Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore/Control experiments

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[MoO(2Hqpdt)2][NBu4]	0.0001	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	8600						144									98.4%; 0%; 1.6%; 0%; 0%			No
		[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	0						0									n/a			No
[MoO(2Hqpdt)2][NBu4]	0.0001			BIH	0.1			DMF						CO2				25	white LED	23	0						0									n/a			No
[MoO(2Hqpdt)2][NBu4]	0.0001	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	0						1466									n/a			No
[MoO(2Hqpdt)2][NBu4]	0.0001	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25		23	0						0									n/a			No
[MoO(2Hqpdt)2][NBu4]	0.0001	[Cu(PP)2][TBA]2	0.1					DMF						CO2				25	white LED	23	0						0									n/a			No
[MoO(2Hqpdt)2][NBu4]	0.00002	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	16109						843									95.0%; 0%; 5.0%; 0%; 0%			No
[MoO(2Hqpdt)2][NBu4]	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	5963						63									99.0%; 0%; 1.0%; 0%; 0%			No
[MoO(2Hqpdt)2][NBu4]	0.0001	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF				Hg		CO2				25	white LED	23	8600						144									98.4%; 0%; 1.6%; 0%; 0%			No
[MoO(2Hqpdt)2][NBu4]	0.0005	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	3385						43									98.7%; 0%; 1.3%; 0%; 0%			No
[MoO(2Hqpdt)2][NBu4]	0.001	[Cu(PP)2][TBA]2	0.1	BIH	0.1			DMF						CO2				25	white LED	23	3131						12									99.6%; 0%; 0.4%; 0%; 0%			No