Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts/Durability test: Difference between revisions
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< Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts
investigation
Molecular process, Photocatalytic CO2 conversion experimentsNo edit summary |
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|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
|e-D conc=0.1 | |e-D conc=0.1 | ||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100507 | |||
|solvent-ratio=4:1 | |||
|λexc=436 nm | |||
|irr time=36 | |||
|TON CO=1004 | |||
|TON H2=68 | |||
|TON HCOOH=310 | |||
|include=No | |include=No | ||
}} | }} | ||
}} | }} |
Latest revision as of 12:56, 30 January 2024
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.05 | 0.25 | 0.1 |
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4:1 | 436 nm | 36 | 1004 | 68 | 310 | 72.6%; 0%; 4.9%; 22.4%; 0% |
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No |