Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions

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DOI 10.1021/jacs.8b10619
Authors Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani,
Submitted 27.11.2018
Published online 27.11.2018
Licenses http://pubs.acs.org/page/policy/authorchoice_termsofuse.html,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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==== Photosensitizer ====
==== Photosensitizer ====
<chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP([*])([*])[Cu]56N7C8C9N5=C(CCCCP6([*])[*])C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP([*])([*])[Cu]56P([*])([*])CCCCC(C=1)=N5C=2C=3N=46" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Ph">
<chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56N7C8C9N5=C(CCCCP6(C5C=CC=CC=5)C5C=CC=CC=5)C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56P(C7C=CC=CC=7)(C7C=CC=CC=7)CCCCC(C=1)=N5C=2C=3N=46" inchi="1S/2C56H50N2P2.2Cu/c2*1-7-23-43(24-8-1)53-41-45(27-19-21-39-59(47-29-11-3-12-30-47)48-31-13-4-14-32-48)57-55-51(53)37-38-52-54(44-25-9-2-10-26-44)42-46(58-56(52)55)28-20-22-40-60(49-33-15-5-16-34-49)50-35-17-6-18-36-50;;/h2*1-18,23-26,29-38,41-42H,19-22,27-28,39-40H2;;" inchikey="LDRCBPXXVZRETI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-03102314502D
   -INDIGO-03312316052D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 BEGIN CTAB
M  V30 COUNTS 82 96 0 0 0
M  V30 COUNTS 122 144 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 C 3.88485 -2.97507 0.0 0
M  V30 1 C 3.88485 -2.97507 0.0 0
Line 242: Line 242:
M  V30 73 C 12.3351 -3.60033 0.0 0
M  V30 73 C 12.3351 -3.60033 0.0 0
M  V30 74 C 11.9351 -4.62533 0.0 0
M  V30 74 C 11.9351 -4.62533 0.0 0
M  V30 75 R# 8.925 -7.875 0.0 0 RGROUPS=(1 1)
M  V30 75 C 6.56618 -0.859074 0.0 0
M  V30 76 R# 8.425 -7.74103 0.0 0 RGROUPS=(1 1)
M  V30 76 C 8.54818 -0.676982 0.0 0
M  V30 77 R# 10.484 -9.0 0.0 0 RGROUPS=(1 1)
M  V30 77 C 11.0504 -2.3253 0.0 0
M  V30 78 R# 9.83397 -8.525 0.0 0 RGROUPS=(1 1)
M  V30 78 C 12.9496 -1.9497 0.0 0
M  V30 79 R# 10.3929 -3.84289 0.0 0 RGROUPS=(1 1)
M  V30 79 C 11.2162 -10.7659 0.0 0
M  V30 80 R# 11.3412 -3.58407 0.0 0 RGROUPS=(1 1)
M  V30 80 C 9.98397 -9.55 0.0 0
M  V30 81 R# 8.3 -2.175 0.0 0 RGROUPS=(1 1)
M  V30 81 C 6.575 -8.99102 0.0 0
M  V30 82 R# 9.26593 -2.91618 0.0 0 RGROUPS=(1 1)
M  V30 82 C 7.75 -10.325 0.0 0
M  V30 83 C 6.12875 -10.6628 0.0 0
M  V30 84 C 6.83437 -9.95754 0.0 0
M  V30 85 C 5.16174 -10.4044 0.0 0
M  V30 86 C 5.60412 -8.73158 0.0 0
M  V30 87 C 4.90155 -9.44329 0.0 0
M  V30 88 C 8.19942 -11.9959 0.0 0
M  V30 89 C 8.45788 -11.0323 0.0 0
M  V30 90 C 7.23276 -12.2556 0.0 0
M  V30 91 C 6.77947 -10.5857 0.0 0
M  V30 92 C 6.52688 -11.5534 0.0 0
M  V30 93 C 9.98562 -11.2803 0.0 0
M  V30 94 C 10.4847 -10.4165 0.0 0
M  V30 95 C 8.98468 -11.281 0.0 0
M  V30 96 C 8.97903 -9.55067 0.0 0
M  V30 97 C 8.4846 -10.42 0.0 0
M  V30 98 C 12.4409 -11.9883 0.0 0
M  V30 99 C 12.1829 -11.0246 0.0 0
M  V30 100 C 11.7336 -12.6965 0.0 0
M  V30 101 C 10.5061 -11.477 0.0 0
M  V30 102 C 10.7711 -12.4413 0.0 0
M  V30 103 C 12.9479 -0.219397 0.0 0
M  V30 104 C 12.4489 -1.08325 0.0 0
M  V30 105 C 13.9489 -0.218726 0.0 0
M  V30 106 C 13.9545 -1.94902 0.0 0
M  V30 107 C 14.4489 -1.07972 0.0 0
M  V30 108 C 10.1839 -0.82764 0.0 0
M  V30 109 C 10.1836 -1.82528 0.0 0
M  V30 110 C 11.0504 -0.326587 0.0 0
M  V30 111 C 11.9204 -1.82225 0.0 0
M  V30 112 C 11.9139 -0.822192 0.0 0
M  V30 113 C 5.06687 0.00465143 0.0 0
M  V30 114 C 5.56547 -0.859457 0.0 0
M  V30 115 C 5.56676 0.871829 0.0 0
M  V30 116 C 7.06807 0.011571 0.0 0
M  V30 117 C 6.56245 0.874412 0.0 0
M  V30 118 C 7.6816 0.82068 0.0 0
M  V30 119 C 7.68134 -0.176956 0.0 0
M  V30 120 C 8.54811 1.32173 0.0 0
M  V30 121 C 9.41815 -0.173926 0.0 0
M  V30 122 C 9.41169 0.826128 0.0 0
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
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M  V30 87 10 27 54
M  V30 87 10 27 54
M  V30 88 10 19 54
M  V30 88 10 19 54
M  V30 89 1 56 75
M  V30 89 1 57 75
M  V30 90 1 56 76
M  V30 90 1 70 77
M  V30 91 1 55 77
M  V30 91 1 70 78
M  V30 92 1 55 78
M  V30 92 1 55 79
M  V30 93 1 70 79
M  V30 93 1 55 80
M  V30 94 1 70 80
M  V30 94 1 56 81
M  V30 95 1 57 81
M  V30 95 1 56 82
M  V30 96 1 57 82
M  V30 96 2 84 81
M  V30 97 2 85 83
M  V30 98 1 81 86
M  V30 99 1 83 84
M  V30 100 2 86 87
M  V30 101 1 87 85
M  V30 102 2 89 82
M  V30 103 2 90 88
M  V30 104 1 82 91
M  V30 105 1 88 89
M  V30 106 2 91 92
M  V30 107 1 92 90
M  V30 108 2 94 80
M  V30 109 2 95 93
M  V30 110 1 80 96
M  V30 111 1 93 94
M  V30 112 2 96 97
M  V30 113 1 97 95
M  V30 114 2 99 79
M  V30 115 2 100 98
M  V30 116 1 79 101
M  V30 117 1 98 99
M  V30 118 2 101 102
M  V30 119 1 102 100
M  V30 120 2 104 78
M  V30 121 2 105 103
M  V30 122 1 78 106
M  V30 123 1 103 104
M  V30 124 2 106 107
M  V30 125 1 107 105
M  V30 126 2 109 77
M  V30 127 2 110 108
M  V30 128 1 77 111
M  V30 129 1 108 109
M  V30 130 2 111 112
M  V30 131 1 112 110
M  V30 132 2 114 75
M  V30 133 2 115 113
M  V30 134 1 75 116
M  V30 135 1 113 114
M  V30 136 2 116 117
M  V30 137 1 117 115
M  V30 138 2 119 76
M  V30 139 2 120 118
M  V30 140 1 76 121
M  V30 141 1 118 119
M  V30 142 2 121 122
M  V30 143 1 122 120
M  V30 144 1 76 57
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB
M  END
M  END
</chemform>
</chemform>

Revision as of 15:05, 31 March 2023



WikiTemplate chemistry.pngMissing molecule Date: 2023-03-10
Author: ChN
This page is missing a molecule. It may reference a chemical substance that is not present in this wiki. Please use the chemical formula template to draw and add it.

Investigation

Investigation-Name: Table 1

Catalyst

Photosensitizer

Investigations