Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts/Durability test: Difference between revisions

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|solvent-ratio=4:1
|solvent-ratio=4:1
|λexc=436 nm
|λexc=436 nm
|irr time=36
|TON CO=1004
|TON H2=68
|TON HCOOH=310
|include=No
|include=No
}}
}}
}}
}}

Latest revision as of 12:56, 30 January 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100845

0.05

[Cu(phen)-(dPPh-Bu)2]2[PF6]2

0.25

BIH

0.1


MeCN

TEOA


4:1 436 nm 36 1004 68 310 72.6%; 0%; 4.9%; 22.4%; 0%


No