A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity: Difference between revisions
From ChemWiki
publication
| About |
|---|
No edit summary |
m auto-generated |
||
| (One intermediate revision by one other user not shown) | |||
| Line 261: | Line 261: | ||
===Further Information=== | ===Further Information=== | ||
====Sacrificial electron donor==== | ====Sacrificial electron donor==== | ||
In this study, the experiments were done with the sacrificial electron donor . | In this study, the experiments were done with the sacrificial electron donor {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}. | ||
====Additives==== | ====Additives==== | ||
{{Tags|tags=photocatalytic CO2 reduction, cobalt phenanthroline catalyst, ruthenium polypyridyl photosensitizer, homogeneous catalysis, triethanolamine sacrificial donor, acetonitrile solvent, visible light irradiation, turnover number, transition metal complexes, organometallic chemistry, phenanthroline ligands, cyanide ligands}} | |||
Latest revision as of 11:40, 21 November 2025
Abstract[edit | edit source]
Summary[edit | edit source]
Additional remarks[edit | edit source]
Content of the published article in detail[edit | edit source]
Catalysts tested in this study[edit | edit source]
Photosensitizer[edit | edit source]
Investigation[edit | edit source]
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | λexc [nm] | . | TON CO | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0 | 0.40 | 0.4 | 469 | 0 | |||||||||
| 2. | 2.5 | 0.40 | 0.4 | 469 | 1130 | |||||||||
| 3. | 5 | 0.40 | 0.4 | 469 | 730 | |||||||||
| 4. | 25 | 0.40 | 0.4 | 469 | 154 | |||||||||
| 5. | 2.5 | 0.40 | 0.4 | 0 | ||||||||||
| 6. | 0 | 0.40 | 0.4 | 469 | 0 | |||||||||
| 7. | 2.5 | 0.40 | 0.4 | 469 | 0 | |||||||||
| 8. | 2.5 | 0.40 | 469 | 0 | ||||||||||
| 9. | 2.5 | 0.40 | 0.4 | 469 | 720 | |||||||||
| 10. | 2.5 | 0.4 | 469 | 0 |
Investigation-Name: Table 1
Further Information[edit | edit source]
Sacrificial electron donor[edit | edit source]
In this study, the experiments were done with the sacrificial electron donor TEOA.
Additives[edit | edit source]
Tags: photocatalytic CO2 reduction, cobalt phenanthroline catalyst, ruthenium polypyridyl photosensitizer, homogeneous catalysis, triethanolamine sacrificial donor, acetonitrile solvent, visible light irradiation, turnover number, transition metal complexes, organometallic chemistry, phenanthroline ligands, cyanide ligands |
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
