Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:52, 12 December 2022

Catalysts


2	3	4	5	6	7
100610	100607	100611	100612	100608	100609

Photosensitizer

Electron donor

TEOA

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
4.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
6.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27

Investigation-Name: Table 1

Literature

[PRo15] Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light. Alonso Rosas-Hernández, Henrik Junge, Matthias Beller, ChemCatChem 2015, Vol. 7, Pages 3316-3321. DOI2: 10.1002/cctc.201500494
Publication: Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light

Investigations

CO2 reduction experiments (Molecular process, Photocatalytic CO2 conversion experiments)
Optimization of concentrations (Molecular process, Photocatalytic CO2 conversion experiments)
Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 3 - CV (Assay, Cyclic Voltammetry experiments)

@@ Line 2: / Line 2: @@
 {{#literature:|doi=http://dx.doi.org/10.1002/cctc.201500494}}
+=== Catalysts ===
 <chemform smiles="C1C=CN2~[Ru](~[*])(~[*])3(~N4C=CC=CC=4C4N~3=CC=CC=4)~N3C=CC=CC=3C=2C=1" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Cl,Cl,H" r2="Cl,CO,CO">
    -INDIGO-12122214162D
@@ Line 309: / Line 310: @@
 M  V30 END CTAB
 M  END
-</chemform><chemform smiles="C1C2C3C=CC=CC=3~[Ir]3(~C4C=CC=CC=4C4C=CC=CN=4~3)3(~N4=C(C5N~3=CC=CC=5)C=CC=C4)~N=2C=CC=1.P(F)(F)(F)(F)(F)F" inchi="1S/2C11H9N.C10H8N2.F6P.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-9H;1-8H;;" inchikey="YLYRMTZQAOANTD-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+</chemform>
+{| class="wikitable"
+|+
+!2
+!3
+!4
+!5
+!6
+!7
+|-
+|100610
+|100607
+|100611
+|100612
+|100608
+|100609
+|}
+=== Photosensitizer ===
+<chemform smiles="C1C2C3C=CC=CC=3~[Ir]3(~C4C=CC=CC=4C4C=CC=CN=4~3)3(~N4=C(C5N~3=CC=CC=5)C=CC=C4)~N=2C=CC=1.P(F)(F)(F)(F)(F)F" inchi="1S/2C11H9N.C10H8N2.F6P.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-9H;1-8H;;" inchikey="YLYRMTZQAOANTD-UHFFFAOYSA-N" height="200px" width="300px" float="none">
    -INDIGO-12122214422D
@@ Line 413: / Line 433: @@
 M  V30 50 1 38 43
 M  V30 51 1 38 44
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+=== Electron donor ===
+<chemform smiles="N(CCO)(CCO)CCO" inchi="1S/C6H15NO3/c8-4-1-7(2-5-9)3-6-10/h8-10H,1-6H2" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-12122214492D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 10 9 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 N 8.45 -5.25 0.0 0
+M  V30 2 C 9.31603 -4.75 0.0 0
+M  V30 3 C 10.1821 -5.25 0.0 0
+M  V30 4 C 8.70882 -6.21593 0.0 0
+M  V30 5 C 8.20882 -7.08195 0.0 0
+M  V30 6 C 7.45 -5.25 0.0 0
+M  V30 7 C 6.975 -4.43397 0.0 0
+M  V30 8 O 5.97501 -4.43751 0.0 0
+M  V30 9 O 11.0481 -4.74998 0.0 0
+M  V30 10 O 8.70882 -7.94798 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 1 1 2
+M  V30 2 1 2 3
+M  V30 3 1 1 4
+M  V30 4 1 4 5
+M  V30 5 1 1 6
+M  V30 6 1 6 7
+M  V30 7 1 7 8
+M  V30 8 1 3 9
+M  V30 9 1 5 10
 M  V30 END BOND
 M  V30 END CTAB

Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:52, 12 December 2022

Catalysts

Photosensitizer

Electron donor

Literature

Investigations

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