Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions

Revision as of 15:11, 26 January 2023

Investigation

Catalyst

Molecule with key NRVILUOLTIKJEU-NGWNFTKISA-I does not exist.

Photosensitizer

Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.

Sacrificial electron donor

TEOA TEA DIPEA

Investigations

Cyclic voltammetry in various conditions (Assay, Cyclic Voltammetry experiments)
Photocatalytic reduction of CO2: conditions optimization (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/acs.jpcc.8b00950
Authors	Heng Rao, Julien Bonin, Marc Robert,
Submitted	28.04.2018
Published online	28.04.2018
Licenses	-
Subjects	Surfaces, Coatings and Films, Physical and Theoretical Chemistry, General Energy, Electronic, Optical and Magnetic Materials
Go to literature page

@@ Line 1: / Line 1: @@
 {{#doiinfobox: 10.1021/acs.jpcc.8b00950}}
+==== Investigation ====
+==== Catalyst ====
+{{#moleculelink:|link=NRVILUOLTIKJEU-NGWNFTKISA-I}}
+==== Photosensitizer ====
+{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N}} <chemform smiles="C1C=C2C3C([Ir+]4(N5C(C6N4=CC=CC=6)=CC=CC=5)4(N5C(C6C4=CC=CC=6)=CC=CC=5)N2=CC=1)=CC=CC=3" inchi="1S/2C11H9N.C10H8N2.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h2*1-9H;1-8H;/q;;;+1" inchikey="WEEPMIZXGXTKSO-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-01262315082D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 37 45 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.45797 -3.44045 0.0 0
+M  V30 2 C 5.96133 -3.36319 0.0 0
+M  V30 3 C 5.12223 -3.03828 0.0 0
+M  V30 4 N 6.18456 -4.17527 0.0 0
+M  V30 5 C 4.46811 -4.21322 0.0 0
+M  V30 6 C 5.26148 -4.65508 0.0 0
+M  V30 7 C 4.51917 -5.73215 0.0 0
+M  V30 8 C 6.22384 -5.76587 0.0 0
+M  V30 9 C 5.27077 -5.2974 0.0 0
+M  V30 10 C 6.0193 -6.57651 0.0 0
+M  V30 11 C 4.5162 -6.49701 0.0 0
+M  V30 12 C 5.18205 -6.90334 0.0 0
+M  V30 13 C 7.51732 -7.30385 0.0 0
+M  V30 14 C 8.97092 -7.39426 0.0 0
+M  V30 15 C 8.09356 -6.79102 0.0 0
+M  V30 16 C 8.96182 -8.29372 0.0 0
+M  V30 17 C 7.6068 -8.20544 0.0 0
+M  V30 18 C 8.27229 -8.63762 0.0 0
+M  V30 19 N 9.48753 -6.07146 0.0 0
+M  V30 20 C 11.0499 -6.53021 0.0 0
+M  V30 21 C 10.3685 -5.88703 0.0 0
+M  V30 22 C 10.9588 -7.31958 0.0 0
+M  V30 23 C 9.51277 -7.13327 0.0 0
+M  V30 24 C 10.258 -7.63524 0.0 0
+M  V30 25 C 7.60897 -1.47271 0.0 0
+M  V30 26 C 9.01802 -1.50872 0.0 0
+M  V30 27 C 8.3457 -1.08144 0.0 0
+M  V30 28 C 8.89639 -2.52314 0.0 0
+M  V30 29 C 7.45099 -2.43365 0.0 0
+M  V30 30 N 8.05713 -3.03115 0.0 0
+M  V30 31 C 9.48728 -2.84506 0.0 0
+M  V30 32 C 10.8821 -2.79881 0.0 0
+M  V30 33 C 10.2032 -2.4236 0.0 0
+M  V30 34 C 10.9119 -3.6346 0.0 0
+M  V30 35 N 9.37872 -3.98759 0.0 0
+M  V30 36 C 10.1731 -4.23891 0.0 0
+M  V30 37 Ir 7.92552 -4.9583 0.0 0 CHG=1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 2 27 25
+M  V30 26 2 28 26
+M  V30 27 1 25 29
+M  V30 28 1 26 27
+M  V30 29 2 29 30
+M  V30 30 1 30 28
+M  V30 31 2 33 31
+M  V30 32 2 34 32
+M  V30 33 1 31 35
+M  V30 34 1 32 33
+M  V30 35 2 35 36
+M  V30 36 1 36 34
+M  V30 37 1 28 31
+M  V30 38 1 14 23
+M  V30 39 1 6 9
+M  V30 40 10 4 37
+M  V30 41 10 8 37
+M  V30 42 10 15 37
+M  V30 43 10 19 37
+M  V30 44 10 35 37
+M  V30 45 10 30 37
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Sacrificial electron donor ====
+{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N}} {{#moleculelink:|link=JGFZNNIVVJXRND-UHFFFAOYSA-N}}
 [[Category:Photocatalytic conversion of CO2 to CH4]]

Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions

Revision as of 15:11, 26 January 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions

Revision as of 15:11, 26 January 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics