Editing Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts

{{#doiinfobox: 10.1021/jacs.8b10619}}
[[Category:Photocatalytic CO2 conversion to HCOOH]]
{{BaseTemplate}}

{{MissingMolecule
|date=2023-03-10
|author=ChN
}}

==== Investigation ====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}

==== Catalyst ====
<chemform smiles="C([*])1C=C2C3N([Mn+](C#O)(C#O)(C#O)([Br-])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe">
  -INDIGO-02132315572D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 22 24 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 4.75985 -3.47507 0.0 0
M  V30 2 C 6.49015 -3.47459 0.0 0
M  V30 3 C 5.62664 -2.97497 0.0 0
M  V30 4 N 6.49015 -4.47553 0.0 0
M  V30 5 C 4.75985 -4.48002 0.0 0
M  V30 6 C 5.62882 -4.97503 0.0 0
M  V30 7 C 4.75985 -6.42507 0.0 0
M  V30 8 N 6.49015 -6.42459 0.0 0
M  V30 9 C 5.62664 -5.92497 0.0 0
M  V30 10 C 6.49015 -7.42553 0.0 0
M  V30 11 C 4.75985 -7.43002 0.0 0
M  V30 12 C 5.62882 -7.92503 0.0 0
M  V30 13 Mn 7.55 -5.475 0.0 0 CHG=1
M  V30 14 Br 7.55 -4.475 0.0 0 CHG=-1
M  V30 15 C 8.41603 -4.975 0.0 0
M  V30 16 C 8.41603 -5.975 0.0 0
M  V30 17 C 7.55 -6.475 0.0 0
M  V30 18 O 7.55 -7.475 0.0 0
M  V30 19 O 9.28205 -6.475 0.0 0
M  V30 20 O 9.28205 -4.475 0.0 0
M  V30 21 R# 3.89382 -2.97507 0.0 0 RGROUPS=(1 1)
M  V30 22 R# 3.89382 -7.93002 0.0 0 RGROUPS=(1 1)
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 1 6 9
M  V30 14 10 4 13
M  V30 15 10 8 13
M  V30 16 10 13 14
M  V30 17 10 13 15
M  V30 18 10 13 16
M  V30 19 10 13 17
M  V30 20 3 17 18
M  V30 21 3 16 19
M  V30 22 3 15 20
M  V30 23 1 1 21
M  V30 24 1 11 22
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C=C2C3C=CC=C(C4C(C)=CC(C)=CC=4C)N=3[Mn](C#O)(C#O)(~Br)N2=C(C2C(C)=CC(C)=CC=2C)C=1" inchi="1S/C28H28N2.2CHO.BrH.Mn/c1-17-13-19(3)27(20(4)14-17)25-11-7-9-23(29-25)24-10-8-12-26(30-24)28-21(5)15-18(2)16-22(28)6;2*1-2;;/h7-16H,1-6H3;2*1H;1H;/q;;;;+1/p-1" inchikey="LAJRVYLSNAAJQU-UHFFFAOYSA-M" height="200px" width="300px" float="none">
  -INDIGO-03102311002D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 36 40 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 4.73485 -2.97507 0.0 0
M  V30 2 C 6.46515 -2.97459 0.0 0
M  V30 3 C 5.60164 -2.47497 0.0 0
M  V30 4 N 6.46515 -3.97553 0.0 0
M  V30 5 C 4.73485 -3.98002 0.0 0
M  V30 6 C 5.60382 -4.47503 0.0 0
M  V30 7 C 5.60768 -5.47503 0.0 0
M  V30 8 C 6.47425 -6.97269 0.0 0
M  V30 9 N 6.47451 -5.97505 0.0 0
M  V30 10 C 5.60775 -7.47374 0.0 0
M  V30 11 C 4.73771 -5.97808 0.0 0
M  V30 12 C 4.74417 -6.97814 0.0 0
M  V30 13 C 7.33141 -2.47499 0.0 0
M  V30 14 C 7.34038 -7.47251 0.0 0
M  V30 15 C 9.07068 -7.47086 0.0 0
M  V30 16 C 8.20683 -6.97182 0.0 0
M  V30 17 C 9.07135 -8.47181 0.0 0
M  V30 18 C 7.34106 -8.47746 0.0 0
M  V30 19 C 8.21036 -8.97189 0.0 0
M  V30 20 C 8.19513 -0.975685 0.0 0
M  V30 21 C 7.33103 -1.47428 0.0 0
M  V30 22 C 9.06231 -1.47558 0.0 0
M  V30 23 C 8.20205 -2.97688 0.0 0
M  V30 24 C 9.06489 -2.47126 0.0 0
M  V30 25 C 6.46497 -0.974331 0.0 0
M  V30 26 C 9.92752 -0.974162 0.0 0
M  V30 27 C 8.20562 -3.97688 0.0 0
M  V30 28 C 8.20677 -5.97182 0.0 0
M  V30 29 C 6.47682 -8.98054 0.0 0
M  V30 30 C 9.93819 -8.97039 0.0 0
M  V30 31 Mn 7.7 -4.95 0.0 0
M  V30 32 Br 7.7 -3.95 0.0 0
M  V30 33 C 8.56603 -4.45 0.0 0
M  V30 34 C 8.56603 -5.45 0.0 0
M  V30 35 O 9.43205 -3.95 0.0 0
M  V30 36 O 9.43205 -5.95 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 1 6 7
M  V30 8 2 9 7
M  V30 9 2 10 8
M  V30 10 1 7 11
M  V30 11 1 8 9
M  V30 12 2 11 12
M  V30 13 1 12 10
M  V30 14 1 2 13
M  V30 15 1 8 14
M  V30 16 2 16 14
M  V30 17 2 17 15
M  V30 18 1 14 18
M  V30 19 1 15 16
M  V30 20 2 18 19
M  V30 21 1 19 17
M  V30 22 2 21 13
M  V30 23 2 22 20
M  V30 24 1 13 23
M  V30 25 1 20 21
M  V30 26 2 23 24
M  V30 27 1 24 22
M  V30 28 1 21 25
M  V30 29 1 22 26
M  V30 30 1 23 27
M  V30 31 1 16 28
M  V30 32 1 18 29
M  V30 33 1 17 30
M  V30 34 10 4 31
M  V30 35 10 9 31
M  V30 36 8 31 32
M  V30 37 10 31 33
M  V30 38 10 31 34
M  V30 39 3 33 35
M  V30 40 3 34 36
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>

==== Photosensitizer ====
<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform>