Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100493	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	103						25									80.5%; 0%; 19.5%; 0%; 0%			Yes
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100761	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	88						12									88.0%; 0%; 12.0%; 0%; 0%			Yes
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100762	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	115															n/a			Yes
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100763	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	112						12									90.3%; 0%; 9.7%; 0%; 0%			Yes
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100764	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	32						57									36.0%; 0%; 64.0%; 0%; 0%			Yes
[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100765	0.2	BIH	0.005			MeCN				TFE	0.1						> 400	21	89															n/a			Yes