Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 10:42, 4 May 2023

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Investigation

Experiment 'Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction/' does not exist.

Catalyst

Photosensitizer

Sacrificial electron donor

TEOA

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1039/c6sc01913g
Authors	Jana Rohacova, Osamu Ishitani,
Submitted	05.07.2016
Published online	2016
Licenses	-
Subjects	-
Go to literature page

Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 10:42, 4 May 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

@@ Line 6: / Line 6: @@
 ==== Catalyst ====
-<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform>Re(bpy)(CO)3(MeCN)
+<chemform smiles="C1C=C2C3C=CC=CN=3[Re+](C#O)(N#CC)(C#O)(C#O)N2=CC=1.[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="PF6-">
+  -INDIGO-05042311362D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 23 24 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.80985 -3.10007 0.0 0
+M  V30 2 C 6.54015 -3.09959 0.0 0
+M  V30 3 C 5.67664 -2.59997 0.0 0
+M  V30 4 N 6.54015 -4.10053 0.0 0
+M  V30 5 C 4.80985 -4.10502 0.0 0
+M  V30 6 C 5.67882 -4.60003 0.0 0
+M  V30 7 C 5.67882 -5.60003 0.0 0
+M  V30 8 C 6.5454 -7.09769 0.0 0
+M  V30 9 N 6.54566 -6.10006 0.0 0
+M  V30 10 C 5.67889 -7.59875 0.0 0
+M  V30 11 C 4.80885 -6.10309 0.0 0
+M  V30 12 C 4.81531 -7.10314 0.0 0
+M  V30 13 Re 7.4 -5.125 0.0 0 CHG=1
+M  V30 14 C 7.4 -6.125 0.0 0
+M  V30 15 C 8.10711 -4.41789 0.0 0
+M  V30 16 N 7.4 -4.125 0.0 0
+M  V30 17 C 8.10711 -5.83211 0.0 0
+M  V30 18 O 7.4 -7.125 0.0 0
+M  V30 19 O 8.81421 -6.53921 0.0 0
+M  V30 20 O 8.81421 -3.71079 0.0 0
+M  V30 21 C 7.4 -3.125 0.0 0
+M  V30 22 C 7.4 -2.125 0.0 0
+M  V30 23 R# 11.025 -1.7 0.0 0 RGROUPS=(1 1)
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 6 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
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+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 10 4 13
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+M  V30 16 10 13 14
+M  V30 17 10 13 15
+M  V30 18 10 13 16
+M  V30 19 10 13 17
+M  V30 20 3 14 18
+M  V30 21 3 17 19
+M  V30 22 3 15 20
+M  V30 23 3 16 21
+M  V30 24 1 21 22
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C(C(C)(C)C)1C=C2C3C=C(C(C)(C)C)C=CN=3[Ru](~Cl)(~Cl)(C#O)(C#O)N2=CC=1" inchi="1S/C18H24N2.2CHO.2ClH.Ru/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2;;;/h7-12H,1-6H3;2*1H;2*1H;/q;;;;;+2/p-2" inchikey="RUJTWEUENVZQPO-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+  -INDIGO-05042311392D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 27 29 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 5.43485 -2.27507 0.0 0
+M  V30 2 C 7.16515 -2.27459 0.0 0
+M  V30 3 C 6.30164 -1.77497 0.0 0
+M  V30 4 N 7.16515 -3.27553 0.0 0
+M  V30 5 C 5.43485 -3.28002 0.0 0
+M  V30 6 C 6.30382 -3.77503 0.0 0
+M  V30 7 C 6.30382 -4.77503 0.0 0
+M  V30 8 C 7.1704 -6.2727 0.0 0
+M  V30 9 N 7.17066 -5.27506 0.0 0
+M  V30 10 C 6.30389 -6.77375 0.0 0
+M  V30 11 C 5.43385 -5.27809 0.0 0
+M  V30 12 C 5.44031 -6.27814 0.0 0
+M  V30 13 Ru 8.325 -4.25 0.0 0
+M  V30 14 C 4.57429 -6.77814 0.0 0
+M  V30 15 C 3.60836 -6.51932 0.0 0
+M  V30 16 C 3.70826 -7.27814 0.0 0
+M  V30 17 C 4.31547 -7.74407 0.0 0
+M  V30 18 C 9.03211 -3.54289 0.0 0
+M  V30 19 C 9.03211 -4.95711 0.0 0
+M  V30 20 O 9.73921 -5.66421 0.0 0
+M  V30 21 O 9.73921 -2.83579 0.0 0
+M  V30 22 Cl 8.325 -5.25 0.0 0
+M  V30 23 Cl 8.325 -3.25 0.0 0
+M  V30 24 C 4.56882 -1.77507 0.0 0
+M  V30 25 C 3.6029 -2.03389 0.0 0
+M  V30 26 C 3.7028 -1.27507 0.0 0
+M  V30 27 C 4.31 -0.809149 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 6 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 10 4 13
+M  V30 15 10 9 13
+M  V30 16 1 12 14
+M  V30 17 1 14 15
+M  V30 18 1 14 16
+M  V30 19 1 14 17
+M  V30 20 10 13 18
+M  V30 21 10 13 19
+M  V30 22 3 19 20
+M  V30 23 3 18 21
+M  V30 24 8 13 22
+M  V30 25 8 13 23
+M  V30 26 1 1 24
+M  V30 27 1 24 25
+M  V30 28 1 24 26
+M  V30 29 1 24 27
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C(C(C)(C)C)1C=C2C3C=C(C(C)(C)C)C=CN=3[Mn+](C#O)(C#O)(C#O)(N#CC)N2=CC=1.[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="PF6-">
+  -INDIGO-05042311412D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 31 32 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 5.33485 -3.22507 0.0 0
+M  V30 2 C 7.06515 -3.22459 0.0 0
+M  V30 3 C 6.20164 -2.72497 0.0 0
+M  V30 4 N 7.06515 -4.22553 0.0 0
+M  V30 5 C 5.33485 -4.23002 0.0 0
+M  V30 6 C 6.20382 -4.72503 0.0 0
+M  V30 7 C 6.20382 -5.72503 0.0 0
+M  V30 8 C 7.0704 -7.22269 0.0 0
+M  V30 9 N 7.07066 -6.22506 0.0 0
+M  V30 10 C 6.20389 -7.72375 0.0 0
+M  V30 11 C 5.33385 -6.22809 0.0 0
+M  V30 12 C 5.34031 -7.22814 0.0 0
+M  V30 13 C 4.46882 -2.72507 0.0 0
+M  V30 14 C 3.5029 -2.98389 0.0 0
+M  V30 15 C 3.6028 -2.22507 0.0 0
+M  V30 16 C 4.21 -1.75915 0.0 0
+M  V30 17 C 4.47429 -7.72814 0.0 0
+M  V30 18 C 3.60826 -8.22814 0.0 0
+M  V30 19 C 3.50836 -7.46932 0.0 0
+M  V30 20 C 4.21547 -8.69407 0.0 0
+M  V30 21 Mn 7.75 -5.2 0.0 0 CHG=1
+M  V30 22 N 7.75 -4.2 0.0 0
+M  V30 23 C 8.61602 -4.7 0.0 0
+M  V30 24 C 8.61602 -5.7 0.0 0
+M  V30 25 C 8.00882 -6.16593 0.0 0
+M  V30 26 C 7.75 -3.2 0.0 0
+M  V30 27 C 7.75 -2.2 0.0 0
+M  V30 28 O 9.48205 -4.2 0.0 0
+M  V30 29 O 9.48205 -6.2 0.0 0
+M  V30 30 O 8.26764 -7.13185 0.0 0
+M  V30 31 R# 10.675 -1.5 0.0 0 RGROUPS=(1 1)
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 6 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 1 1 13
+M  V30 15 1 13 14
+M  V30 16 1 13 15
+M  V30 17 1 13 16
+M  V30 18 1 12 17
+M  V30 19 1 17 18
+M  V30 20 1 17 19
+M  V30 21 1 17 20
+M  V30 22 10 4 21
+M  V30 23 10 9 21
+M  V30 24 10 21 22
+M  V30 25 10 21 23
+M  V30 26 10 21 24
+M  V30 27 10 21 25
+M  V30 28 3 22 26
+M  V30 29 1 26 27
+M  V30 30 3 23 28
+M  V30 31 3 24 29
+M  V30 32 3 25 30
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
 ==== Photosensitizer ====

Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 10:42, 4 May 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics