Editing Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction

{{BaseTemplate}}
{{#doiinfobox: 10.1002/anie.201809084}}

==== Catalyst====
<chemform smiles="[Mo-2](=O)1(~SC2C3=NC4C=CC=CC=4N(C)C3OC(C)(C)C=2S~1)1~SC2C(C)(C)OC3N(C)C4C=CC=CC=4N=C3C=2S~1.[K+].[K+]" inchi="1S/2C14H16N2OS2.2K.Mo.O/c2*1-14(2)12(19)11(18)10-13(17-14)16(3)9-7-5-4-6-8(9)15-10;;;;/h2*4-7,13,18-19H,1-3H3;;;;/q;;2*+1;+2;/p-4" inchikey="ZANCFLAGIYSVGM-UHFFFAOYSA-J" height="200px" width="300px" float="none">
  -INDIGO-01242316062D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 42 47 0 0 0
M  V30 BEGIN ATOM
M  V30 1 Mo 9.1 -6.375 0.0 0 CHG=-2
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M  V30 3 S 9.96603 -5.875 0.0 0
M  V30 4 S 8.23397 -6.875 0.0 0
M  V30 5 S 9.96603 -6.875 0.0 0
M  V30 6 C 5.60985 -5.85007 0.0 0
M  V30 7 C 7.34015 -5.84959 0.0 0
M  V30 8 C 6.47664 -5.34997 0.0 0
M  V30 9 C 7.34015 -6.85053 0.0 0
M  V30 10 O 5.60985 -6.85502 0.0 0
M  V30 11 C 6.47882 -7.35003 0.0 0
M  V30 12 N 4.74634 -5.35045 0.0 0
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M  V30 14 N 6.47664 -4.34502 0.0 0
M  V30 15 C 5.60767 -3.85001 0.0 0
M  V30 16 C 3.88606 -3.8543 0.0 0
M  V30 17 C 3.88386 -2.85839 0.0 0
M  V30 18 C 5.60545 -2.85011 0.0 0
M  V30 19 C 4.73976 -2.3595 0.0 0
M  V30 20 C 5.77171 -8.05714 0.0 0
M  V30 21 C 6.97882 -8.21606 0.0 0
M  V30 22 C 3.88008 -5.85005 0.0 0
M  V30 23 O 9.1 -5.375 0.0 0
M  V30 24 C 12.5774 -6.855 0.0 0
M  V30 25 C 10.8447 -6.85549 0.0 0
M  V30 26 C 11.7094 -7.35581 0.0 0
M  V30 27 C 10.8447 -5.85314 0.0 0
M  V30 28 O 12.5774 -5.84865 0.0 0
M  V30 29 C 11.7073 -5.35294 0.0 0
M  V30 30 N 13.4422 -7.35532 0.0 0
M  V30 31 C 13.4422 -8.35767 0.0 0
M  V30 32 N 11.7094 -8.36216 0.0 0
M  V30 33 C 12.5796 -8.85787 0.0 0
M  V30 34 C 14.3036 -8.85357 0.0 0
M  V30 35 C 14.3058 -9.85087 0.0 0
M  V30 36 C 12.5818 -9.85916 0.0 0
M  V30 37 C 13.4487 -10.3505 0.0 0
M  V30 38 C 12.4153 -4.64485 0.0 0
M  V30 39 C 11.2066 -4.48571 0.0 0
M  V30 40 C 14.3096 -6.85503 0.0 0
M  V30 41 K 9.1 -3.425 0.0 0 CHG=1
M  V30 42 K 9.125 -3.925 0.0 0 CHG=1
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 8 1 2
M  V30 2 8 1 3
M  V30 3 8 1 4
M  V30 4 8 1 5
M  V30 5 1 8 6
M  V30 6 2 9 7
M  V30 7 1 6 10
M  V30 8 1 7 8
M  V30 9 1 10 11
M  V30 10 1 11 9
M  V30 11 1 13 12
M  V30 12 2 8 14
M  V30 13 1 12 6
M  V30 14 1 14 15
M  V30 15 2 15 13
M  V30 16 2 17 16
M  V30 17 1 15 18
M  V30 18 1 16 13
M  V30 19 2 18 19
M  V30 20 1 19 17
M  V30 21 1 7 2
M  V30 22 1 9 4
M  V30 23 1 11 20
M  V30 24 1 11 21
M  V30 25 1 12 22
M  V30 26 2 1 23
M  V30 27 1 26 24
M  V30 28 2 27 25
M  V30 29 1 24 28
M  V30 30 1 25 26
M  V30 31 1 28 29
M  V30 32 1 29 27
M  V30 33 1 31 30
M  V30 34 2 26 32
M  V30 35 1 30 24
M  V30 36 1 32 33
M  V30 37 2 33 31
M  V30 38 2 35 34
M  V30 39 1 33 36
M  V30 40 1 34 31
M  V30 41 2 36 37
M  V30 42 1 37 35
M  V30 43 1 29 38
M  V30 44 1 29 39
M  V30 45 1 30 40
M  V30 46 1 3 27
M  V30 47 1 5 25
M  V30 END BOND
M  V30 END CTAB
M  END
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  -INDIGO-01242316142D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 63 69 6 0 0
M  V30 BEGIN ATOM
M  V30 1 N 17.45 -0.225 0.0 0 CHG=1
M  V30 2 C 17.45 0.775 0.0 0
M  V30 3 C 17.1227 1.71991 0.0 0
M  V30 4 C 17.7773 2.47582 0.0 0
M  V30 5 C 17.45 3.42073 0.0 0
M  V30 6 C 16.45 -0.225 0.0 0
M  V30 7 C 17.45 -1.225 0.0 0
M  V30 8 C 18.45 -0.225 0.0 0
M  V30 9 C 19.3949 0.102337 0.0 0
M  V30 10 C 20.1508 -0.55234 0.0 0
M  V30 11 C 21.0957 -0.225 0.0 0
M  V30 12 C 17.7773 -2.16991 0.0 0
M  V30 13 C 17.1227 -2.92582 0.0 0
M  V30 14 C 17.45 -3.87073 0.0 0
M  V30 15 C 15.5051 -0.55234 0.0 0
M  V30 16 C 14.7492 0.102337 0.0 0
M  V30 17 C 13.8043 -0.225 0.0 0
M  V30 18 Mo 9.4 -6.05 0.0 0 CHG=-1
M  V30 19 S 10.266 -5.55 0.0 0
M  V30 20 S 8.53397 -6.55 0.0 0
M  V30 21 S 8.53397 -5.55 0.0 0
M  V30 22 S 10.266 -6.55 0.0 0
M  V30 23 O 9.4 -5.05 0.0 0
M  V30 24 C 5.65985 -5.65007 0.0 0
M  V30 25 C 7.39015 -5.64959 0.0 0
M  V30 26 C 6.52664 -5.14997 0.0 0
M  V30 27 C 7.39015 -6.65053 0.0 0
M  V30 28 O 5.65985 -6.65502 0.0 0
M  V30 29 C 6.52882 -7.15003 0.0 0
M  V30 30 N 6.52694 -4.14923 0.0 0
M  V30 31 C 5.66045 -3.6486 0.0 0
M  V30 32 C 4.79366 -4.14871 0.0 0
M  V30 33 N 4.79336 -5.14945 0.0 0
M  V30 34 C 3.93015 -3.64909 0.0 0
M  V30 35 C 3.93015 -2.64814 0.0 0
M  V30 36 C 5.66045 -2.64366 0.0 0
M  V30 37 C 4.79148 -2.14864 0.0 0
M  V30 38 C 5.82171 -7.85714 0.0 0
M  V30 39 C 7.23593 -7.85714 0.0 0
M  V30 40 C 3.92734 -5.64945 0.0 0
M  V30 41 C 7.39296 -3.64923 0.0 0
M  V30 42 C 7.39302 -2.6492 0.0 0
M  V30 43 O 8.25895 -4.14924 0.0 0
M  V30 44 C 13.0574 -6.61528 0.0 0
M  V30 45 C 11.3274 -6.61576 0.0 0
M  V30 46 C 12.1908 -7.11532 0.0 0
M  V30 47 C 11.3274 -5.61495 0.0 0
M  V30 48 O 13.0574 -5.61046 0.0 0
M  V30 49 C 12.1886 -5.11552 0.0 0
M  V30 50 N 12.1904 -8.11592 0.0 0
M  V30 51 C 13.0568 -8.61649 0.0 0
M  V30 52 C 13.9235 -8.11644 0.0 0
M  V30 53 N 13.9238 -7.11584 0.0 0
M  V30 54 C 14.7869 -8.616 0.0 0
M  V30 55 C 14.7869 -9.61681 0.0 0
M  V30 56 C 13.0568 -9.6213 0.0 0
M  V30 57 C 13.9257 -10.1162 0.0 0
M  V30 58 C 12.8956 -4.4085 0.0 0
M  V30 59 C 11.4816 -4.4085 0.0 0
M  V30 60 C 14.7897 -6.61591 0.0 0
M  V30 61 C 11.3245 -8.61586 0.0 0
M  V30 62 C 11.3245 -9.61575 0.0 0
M  V30 63 O 10.4587 -8.11591 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 2 1 2 3
M  V30 3 1 3 4
M  V30 4 1 4 5
M  V30 5 1 1 6
M  V30 6 1 1 7
M  V30 7 1 1 8
M  V30 8 1 8 9
M  V30 9 1 9 10
M  V30 10 1 10 11
M  V30 11 1 7 12
M  V30 12 1 12 13
M  V30 13 1 13 14
M  V30 14 1 6 15
M  V30 15 1 15 16
M  V30 16 1 16 17
M  V30 17 8 18 19
M  V30 18 8 18 20
M  V30 19 8 18 21
M  V30 20 8 18 22
M  V30 21 2 18 23
M  V30 22 1 26 24
M  V30 23 2 27 25
M  V30 24 1 24 28
M  V30 25 1 25 26
M  V30 26 1 28 29
M  V30 27 1 29 27
M  V30 28 1 26 30
M  V30 29 1 30 31
M  V30 30 2 31 32
M  V30 31 1 32 33
M  V30 32 1 33 24
M  V30 33 2 35 34
M  V30 34 1 31 36
M  V30 35 1 34 32
M  V30 36 2 36 37
M  V30 37 1 37 35
M  V30 38 1 29 38
M  V30 39 1 29 39
M  V30 40 1 33 40
M  V30 41 1 30 41
M  V30 42 1 42 41
M  V30 43 2 41 43
M  V30 44 1 46 44
M  V30 45 2 47 45
M  V30 46 1 44 48
M  V30 47 1 45 46
M  V30 48 1 48 49
M  V30 49 1 49 47
M  V30 50 1 46 50
M  V30 51 1 50 51
M  V30 52 2 51 52
M  V30 53 1 52 53
M  V30 54 1 53 44
M  V30 55 2 55 54
M  V30 56 1 51 56
M  V30 57 1 54 52
M  V30 58 2 56 57
M  V30 59 1 57 55
M  V30 60 1 49 58
M  V30 61 1 49 59
M  V30 62 1 53 60
M  V30 63 1 50 61
M  V30 64 1 62 61
M  V30 65 2 61 63
M  V30 66 1 25 21
M  V30 67 1 27 20
M  V30 68 1 22 45
M  V30 69 1 19 47
M  V30 END BOND
M  V30 BEGIN SGROUP
M  V30 1 SUP 1 ATOMS=(4 2 3 4 5) BRKXYZ=(9 0.000000 0.000000 0.000000 0.00000-
M  V30 0 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) -
M  V30 LABEL=Bu
M  V30 2 SUP 2 ATOMS=(4 8 9 10 11) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000-
M  V30 000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0-
M  V30 .000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000-
M  V30 ) LABEL=Bu
M  V30 3 SUP 3 ATOMS=(4 7 12 13 14) BRKXYZ=(9 0.000000 0.000000 0.000000 0.00-
M  V30 0000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.00000-
M  V30 0) LABEL=Bu
M  V30 4 SUP 4 ATOMS=(4 6 15 16 17) BRKXYZ=(9 0.000000 0.000000 0.000000 0.00-
M  V30 0000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.00000-
M  V30 0) LABEL=Bu
M  V30 5 SUP 5 ATOMS=(3 41 42 43) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000)-
M  V30  LABEL=Ac
M  V30 6 SUP 6 ATOMS=(3 61 62 63) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000)-
M  V30  LABEL=Ac
M  V30 END SGROUP
M  V30 END CTAB
M  END
</chemform><chemform smiles="[Mo-2](=O)1(~SC2C3=NC4C=CC=CC=4N=C3OC(C)(C)C=2S~1)1~SC2C(C)(C)OC3=NC4C=CC=CC=4N=C3C=2S~1.[N+](CCCC)(CCCC)(CCCC)CCCC.[N+](CCCC)(CCCC)(CCCC)CCCC" inchi="1S/2C16H36N.2C13H12N2OS2.Mo.O/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-13(2)11(18)10(17)9-12(16-13)15-8-6-4-3-5-7(8)14-9;;/h2*5-16H2,1-4H3;2*3-6,17-18H,1-2H3;;/q2*+1;;;+2;/p-4" inchikey="IGLNGZFBERTREK-UHFFFAOYSA-J" height="200px" width="300px" float="none">
  -INDIGO-01242316192D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 72 77 8 0 0
M  V30 BEGIN ATOM
M  V30 1 Mo 8.675 -5.8 0.0 0 CHG=-2
M  V30 2 S 7.80897 -5.3 0.0 0
M  V30 3 S 9.54103 -5.3 0.0 0
M  V30 4 S 7.80897 -6.3 0.0 0
M  V30 5 S 9.54103 -6.3 0.0 0
M  V30 6 C 5.13485 -5.32507 0.0 0
M  V30 7 C 6.86515 -5.32459 0.0 0
M  V30 8 C 6.00164 -4.82497 0.0 0
M  V30 9 C 6.86515 -6.32553 0.0 0
M  V30 10 O 5.13485 -6.33002 0.0 0
M  V30 11 C 6.00382 -6.82503 0.0 0
M  V30 12 N 6.00194 -3.82423 0.0 0
M  V30 13 C 5.13545 -3.3236 0.0 0
M  V30 14 C 4.26866 -3.82371 0.0 0
M  V30 15 N 4.26836 -4.82445 0.0 0
M  V30 16 C 3.40515 -3.32409 0.0 0
M  V30 17 C 3.40515 -2.32314 0.0 0
M  V30 18 C 5.13545 -2.31866 0.0 0
M  V30 19 C 4.26648 -1.82364 0.0 0
M  V30 20 C 5.29671 -7.53214 0.0 0
M  V30 21 C 6.71093 -7.53214 0.0 0
M  V30 22 C 12.1924 -6.27275 0.0 0
M  V30 23 C 10.4624 -6.27323 0.0 0
M  V30 24 C 11.3258 -6.77278 0.0 0
M  V30 25 C 10.4624 -5.27245 0.0 0
M  V30 26 O 12.1924 -5.26797 0.0 0
M  V30 27 C 11.3236 -4.77303 0.0 0
M  V30 28 N 11.3255 -7.77335 0.0 0
M  V30 29 C 12.1918 -8.2739 0.0 0
M  V30 30 C 13.0585 -7.77387 0.0 0
M  V30 31 N 13.0588 -6.7733 0.0 0
M  V30 32 C 13.9219 -8.27341 0.0 0
M  V30 33 C 13.9219 -9.2742 0.0 0
M  V30 34 C 12.1918 -9.27868 0.0 0
M  V30 35 C 13.0607 -9.77362 0.0 0
M  V30 36 C 12.0306 -4.06604 0.0 0
M  V30 37 C 10.6166 -4.06604 0.0 0
M  V30 38 O 8.675 -4.8 0.0 0
M  V30 39 N 17.475 -1.825 0.0 0 CHG=1
M  V30 40 C 17.475 -2.825 0.0 0
M  V30 41 C 16.475 -1.825 0.0 0
M  V30 42 C 17.475 -0.825 0.0 0
M  V30 43 C 18.475 -1.825 0.0 0
M  V30 44 C 16.5301 -3.15234 0.0 0
M  V30 45 C 15.7742 -2.49766 0.0 0
M  V30 46 C 14.8293 -2.825 0.0 0
M  V30 47 C 15.5301 -2.15234 0.0 0
M  V30 48 C 14.7742 -1.49766 0.0 0
M  V30 49 C 13.8293 -1.825 0.0 0
M  V30 50 C 19.4199 -1.49766 0.0 0
M  V30 51 C 20.1758 -2.15234 0.0 0
M  V30 52 C 21.1207 -1.825 0.0 0
M  V30 53 C 17.1477 0.119908 0.0 0
M  V30 54 C 17.8023 0.87582 0.0 0
M  V30 55 C 17.475 1.82073 0.0 0
M  V30 56 N 17.475 -6.9 0.0 0 CHG=1
M  V30 57 C 17.475 -7.9 0.0 0
M  V30 58 C 16.475 -6.9 0.0 0
M  V30 59 C 17.475 -5.9 0.0 0
M  V30 60 C 18.475 -6.9 0.0 0
M  V30 61 C 17.8023 -8.84491 0.0 0
M  V30 62 C 17.1477 -9.60082 0.0 0
M  V30 63 C 17.475 -10.5457 0.0 0
M  V30 64 C 17.1477 -4.95509 0.0 0
M  V30 65 C 17.8023 -4.19918 0.0 0
M  V30 66 C 17.475 -3.25427 0.0 0
M  V30 67 C 15.5301 -7.22734 0.0 0
M  V30 68 C 14.7742 -6.57266 0.0 0
M  V30 69 C 13.8293 -6.9 0.0 0
M  V30 70 C 19.4199 -6.57266 0.0 0
M  V30 71 C 20.1758 -7.22734 0.0 0
M  V30 72 C 21.1207 -6.9 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 8 1 2
M  V30 2 8 1 3
M  V30 3 8 1 4
M  V30 4 8 1 5
M  V30 5 1 8 6
M  V30 6 2 9 7
M  V30 7 1 6 10
M  V30 8 1 7 8
M  V30 9 1 10 11
M  V30 10 1 11 9
M  V30 11 2 8 12
M  V30 12 1 12 13
M  V30 13 2 13 14
M  V30 14 1 14 15
M  V30 15 2 15 6
M  V30 16 2 17 16
M  V30 17 1 13 18
M  V30 18 1 16 14
M  V30 19 2 18 19
M  V30 20 1 19 17
M  V30 21 1 11 20
M  V30 22 1 11 21
M  V30 23 1 24 22
M  V30 24 2 25 23
M  V30 25 1 22 26
M  V30 26 1 23 24
M  V30 27 1 26 27
M  V30 28 1 27 25
M  V30 29 2 24 28
M  V30 30 1 28 29
M  V30 31 2 29 30
M  V30 32 1 30 31
M  V30 33 2 31 22
M  V30 34 2 33 32
M  V30 35 1 29 34
M  V30 36 1 32 30
M  V30 37 2 34 35
M  V30 38 1 35 33
M  V30 39 1 27 36
M  V30 40 1 27 37
M  V30 41 1 7 2
M  V30 42 1 9 4
M  V30 43 1 5 23
M  V30 44 1 3 25
M  V30 45 2 1 38
M  V30 46 1 39 40
M  V30 47 1 39 41
M  V30 48 1 39 42
M  V30 49 1 39 43
M  V30 50 1 40 44
M  V30 51 1 44 45
M  V30 52 1 45 46
M  V30 53 1 41 47
M  V30 54 1 47 48
M  V30 55 1 48 49
M  V30 56 1 43 50
M  V30 57 1 50 51
M  V30 58 1 51 52
M  V30 59 1 42 53
M  V30 60 1 53 54
M  V30 61 1 54 55
M  V30 62 1 56 57
M  V30 63 1 56 58
M  V30 64 1 56 59
M  V30 65 1 56 60
M  V30 66 1 57 61
M  V30 67 1 61 62
M  V30 68 1 62 63
M  V30 69 1 59 64
M  V30 70 1 64 65
M  V30 71 1 65 66
M  V30 72 1 58 67
M  V30 73 1 67 68
M  V30 74 1 68 69
M  V30 75 1 60 70
M  V30 76 1 70 71
M  V30 77 1 71 72
M  V30 END BOND
M  V30 BEGIN SGROUP
M  V30 1 SUP 1 ATOMS=(4 40 44 45 46) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 2 SUP 2 ATOMS=(4 41 47 48 49) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 3 SUP 3 ATOMS=(4 43 50 51 52) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 4 SUP 4 ATOMS=(4 42 53 54 55) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 5 SUP 5 ATOMS=(4 57 61 62 63) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 6 SUP 6 ATOMS=(4 59 64 65 66) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 7 SUP 7 ATOMS=(4 58 67 68 69) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 8 SUP 8 ATOMS=(4 60 70 71 72) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M  V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M  V30  0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M  V30 00) LABEL=Bu
M  V30 END SGROUP
M  V30 END CTAB
M  END
</chemform>

====Photosensitizer====
{{#moleculelink: |link=CLNINCHTGNZSOI-UHFFFAOYSA-N|image=true}}

====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}

==== Sacrificial electron donor====
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
[[Category:Photocatalytic CO2 conversion to HCOOH]]