Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts/Durability test: Difference between revisions

Latest revision as of 12:56, 30 January 2024

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100845	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.1			MeCN	TEOA		4:1								436 nm	36	1004						68			310						72.6%; 0%; 4.9%; 22.4%; 0%			No

@@ Line 2: / Line 2: @@
 |experiments={{Photocatalytic CO2 conversion
 |catalyst=Molecule:100845
+|cat conc=0.05
 |PS=Molecule:100828
+|PS conc=0.25
 |e-D=Molecule:100508
 |e-D conc=0.1
+|solvent A=Molecule:100530
+|solvent B=Molecule:100507
+|solvent-ratio=4:1
+|λexc=436 nm
+|irr time=36
+|TON CO=1004
+|TON H2=68
+|TON HCOOH=310
 |include=No
 }}
 }}