Editing A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
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  -INDIGO-12072422132D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 33 40 2 0 0
M  V30 BEGIN ATOM
M  V30 1 C -3.13722 -0.831344 0.0 0
M  V30 2 C -2.71343 -1.53918 0.0 0
M  V30 3 C -1.88853 -1.52608 0.0 0
M  V30 4 N -1.48743 -0.805155 0.0 0
M  V30 5 C -1.91121 -0.097321 0.0 0
M  V30 6 C -2.73611 -0.110416 0.0 0
M  V30 7 C -1.51011 0.623607 0.0 0
M  V30 8 C -1.93389 1.33144 0.0 0
M  V30 9 C -2.75879 1.31835 0.0 0
M  V30 10 C -3.1599 0.597418 0.0 0
M  V30 11 N -0.685211 0.636701 0.0 0
M  V30 12 C -0.284103 1.35763 0.0 0
M  V30 13 C -0.707891 2.06546 0.0 0
M  V30 14 C -1.53279 2.05237 0.0 0
M  V30 15 C 1.52227 2.09226 0.0 0
M  V30 16 C 0.697304 2.09937 0.0 0
M  V30 17 C 0.278662 1.38848 0.0 0
M  V30 18 N 0.684991 0.670483 0.0 0
M  V30 19 C 1.50996 0.663375 0.0 0
M  V30 20 C 1.9286 1.37426 0.0 0
M  V30 21 C 1.91629 -0.054624 0.0 0
M  V30 22 C 2.74126 -0.061733 0.0 0
M  V30 23 C 3.1599 0.649157 0.0 0
M  V30 24 C 2.75357 1.36716 0.0 0
M  V30 25 N 1.49765 -0.765515 0.0 0
M  V30 26 C 1.90398 -1.48351 0.0 0
M  V30 27 C 2.72895 -1.49062 0.0 0
M  V30 28 C 3.14759 -0.779732 0.0 0
M  V30 29 Co 0.008948 -0.207104 0.0 0
M  V30 30 C -0.575828 -1.33399 0.0 0
M  V30 31 N -0.955826 -2.06627 0.0 0
M  V30 32 C 0.462698 -1.33407 0.0 0
M  V30 33 N 0.770828 -2.09937 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 3 30 31
M  V30 2 1 29 30
M  V30 3 3 32 33
M  V30 4 1 29 32
M  V30 5 2 1 2
M  V30 6 1 2 3
M  V30 7 2 3 4
M  V30 8 1 4 5
M  V30 9 2 5 6
M  V30 10 1 6 1
M  V30 11 1 5 7
M  V30 12 2 7 8
M  V30 13 1 8 9
M  V30 14 2 9 10
M  V30 15 1 10 6
M  V30 16 1 7 11
M  V30 17 2 11 12
M  V30 18 1 12 13
M  V30 19 2 13 14
M  V30 20 1 14 8
M  V30 21 2 15 16
M  V30 22 1 16 17
M  V30 23 2 17 18
M  V30 24 1 18 19
M  V30 25 2 19 20
M  V30 26 1 20 15
M  V30 27 1 19 21
M  V30 28 2 21 22
M  V30 29 1 22 23
M  V30 30 2 23 24
M  V30 31 1 24 20
M  V30 32 1 21 25
M  V30 33 2 25 26
M  V30 34 1 26 27
M  V30 35 2 27 28
M  V30 36 1 28 22
M  V30 37 10 11 29
M  V30 38 10 18 29
M  V30 39 10 4 29
M  V30 40 10 25 29
M  V30 END BOND
M  V30 BEGIN SGROUP
M  V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M  V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M  V30 BEL=CN
M  V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M  V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M  V30 BEL=CN
M  V30 END SGROUP
M  V30 END CTAB
M  END
</chemform>


=== Photosensitizer ===



<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
  -INDIGO-12072422152D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 59 68 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C -4.49166 0.079824 0.0 0
M  V30 2 C -4.06787 -0.62801 0.0 0
M  V30 3 C -3.24298 -0.614915 0.0 0
M  V30 4 N -2.84187 0.106013 0.0 0
M  V30 5 C -3.26566 0.813846 0.0 0
M  V30 6 C -4.09055 0.800752 0.0 0
M  V30 7 C -2.86455 1.53478 0.0 0
M  V30 8 C -3.28834 2.24261 0.0 0
M  V30 9 C -4.11323 2.22951 0.0 0
M  V30 10 C -4.51434 1.50859 0.0 0
M  V30 11 N -2.03965 1.54787 0.0 0
M  V30 12 C -1.63855 2.2688 0.0 0
M  V30 13 C -2.06233 2.97663 0.0 0
M  V30 14 C -2.88723 2.96354 0.0 0
M  V30 15 C 0.250331 2.98281 0.0 0
M  V30 16 C -0.574639 2.98991 0.0 0
M  V30 17 C -0.99328 2.27903 0.0 0
M  V30 18 N -0.586952 1.56103 0.0 0
M  V30 19 C 0.238017 1.55392 0.0 0
M  V30 20 C 0.656658 2.26481 0.0 0
M  V30 21 C 0.644346 0.835919 0.0 0
M  V30 22 C 1.46932 0.828809 0.0 0
M  V30 23 C 1.88796 1.5397 0.0 0
M  V30 24 C 1.48163 2.2577 0.0 0
M  V30 25 N 0.225704 0.125028 0.0 0
M  V30 26 C 0.632033 -0.59297 0.0 0
M  V30 27 C 1.457 -0.600079 0.0 0
M  V30 28 C 1.87564 0.110811 0.0 0
M  V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M  V30 30 C 0.325773 -2.28096 0.0 0
M  V30 31 C 0.741449 -1.56833 0.0 0
M  V30 32 C 0.332132 -0.852031 0.0 0
M  V30 33 N -0.49286 -0.848359 0.0 0
M  V30 34 C -0.908535 -1.56099 0.0 0
M  V30 35 C -0.499218 -2.27729 0.0 0
M  V30 36 C -1.73353 -1.55732 0.0 0
M  V30 37 C -2.1492 -2.26994 0.0 0
M  V30 38 C -1.73989 -2.98624 0.0 0
M  V30 39 C -0.914894 -2.98991 0.0 0
M  V30 40 N -2.14284 -0.841017 0.0 0
M  V30 41 C -2.96783 -0.837345 0.0 0
M  V30 42 C -3.38351 -1.54997 0.0 0
M  V30 43 C -2.97419 -2.26627 0.0 0
M  V30 44 P 3.56559 0.765939 0.0 0
M  V30 45 F 3.35207 -0.030949 0.0 0
M  V30 46 F 2.85112 1.17844 0.0 0
M  V30 47 F 4.14895 1.3493 0.0 0
M  V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M  V30 49 F 4.39059 0.765939 0.0 0
M  V30 50 F 2.7687 0.552413 0.0 0
M  V30 51 F 4.14895 0.182576 0.0 0
M  V30 52 P 3.68934 -1.58531 0.0 0
M  V30 53 F 3.47582 -2.3822 0.0 0
M  V30 54 F 2.97487 -1.17281 0.0 0
M  V30 55 F 4.27271 -1.00195 0.0 0
M  V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M  V30 57 F 4.51434 -1.58531 0.0 0
M  V30 58 F 2.89245 -1.79884 0.0 0
M  V30 59 F 4.27271 -2.16867 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 1 2
M  V30 2 1 2 3
M  V30 3 2 3 4
M  V30 4 1 4 5
M  V30 5 2 5 6
M  V30 6 1 6 1
M  V30 7 1 5 7
M  V30 8 2 7 8
M  V30 9 1 8 9
M  V30 10 2 9 10
M  V30 11 1 10 6
M  V30 12 1 7 11
M  V30 13 2 11 12
M  V30 14 1 12 13
M  V30 15 2 13 14
M  V30 16 1 14 8
M  V30 17 2 15 16
M  V30 18 1 16 17
M  V30 19 2 17 18
M  V30 20 1 18 19
M  V30 21 2 19 20
M  V30 22 1 20 15
M  V30 23 1 19 21
M  V30 24 2 21 22
M  V30 25 1 22 23
M  V30 26 2 23 24
M  V30 27 1 24 20
M  V30 28 1 21 25
M  V30 29 2 25 26
M  V30 30 1 26 27
M  V30 31 2 27 28
M  V30 32 1 28 22
M  V30 33 10 11 29
M  V30 34 10 18 29
M  V30 35 10 4 29
M  V30 36 10 25 29
M  V30 37 2 30 31
M  V30 38 1 31 32
M  V30 39 2 32 33
M  V30 40 1 33 34
M  V30 41 2 34 35
M  V30 42 1 35 30
M  V30 43 1 34 36
M  V30 44 2 36 37
M  V30 45 1 37 38
M  V30 46 2 38 39
M  V30 47 1 39 35
M  V30 48 1 36 40
M  V30 49 2 40 41
M  V30 50 1 41 42
M  V30 51 2 42 43
M  V30 52 1 43 37
M  V30 53 10 40 29
M  V30 54 10 33 29
M  V30 55 1 44 45
M  V30 56 1 44 46
M  V30 57 1 44 47
M  V30 58 1 44 48
M  V30 59 1 44 49
M  V30 60 1 44 50
M  V30 61 1 44 51
M  V30 62 1 52 53
M  V30 63 1 52 54
M  V30 64 1 52 55
M  V30 65 1 52 56
M  V30 66 1 52 57
M  V30 67 1 52 58
M  V30 68 1 52 59
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>

=== Investigation ===

{{#experimentlist:|form=Cyclic_Voltammetry_experiments|name=Table CO2 reduction|importFile=Import File.xlsx|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor .
====Additives====