Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction: Difference between revisions
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==== Photosensitizer ==== | ==== Photosensitizer ==== | ||
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==== Sacrificial electron donor ==== | ==== Sacrificial electron donor ==== | ||
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[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] | ||
Revision as of 12:53, 3 May 2023
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | λexc [nm] | . | TON CO | TON H2 | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.05 | 0.5 | 0.1 | 400 | 73 | 670 | 80 | |||||||||
| 2. | 0.05 | 0.5 | 0.1 | 400 | 13 | 51 | 31 | |||||||||
| 3. | 0.05 | 0.5 | 0.1 | 400 | 40 | 89 | 83 |
Investigation-Name: Table 1
Catalyst
[K]2[MoO(Hqpdt)2]
[MoO(2Hqpdt)2][NBu4]
Photosensitizer
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
