Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions

From ChemWiki
publication
About
DOI 10.1021/jacs.0c08145
Authors Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim,
Submitted 19.10.2020
Published online 19.10.2020
Licenses https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page
m (auto-update)
(Added molecules)
Line 167: Line 167:


==== Photosensitizer ====
==== Photosensitizer ====
{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L}}
<chemform smiles="" inchi="" inchikey="SEACYXSIPDVVMV-UHFFFAOYSA-L " height="200px" width="300px" float="none"></chemform>


==== Sacrificial electron donor ====
==== Sacrificial electron donor ====
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N}}
<chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
[[Category:Photocatalytic CO2 conversion to HCOOH]]
[[Category:Photocatalytic CO2 conversion to HCOOH]]

Revision as of 12:57, 3 May 2023


Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A....TON HCOOH...
1.

Ni(pbi)(pyS)2

0.004

Eosin Y

2

TEOA

0.4

H2O

14000
2.

Ni(pbt)(pyS)2

0.004

Eosin Y

2

TEOA

0.4

H2O

13100
Investigation-Name: Table 1

Catalyst

Ni(pbi)(pyS)2 Ni(pbt)(pyS)2

Photosensitizer

Eosin Y

Sacrificial electron donor

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)