ====
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}

Revision as of 10:13, 7 July 2023


Catalyst

100751 [Show R-Groups]

Photosensitizer

Investigation

  1. REDIRECT Results for photocatalytic reduction of CO2
Investigation-Name: Table 1

Sacrificial electron donor

BIHTEOA

Investigations

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