Editing Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate

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{{#doiinfobox: 10.1021/jacs.0c08145}}

==== Catalyst====
<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1[S-]C2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none">
  -INDIGO-11282314122D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 30 37 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 3.92871 -7.18068 0.0 0
M  V30 2 N 5.77912 -7.18742 0.0 0
M  V30 3 C 4.81054 -6.73889 0.0 0
M  V30 4 C 5.65162 -8.10666 0.0 0
M  V30 5 C 3.87736 -8.0075 0.0 0
M  V30 6 C 4.65157 -8.50857 0.0 0
M  V30 7 C 4.80991 -5.98331 0.0 0
M  V30 8 N 4.0137 -5.46246 0.0 0
M  V30 9 C 4.2801 -4.64013 0.0 0
M  V30 10 C 5.259 -4.59864 0.0 0
M  V30 11 N 5.69533 -5.48533 0.0 0
M  V30 12 C 3.75867 -3.95526 0.0 0
M  V30 13 C 4.15256 -3.20166 0.0 0
M  V30 14 C 5.58883 -3.8962 0.0 0
M  V30 15 C 5.05569 -3.16467 0.0 0
M  V30 16 C 7.98564 -4.74873 0.0 0
M  V30 17 C 9.46403 -4.02754 0.0 0
M  V30 18 C 8.64118 -3.86203 0.0 0
M  V30 19 C 9.68906 -4.85978 0.0 0
M  V30 20 N 8.23234 -5.48611 0.0 0
M  V30 21 C 9.05042 -5.60839 0.0 0
M  V30 22 N 8.32236 -6.85273 0.0 0
M  V30 23 C 9.86571 -7.30043 0.0 0
M  V30 24 C 9.1513 -6.62716 0.0 0
M  V30 25 C 9.72525 -8.1515 0.0 0
M  V30 26 C 8.16095 -7.60143 0.0 0
M  V30 27 C 8.9122 -8.40358 0.0 0
M  V30 28 S 7.004 -4.94982 0.0 0 CHG=-1
M  V30 29 S 7.15093 -7.50667 0.0 0 CHG=-1
M  V30 30 Ni 7.08398 -6.24492 0.0 0 CHG=2
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 1 3 7
M  V30 8 1 7 8
M  V30 9 1 8 9
M  V30 10 2 9 10
M  V30 11 1 10 11
M  V30 12 2 11 7
M  V30 13 2 13 12
M  V30 14 1 10 14
M  V30 15 1 12 9
M  V30 16 2 14 15
M  V30 17 1 15 13
M  V30 18 2 18 16
M  V30 19 2 19 17
M  V30 20 1 16 20
M  V30 21 1 17 18
M  V30 22 2 20 21
M  V30 23 1 21 19
M  V30 24 2 24 22
M  V30 25 2 25 23
M  V30 26 1 22 26
M  V30 27 1 23 24
M  V30 28 2 26 27
M  V30 29 1 27 25
M  V30 30 1 16 28
M  V30 31 1 26 29
M  V30 32 10 20 30
M  V30 33 10 28 30
M  V30 34 10 11 30
M  V30 35 10 2 30
M  V30 36 10 22 30
M  V30 37 10 29 30
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C=CC=N2[Ni](N3=C(SC4C=CC=CC=43)C=12)1(N2C(S~1)=CC=CC=2)1N2C=CC=CC=2S~1" inchi="1S/C12H8N2S.2C5H5NS.Ni/c1-2-7-11-9(5-1)14-12(15-11)10-6-3-4-8-13-10;2*7-5-3-1-2-4-6-5;/h1-8H;2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="BDPUYSVREMMVBP-UHFFFAOYSA-L" height="200px" width="300px" float="none">
  -INDIGO-01252311232D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 30 37 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 4.11328 -6.99588 0.0 0
M  V30 2 N 5.97043 -6.96694 0.0 0
M  V30 3 C 5.06556 -6.51543 0.0 0
M  V30 4 C 5.83962 -7.95822 0.0 0
M  V30 5 C 4.04457 -7.85785 0.0 0
M  V30 6 C 4.80838 -8.37469 0.0 0
M  V30 7 N 8.53748 -6.34335 0.0 0
M  V30 8 C 10.0947 -6.56358 0.0 0
M  V30 9 C 9.28611 -6.01049 0.0 0
M  V30 10 C 10.0878 -7.47584 0.0 0
M  V30 11 C 8.46263 -7.17926 0.0 0
M  V30 12 C 9.29975 -7.86191 0.0 0
M  V30 13 C 9.72395 -4.21259 0.0 0
M  V30 14 N 8.38205 -4.95994 0.0 0
M  V30 15 C 9.17536 -4.97982 0.0 0
M  V30 16 C 8.08655 -4.2472 0.0 0
M  V30 17 C 9.46404 -3.43675 0.0 0
M  V30 18 C 8.6765 -3.34062 0.0 0
M  V30 19 C 5.01674 -5.7858 0.0 0
M  V30 20 S 4.32965 -5.22897 0.0 0
M  V30 21 C 4.62248 -4.40093 0.0 0
M  V30 22 C 5.63863 -4.4363 0.0 0
M  V30 23 N 5.96848 -5.24313 0.0 0
M  V30 24 C 4.18681 -3.69801 0.0 0
M  V30 25 C 4.65187 -2.96412 0.0 0
M  V30 26 C 5.99621 -3.7537 0.0 0
M  V30 27 C 5.57138 -2.99334 0.0 0
M  V30 28 S 7.16543 -4.54732 0.0 0
M  V30 29 S 7.45355 -7.19354 0.0 0
M  V30 30 Ni 7.28742 -5.90094 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 1 3 19
M  V30 20 1 19 20
M  V30 21 1 20 21
M  V30 22 2 21 22
M  V30 23 1 22 23
M  V30 24 2 23 19
M  V30 25 2 25 24
M  V30 26 1 22 26
M  V30 27 1 24 21
M  V30 28 2 26 27
M  V30 29 1 27 25
M  V30 30 1 16 28
M  V30 31 1 11 29
M  V30 32 8 29 30
M  V30 33 8 28 30
M  V30 34 10 14 30
M  V30 35 10 7 30
M  V30 36 10 2 30
M  V30 37 10 23 30
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>

====Photosensitizer====
{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L|image=true|width=500|height=300}}

====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}

==== Sacrificial electron donor====
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
[[Category:Photocatalytic CO2 conversion to HCOOH]]