New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2/Photocatalytic CO2 reduction and control experiments: Difference between revisions

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{{Photocatalytic CO2 conversion experiments
{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100906
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=4.3
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100907
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=4.9
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100908
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=8.1
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100909
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=4.6
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=2.6
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100907
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=3.5
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100908
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=5.0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100909
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=1.8
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=4:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|TON CO=2.8
|include=No
}}{{Photocatalytic CO2 conversion
|PS=Molecule:100908
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100908
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100910
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100908
|PS conc=1
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100908
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=argon
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=dark
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100911
|cat conc=0.1
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=4
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100906
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=10
|TON CO=7.3
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100812
|cat conc=0.1
|PS=Molecule:100907
|PS conc=1
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=23
|λexc=420 nm (4 x 8 W)
|irr time=10
|TON CO=6.5
|include=No
|include=No
}}
}}
}}
}}

Latest revision as of 17:23, 3 April 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Ni(cyclam)Cl2

0.1

Molecule:100906

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 4.3 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100907

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 4.9 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100908

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 8.1 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100909

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 4.6 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100906

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 2.6 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100907

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 3.5 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100908

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 5.0 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100909

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 1.8 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100906

1

BIH

0.01


MeCN

TEOA


4:1 CO2 23 420 nm (4 x 8 W) 4 2.8 n/a


No


Molecule:100908

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100908

1

BIH

0.01


MeCN

N(Me)3


5:1 CO2 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100908

1



MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100908

1

BIH

0.01


MeCN

TEOA


5:1 argon 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1


BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100906

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 dark 4 n/a


No

[Cu(ACN)4][BF4]

0.1

Molecule:100906

1

BIH

0.01


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 4 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100906

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 10 7.3 n/a


No

Ni(cyclam)Cl2

0.1

Molecule:100907

1

BIH

0.02


MeCN

TEOA


5:1 CO2 23 420 nm (4 x 8 W) 10 6.5 n/a


No
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