09:46:02 1792571 PublicationImportJob - prompt for AI: [SYSTEM-LIKE INSTRUCTIONS] You are a highly conservative scientific information extractor and formatter. Your primary goal is factual fidelity to the attached article. You must extract only what is explicitly supported by the article. Never guess, reconstruct, or “complete” missing scientific data from general chemistry knowledge. When a value is unclear, ambiguous, inconsistent, or not explicitly stated, output "not reported". Core extraction policy: - Correctness is more important than completeness. - Unit normalization must be exact. - Never confuse catalyst, photosensitizer, sacrificial electron donor, solvent, additive, proton source, irradiation wavelength, or product metric. - Values should only be converted when the article provides a clear and scientifically reliable basis for conversion. - Never infer absolute concentrations from mol% unless the absolute concentration is explicitly stated. - Never infer TON CO from yield, selectivity, graph shape, or discussion text unless the TON CO value itself is explicitly reported or unambiguously readable. - Never replace a wavelength range with a single wavelength. - Never merge data across figures, tables, or sections unless the article clearly shows that they refer to the same experiment. - Never include bibliographic metadata in the output. Formatting policy: - Follow the requested section titles exactly. - Output only the requested final formatted content. - Use "not reported" for unsupported entries. - Do not mention uncertainty analysis, self-checking, or extraction workflow in the final answer. Before finalizing, silently verify: - catalyst concentration is in µM - photosensitizer concentration is in mM - electron donor concentration is in M - excitation wavelength is in nm - TON CO refers only to CO - no unsupported claim has been added - no bibliographic metadata is present [TASK] Read the attached scientific article and convert it into a structured educational chemistry wiki entry about a molecular photocatalytic CO2 reduction system. TASK Produce a scientifically accurate, teaching-oriented summary in MediaWiki format for advanced undergraduate chemistry students. Focus strictly on the chemistry, mechanism, photocatalytic setup, components, and reported results. CONTENT RESTRICTIONS - Use only information explicitly supported by the attached article. - Do NOT include author names, affiliations, journal name, year, DOI, citation labels, references, page numbers, or any publication metadata. - Do NOT speculate. - Do NOT fill missing values from chemical intuition or standard literature practice. - Whenever a requested value is missing, ambiguous, or not explicitly reported, write: "not reported". STYLE REQUIREMENTS - Use proper MediaWiki markup. - Use accessible but precise scientific language. - Keep the explanation educational, technically correct, and chemically specific. - Avoid unnecessary jargon, but do not oversimplify. - Distinguish clearly between established experimental observations and proposed mechanistic interpretation. OUTPUT REQUIREMENTS - Return only the final MediaWiki-formatted entry. - Use exactly the section headings below, in exactly the same order. - Do not add extra sections. - The final section, "Investigation", must contain CSV data inside a plain fenced code block. Use exactly this structure: == Abstract Summary == Provide a concise overview of the scientific goal, the photocatalytic system, and the main findings. State what was converted, what kind of photocatalytic system was used, and what the main outcome was. == Advances and Special Progress == Explain the key scientific advances compared with earlier molecular photocatalytic CO2 reduction systems. Focus on scientifically meaningful progress such as: - higher activity, - improved CO selectivity, - improved compatibility with water or mixed solvents, - unusual catalyst design, - mechanistic insight, - improved durability, - use of earth-abundant components, - unusual electron-transfer design, - better coupling between catalyst and photosensitizer. Only mention advances that are supported by the article itself. == Additional Remarks == Provide important contextual remarks relevant to the chemistry and significance of the work. Examples may include: - sustainability relevance of CO2-to-CO photoreduction, - strengths and limitations of sacrificial photochemical systems, - dependence on noble-metal photosensitizers, - solvent limitations, - water tolerance, - competition with H2 evolution, - catalyst decomposition, - low long-term durability, - mechanistic elegance versus practical limitations. Keep this section balanced, factual, and chemically relevant. == Content of the Published Article in Detail == Write a clear, teaching-oriented explanation of the scientific content of the article. Include, where supported by the article: - the molecular components of the system, - how the photocatalytic experiment is set up, - what happens after light absorption by the photosensitizer, - whether reductive or oxidative quenching is proposed, - how the sacrificial electron donor participates, - how electrons are transferred to the catalyst, - what reduced catalyst states are proposed or observed, - how CO2 activation and reduction are described, - how CO is formed and released, - whether proton transfer is involved, - what side products are observed or suppressed, - what control experiments or spectroscopic/electrochemical studies support the mechanism. Mechanistic explanation rules: - Explain the mechanism in words. - Be chemically accurate. - Distinguish proposed intermediates from directly observed intermediates. - Use cautious wording where appropriate, such as "the article proposes" or "the data support". - Do not overstate mechanistic certainty. Possible supporting evidence may include: - Stern-Volmer quenching, - emission quenching, - transient absorption, - UV/Vis spectroscopy, - cyclic voltammetry, - spectroelectrochemistry, - control experiments omitting one component, - atmosphere controls, - product analysis, - catalyst comparison studies. == Catalyst == Describe the catalyst in a compact but chemically informative way. Include only details explicitly supported by the article, such as: - exact catalyst identity, - catalyst class, - metal center, - oxidation state if stated, - ligand family or coordination environment, - whether it is mononuclear, dinuclear, supramolecular, macrocyclic, polypyridyl, porphyrinic, or another named class, - whether it is molecular, immobilized, or heterogeneous, - catalytic role in CO2 reduction, - special redox or structural properties relevant to function, - selectivity-related features, - stability or decomposition issues relevant to performance. Do not invent structural details beyond what the article actually states or names. == Photosensitizer == Describe the photosensitizer in the same style. Include only details explicitly supported by the article, such as: - exact identity, - photosensitizer class, - light-harvesting role, - excited-state function, - whether it undergoes reductive or oxidative quenching, - relevant redox or photophysical properties if explicitly discussed, - why it is suitable in this system, - any stability or photobleaching issues if reported. If multiple photosensitizers are compared, identify the main one clearly and mention others only when relevant data are reported. == Investigation == Provide the core photocatalytic experiments as ONE fenced code block that starts with ```csv and ends with ```. The block must be plain CSV — no markdown table, no JSON, no text before or after it inside the block. The header row MUST be EXACTLY these columns, in this order: catalyst , cat conc , PS , PS conc , e-D , e-D conc , solvent A , solvent B , solvent C , solvent-ratio , additives , additives conc , feedstock gas , intensity , pH , Temperature , λexc , irr time , Turnover_number__CO , Turnover_frequency__CO , Quantum_yield__CO , Turnover_number__CH4 , Turnover_number__H2 , Turnover_frequency__H2 , Turnover_number__HCOOH , Turnover_frequency__HCOOH , Quantum_yield__HCOOH , H-D , H-D conc Extraction rules for the CSV: - One row per distinct experimental condition explicitly reported. Take the main photocatalytic performance table first, and add control / condition-variation rows when they are explicitly reported. Include EVERY distinct experiment — do not summarise or collapse rows. - Report numbers as bare values (no unit text) in exactly these units, converting only when the article gives a clear basis: cat conc = µM; PS conc = mM; e-D conc = M; H-D conc = M; Temperature = °C; λexc = nm; irr time = h; Turnover_frequency__* = h^-1; Quantum_yield__* = %. - catalyst, PS (photosensitizer), e-D (sacrificial electron donor), H-D (hydrogen/proton donor): use the identity (name or abbreviation) exactly as given in the article. Keep names consistent across rows. Never swap catalyst, photosensitizer, electron donor, hydrogen donor, solvent, or additive. - Turnover_number__X, Turnover_frequency__X, Quantum_yield__X are per product X (CO, CH4, H2, HCOOH). Put each product's value in its own column; never substitute CO yield, selectivity, total TON, or a value read from a graph. - For a solvent mixture, give solvent A/B/C and the ratio in solvent-ratio (for example 4:1). Keep additives out of the solvent fields. - Keep a wavelength range as a range (for example 420-650); a monochromatic source is a single nm value. - Leave a cell EMPTY only when the article does not state the value. Never invent, guess, reconstruct, or infer a value from general knowledge, figures, or discussion — every value must be explicitly supported by the article. - Do NOT use a value that appears only in the supporting information unless the main text also states it. - Never put a comma inside a cell (commas separate columns); use a space or a slash instead. - Do not add, remove, rename, or reorder columns. Before output, silently verify: section headings match exactly; no bibliographic metadata; units are as specified above; catalyst and photosensitizer are not swapped; no unsupported value was added; one row per distinct experiment. Return only the final MediaWiki entry with the CSV code block in the Investigation section. [OUTPUT SECTIONS - MANDATORY, emit ALL of them in this exact order, each as a wiki heading with substantive content (≥20 words)] == Abstract Summary == == Advances and Special Progress == == Additional Remarks == == Content of the Published Article in Detail == == Catalyst == == Photosensitizer == == Investigation == The Investigation section must contain ONE fenced ```csv block with the header below as its first row. [OUTPUT FORMAT — INVESTIGATION CSV] Output the experiments as ONE fenced code block that starts with ```csv and ends with ```. The header row MUST be EXACTLY these columns, in this order: catalyst , cat conc , PS , PS conc , e-D , e-D conc , solvent A , solvent B , solvent-ratio , feedstock gas , Temperature , λexc , irr time , Turnover_number__CO , Turnover_frequency__CO , Turnover_number__H2 , Turnover_frequency__H2 , additives , Turnover_number__HCOOH , intensity , Turnover_number__CH4 , additives conc , Quantum_yield__CO , H-D , H-D conc , solvent C , Quantum_yield__HCOOH One row per distinct experiment; one value per cell; leave a cell empty only if the paper does not state it. 09:46:06 1792571 AIClient - Uploaded file: SI_6a4768b3e21fb.pdf, id: file-JNvw3wpSmUDARy3dxpB525 09:46:08 1792571 AIClient - Uploaded file: Ferreira Jr. et al. - 2026 - Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO_6a4768b3e3707.pdf, id: file-JCp3joAbycvnM4r4p7CTKU 09:46:08 1792571 AIClient - Request to AI with prompt: '[SYSTEM-LIKE INSTRUCTIONS] You are a highly conservative scientific information extractor and formatter. Your primary goal is factual fidelity to the attached article. You must extract only what is explicitly supported by the article. Never guess, reconstruct, or “complete” missing scientific data from general chemistry knowledge. When a value is unclear, ambiguous, inconsistent, or not explicitly stated, output "not reported". Core extraction policy: - Correctness is more important than completeness. - Unit normalization must be exact. - Never confuse catalyst, photosensitizer, sacrificial electron donor, solvent, additive, proton source, irradiation wavelength, or product metric. - Values should only be converted when the article provides a clear and scientifically reliable basis for conversion. - Never infer absolute concentrations from mol% unless the absolute concentration is explicitly stated. - Never infer TON CO from yield, selectivity, graph shape, or discussion text unless the TON CO value itself is explicitly reported or unambiguously readable. - Never replace a wavelength range with a single wavelength. - Never merge data across figures, tables, or sections unless the article clearly shows that they refer to the same experiment. - Never include bibliographic metadata in the output. Formatting policy: - Follow the requested section titles exactly. - Output only the requested final formatted content. - Use "not reported" for unsupported entries. - Do not mention uncertainty analysis, self-checking, or extraction workflow in the final answer. Before finalizing, silently verify: - catalyst concentration is in µM - photosensitizer concentration is in mM - electron donor concentration is in M - excitation wavelength is in nm - TON CO refers only to CO - no unsupported claim has been added - no bibliographic metadata is present [TASK] Read the attached scientific article and convert it into a structured educational chemistry wiki entry about a molecular photocatalytic CO2 reduction system. TASK Produce a scientifically accurate, teaching-oriented summary in MediaWiki format for advanced undergraduate chemistry students. Focus strictly on the chemistry, mechanism, photocatalytic setup, components, and reported results. CONTENT RESTRICTIONS - Use only information explicitly supported by the attached article. - Do NOT include author names, affiliations, journal name, year, DOI, citation labels, references, page numbers, or any publication metadata. - Do NOT speculate. - Do NOT fill missing values from chemical intuition or standard literature practice. - Whenever a requested value is missing, ambiguous, or not explicitly reported, write: "not reported". STYLE REQUIREMENTS - Use proper MediaWiki markup. - Use accessible but precise scientific language. - Keep the explanation educational, technically correct, and chemically specific. - Avoid unnecessary jargon, but do not oversimplify. - Distinguish clearly between established experimental observations and proposed mechanistic interpretation. OUTPUT REQUIREMENTS - Return only the final MediaWiki-formatted entry. - Use exactly the section headings below, in exactly the same order. - Do not add extra sections. - The final section, "Investigation", must contain CSV data inside a plain fenced code block. Use exactly this structure: == Abstract Summary == Provide a concise overview of the scientific goal, the photocatalytic system, and the main findings. State what was converted, what kind of photocatalytic system was used, and what the main outcome was. == Advances and Special Progress == Explain the key scientific advances compared with earlier molecular photocatalytic CO2 reduction systems. Focus on scientifically meaningful progress such as: - higher activity, - improved CO selectivity, - improved compatibility with water or mixed solvents, - unusual catalyst design, - mechanistic insight, - improved durability, - use of earth-abundant components, - unusual electron-transfer design, - better coupling between catalyst and photosensitizer. Only mention advances that are supported by the article itself. == Additional Remarks == Provide important contextual remarks relevant to the chemistry and significance of the work. Examples may include: - sustainability relevance of CO2-to-CO photoreduction, - strengths and limitations of sacrificial photochemical systems, - dependence on noble-metal photosensitizers, - solvent limitations, - water tolerance, - competition with H2 evolution, - catalyst decomposition, - low long-term durability, - mechanistic elegance versus practical limitations. Keep this section balanced, factual, and chemically relevant. == Content of the Published Article in Detail == Write a clear, teaching-oriented explanation of the scientific content of the article. Include, where supported by the article: - the molecular components of the system, - how the photocatalytic experiment is set up, - what happens after light absorption by the photosensitizer, - whether reductive or oxidative quenching is proposed, - how the sacrificial electron donor participates, - how electrons are transferred to the catalyst, - what reduced catalyst states are proposed or observed, - how CO2 activation and reduction are described, - how CO is formed and released, - whether proton transfer is involved, - what side products are observed or suppressed, - what control experiments or spectroscopic/electrochemical studies support the mechanism. Mechanistic explanation rules: - Explain the mechanism in words. - Be chemically accurate. - Distinguish proposed intermediates from directly observed intermediates. - Use cautious wording where appropriate, such as "the article proposes" or "the data support". - Do not overstate mechanistic certainty. Possible supporting evidence may include: - Stern-Volmer quenching, - emission quenching, - transient absorption, - UV/Vis spectroscopy, - cyclic voltammetry, - spectroelectrochemistry, - control experiments omitting one component, - atmosphere controls, - product analysis, - catalyst comparison studies. == Catalyst == Describe the catalyst in a compact but chemically informative way. Include only details explicitly supported by the article, such as: - exact catalyst identity, - catalyst class, - metal center, - oxidation state if stated, - ligand family or coordination environment, - whether it is mononuclear, dinuclear, supramolecular, macrocyclic, polypyridyl, porphyrinic, or another named class, - whether it is molecular, immobilized, or heterogeneous, - catalytic role in CO2 reduction, - special redox or structural properties relevant to function, - selectivity-related features, - stability or decomposition issues relevant to performance. Do not invent structural details beyond what the article actually states or names. == Photosensitizer == Describe the photosensitizer in the same style. Include only details explicitly supported by the article, such as: - exact identity, - photosensitizer class, - light-harvesting role, - excited-state function, - whether it undergoes reductive or oxidative quenching, - relevant redox or photophysical properties if explicitly discussed, - why it is suitable in this system, - any stability or photobleaching issues if reported. If multiple photosensitizers are compared, identify the main one clearly and mention others only when relevant data are reported. == Investigation == Provide the core photocatalytic experiments as ONE fenced code block that starts with ```csv and ends with ```. The block must be plain CSV — no markdown table, no JSON, no text before or after it inside the block. The header row MUST be EXACTLY these columns, in this order: catalyst , cat conc , PS , PS conc , e-D , e-D conc , solvent A , solvent B , solvent C , solvent-ratio , additives , additives conc , feedstock gas , intensity , pH , Temperature , λexc , irr time , Turnover_number__CO , Turnover_frequency__CO , Quantum_yield__CO , Turnover_number__CH4 , Turnover_number__H2 , Turnover_frequency__H2 , Turnover_number__HCOOH , Turnover_frequency__HCOOH , Quantum_yield__HCOOH , H-D , H-D conc Extraction rules for the CSV: - One row per distinct experimental condition explicitly reported. Take the main photocatalytic performance table first, and add control / condition-variation rows when they are explicitly reported. Include EVERY distinct experiment — do not summarise or collapse rows. - Report numbers as bare values (no unit text) in exactly these units, converting only when the article gives a clear basis: cat conc = µM; PS conc = mM; e-D conc = M; H-D conc = M; Temperature = °C; λexc = nm; irr time = h; Turnover_frequency__* = h^-1; Quantum_yield__* = %. - catalyst, PS (photosensitizer), e-D (sacrificial electron donor), H-D (hydrogen/proton donor): use the identity (name or abbreviation) exactly as given in the article. Keep names consistent across rows. Never swap catalyst, photosensitizer, electron donor, hydrogen donor, solvent, or additive. - Turnover_number__X, Turnover_frequency__X, Quantum_yield__X are per product X (CO, CH4, H2, HCOOH). Put each product's value in its own column; never substitute CO yield, selectivity, total TON, or a value read from a graph. - For a solvent mixture, give solvent A/B/C and the ratio in solvent-ratio (for example 4:1). Keep additives out of the solvent fields. - Keep a wavelength range as a range (for example 420-650); a monochromatic source is a single nm value. - Leave a cell EMPTY only when the article does not state the value. Never invent, guess, reconstruct, or infer a value from general knowledge, figures, or discussion — every value must be explicitly supported by the article. - Do NOT use a value that appears only in the supporting information unless the main text also states it. - Never put a comma inside a cell (commas separate columns); use a space or a slash instead. - Do not add, remove, rename, or reorder columns. Before output, silently verify: section headings match exactly; no bibliographic metadata; units are as specified above; catalyst and photosensitizer are not swapped; no unsupported value was added; one row per distinct experiment. Return only the final MediaWiki entry with the CSV code block in the Investigation section. [OUTPUT SECTIONS - MANDATORY, emit ALL of them in this exact order, each as a wiki heading with substantive content (≥20 words)] == Abstract Summary == == Advances and Special Progress == == Additional Remarks == == Content of the Published Article in Detail == == Catalyst == == Photosensitizer == == Investigation == The Investigation section must contain ONE fenced ```csv block with the header below as its first row. [OUTPUT FORMAT — INVESTIGATION CSV] Output the experiments as ONE fenced code block that starts with ```csv and ends with ```. The header row MUST be EXACTLY these columns, in this order: catalyst , cat conc , PS , PS conc , e-D , e-D conc , solvent A , solvent B , solvent-ratio , feedstock gas , Temperature , λexc , irr time , Turnover_number__CO , Turnover_frequency__CO , Turnover_number__H2 , Turnover_frequency__H2 , additives , Turnover_number__HCOOH , intensity , Turnover_number__CH4 , additives conc , Quantum_yield__CO , H-D , H-D conc , solvent C , Quantum_yield__HCOOH One row per distinct experiment; one value per cell; leave a cell empty only if the paper does not state it.' and documents [file-JNvw3wpSmUDARy3dxpB525file-JCp3joAbycvnM4r4p7CTKU] 09:47:08 1792571 AIClient - Response from AI: == Abstract Summary == This article describes a visible-light-driven ''molecular'' photocatalytic system for reducing CO2 to CO using iron(II) bis(pyrazolyl)phenanthroline complexes as homogeneous catalysts. The catalyst series Fe1-Fe4 was combined with [Ru(bpy)3]2+ as photosensitizer and BIH as sacrificial electron donor in CO2-saturated MeCN/H2O. All four iron complexes were active for CO2-to-CO photoreduction. Fe2 gave the highest overall activity in the standard comparison experiments, while Fe4 gave the highest CO selectivity in that series. Under lower catalyst loading, Fe2 reached a much higher turnover number for CO, and the system operated with substantial CO selectivity in mixed aqueous organic solvent. The article also supports a homogeneous catalytic pathway and identifies photosensitizer deterioration as a major cause of deactivation. == Advances and Special Progress == A central advance is the introduction of a new family of ''iron(II) bis(pyrazolyl)phenanthroline'' molecular catalysts for visible-light CO2 photoreduction. The article presents this ligand platform as distinct from more commonly studied iron polypyridyl and salophen-type systems, allowing systematic comparison of substituent effects on catalytic behavior. The work also reports strong performance at very low catalyst loading. For Fe2, decreasing the catalyst concentration increased the CO turnover number substantially, reaching 23,138 under the lowest loading explicitly reported in the main text. The article identifies this as one of the stronger performances among molecular iron-based photocatalytic CO2-to-CO systems discussed in the paper. Another important advance is the demonstrated compatibility with water-containing solvent mixtures. The system was studied in MeCN/H2O, and the article shows that 7.5-10% water is essential for efficient catalysis and high CO selectivity. This is chemically significant because water both enables proton-coupled steps and competes with H2 evolution. The paper also provides mechanistic insight through combined photophysical, electrochemical, and computational analysis. Stern-Volmer quenching measurements, cyclic voltammetry, orbital analysis, and atmosphere-dependent electrochemistry support a mechanism in which the excited photosensitizer is quenched primarily by BIH, reduced iron species become accessible within the photosensitizer redox window, and single-electron-reduced catalyst states are implicated in CO2 activation. Durability was examined in a chemically informative way. The activity loss over time was linked mainly to degradation of [Ru(bpy)3]2+, not primarily to catalyst destruction, and replenishing the photosensitizer restored CO production. Mercury poisoning tests further supported the conclusion that catalysis remains homogeneous rather than nanoparticle-driven. == Additional Remarks == The chemistry is significant because CO2-to-CO photoreduction stores reducing equivalents in a useful C1 product. CO is a valuable synthetic intermediate, but selective photochemical formation is challenging because proton reduction to H2 competes strongly under many conditions. This system uses an earth-abundant catalytic metal center, iron, which is an advantage from a sustainability perspective. However, the photochemical system still depends on a ruthenium photosensitizer and a sacrificial electron donor, so it is not a fully sustainable closed-cycle solar fuel system. The article shows both strengths and limitations of sacrificial molecular photocatalysis. Strengths include clear molecular design, high CO selectivity, tunable ligand effects, and useful mechanistic observables. Limitations include reliance on BIH, sensitivity to photosensitizer degradation, and finite long-term durability under continuous irradiation. The role of water is chemically important but also highlights practical tradeoffs. Too little water suppresses productive CO2 reduction, while too much water lowers activity. The article attributes the decline at higher water content partly to limited BIH solubility and reduced efficiency of excited-state quenching. The study is mechanistically informative because it distinguishes supported observations from interpretation. Product analysis, control experiments, mercury poisoning, Stern-Volmer quenching, UV/Vis changes, and cyclic voltammetry directly support the main conclusions, whereas specific catalyst intermediates in the CO2 reduction sequence are proposed rather than directly isolated. == Content of the Published Article in Detail == The molecular photocatalytic system contains three main functional components: an iron(II) bis(pyrazolyl)phenanthroline complex as CO2 reduction catalyst, [Ru(bpy)3]2+ as visible-light photosensitizer, and BIH as sacrificial electron donor. The reaction medium is CO2-saturated MeCN/H2O in a sealed borosilicate photoreactor irradiated with blue light at 462 nm. Gas products were analyzed from the headspace by gas chromatography. The iron complexes Fe1-Fe4 are mononuclear Fe(II) species with tetradentate bis(pyrazolyl)phenanthroline ligands and two water ligands. Magnetic measurements and calculations support high-spin Fe(II) ground states. The article states that all complexes are active for photocatalytic CO2 reduction to CO, with H2 as the main competing side product. No significant formate or CH4 was detected. The optical role is assigned to [Ru(bpy)3]2+. Upon light absorption, the article discusses the excited metal-to-ligand charge-transfer state of the ruthenium photosensitizer. Quenching experiments and orbital-energy analysis were used to determine how this excited state interacts with BIH and the iron complexes. The mechanistic interpretation supported by the article is that ''reductive quenching by BIH is dominant''. Stern-Volmer experiments showed that BIH quenches the emission of [Ru(bpy)3]2+ much more efficiently than Fe1-Fe4. The reported quenching constant for BIH is about one order of magnitude larger than for the iron complexes. The article therefore supports the view that BIH primarily reduces the excited photosensitizer, generating a reduced ruthenium species capable of transferring electrons onward. The article also evaluates possible oxidative quenching by the iron catalysts. Based on the calculated energy-level alignment, the SOMO energies of Fe1-Fe4 do not favor reductive quenching of the excited photosensitizer by the iron complexes, but the SUMO levels lie below the photosensitizer LUMO, making oxidative quenching energetically feasible. Even so, the quenching data show BIH to be the dominant quencher under the studied conditions. Electrochemical data are used to connect photophysics to catalysis. Cyclic voltammetry showed two reduction waves for the iron complexes in acetonitrile. The article interprets these reductions as predominantly ''ligand-centered'' rather than formal Fe(II)/Fe(I)/Fe(0) metal-centered reductions, based on DFT orbital composition and correlation between calculated orbital energies and electrochemical potentials. Within the potential window accessible to reduced [Ru(bpy)3]+, the first reduction event is sufficiently stable to be chemically relevant. The article states that reduced iron species formed after single-electron reduction react with CO2. Under CO2 atmosphere, cyclic voltammograms differed from those under Ar, with progressive changes in current response and peak shape during repeated scans. These observations support the conclusion that the reduced iron complexes interact with CO2 to form catalytic intermediates that are not re-oxidized within the applied scan window. The paper does not report direct spectroscopic observation of a specific bound CO2 intermediate during photocatalysis, but it discusses catalyst reduction followed by CO2 activation as the productive pathway. It further states that water is essential for effective proton-coupled electron transfer and stabilization of intermediates. In particular, the absence of water nearly suppresses CO formation, while 7.5-10% water strongly increases activity and selectivity. For Fe4, the article proposes a structural feature that may contribute to selectivity: hydrogen-bonding interactions between coordinated water ligands and CF3-substituent fluorine atoms distort the coordination environment and may help proton management near the metal center. This is presented as an interpretation linked to its high CO selectivity, not as directly observed catalytic turnover chemistry. Control experiments strongly support the full photocatalytic assignment. Removing light, catalyst, photosensitizer, sacrificial donor, or CO2 suppressed productive CO formation. Replacing the molecular iron complex with Fe(ClO4)2 gave only minor amounts of CO and H2, showing that free Fe2+ is not responsible for the catalytic behavior. The article also addresses whether the active species are homogeneous or nanoparticulate. Mercury poisoning experiments did not suppress catalytic CO formation, and this is taken as evidence against catalysis by colloidal or heterogeneous metal particles. The authors therefore conclude that the active system is homogeneous. Catalyst lifetime was investigated indirectly through time-dependent product formation and UV/Vis monitoring. Activity rose strongly at early times and then approached a plateau. The article attributes most of this deactivation to deterioration of [Ru(bpy)3]2+, supported by hypochromism in the UV/Vis spectra of the reaction mixture over time. When fresh photosensitizer was added after 24 h, CO production resumed and the turnover number increased further, supporting the idea that the catalyst remains largely intact while the photosensitizer degrades. Overall, the data support the following chemistry in words: light excites [Ru(bpy)3]2+; BIH predominantly quenches the excited state reductively; the reduced photosensitizer transfers electrons to the iron catalyst; a singly reduced iron complex is implicated in CO2 activation; proton-coupled electron transfer steps in the presence of water lead to CO formation; H2 is the main side product; and the catalyst functions homogeneously under the reported conditions. == Catalyst == The catalysts are a series of ''molecular homogeneous mononuclear iron(II) bis(pyrazolyl)phenanthroline complexes'' labeled Fe1-Fe4. Their formulations are reported as [Fe(bpzRphen)(H2O)2]X2, where the bis(pyrazolyl)phenanthroline ligand bears different pyrazolyl substituents and X is BF4- or ClO4-. The article describes them as high-spin Fe(II) complexes with distorted octahedral geometries. The tetradentate bis(pyrazolyl)phenanthroline ligand occupies four coordination sites, and two water ligands occupy the remaining positions. The complexes are used as ''CO2 reduction catalysts'' in a homogeneous visible-light photocatalytic system. Their redox behavior is reported to be mainly ligand-centered. This is relevant because electron uptake by the catalyst appears to occur on the coordinated ligand framework while still enabling catalytically relevant reduced states that react with CO2. Catalyst performance depends on ligand substitution. In the standard 24 h comparison at 50 μM catalyst loading, Fe2 gave the highest CO activity, while Fe4 gave the highest CO selectivity. Fe4 also showed a structurally distinctive distortion associated with possible intramolecular hydrogen-bonding interactions involving coordinated water and CF3 substituents, which the article suggests may be linked to selectivity. Regarding stability, the article concludes that the catalysts are robust enough to remain active in solution and that major deactivation is due mainly to photosensitizer deterioration rather than catalyst failure. Mercury poisoning tests also support the conclusion that the catalysis is homogeneous rather than nanoparticle-based. == Photosensitizer == The photosensitizer is ''[Ru(bpy)3]2+''. It serves as the visible-light absorber and initiates the photoredox sequence upon irradiation at 462 nm. The article discusses its excited metal-to-ligand charge-transfer state as the relevant photoactive state. Photophysical measurements show that this excited state is quenched by both BIH and the iron complexes, but BIH is the more efficient quencher. The article therefore supports a mechanism in which [Ru(bpy)3]2+* is quenched primarily ''reductively'' by BIH, producing a reduced ruthenium species that can transfer electrons to the iron catalyst. The photosensitizer is chemically suitable here because its reduced form is sufficiently reducing to access the first catalyst reduction event. Electrochemical analysis explicitly compares the catalyst reduction window with the potential of the ruthenium couple. A major limitation is stability under prolonged irradiation. The article reports photodegradation of [Ru(bpy)3]2+, observed as hypochromism in UV/Vis spectra of the reaction mixture. Replenishment of the photosensitizer after 24 h restored catalytic CO production, identifying photosensitizer deterioration as a main cause of deactivation. == Investigation == ```csv catalyst , cat conc , PS , PS conc , e-D , e-D conc , solvent A , solvent B , solvent C , solvent-ratio , additives , additives conc , feedstock gas , intensity , pH , Temperature , λexc , irr time , Turnover_number__CO , Turnover_frequency__CO , Quantum_yield__CO , Turnover_number__CH4 , Turnover_number__H2 , Turnover_frequency__H2 , Turnover_number__HCOOH , Turnover_frequency__HCOOH , Quantum_yield__HCOOH , H-D , H-D conc Fe1 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 987 , 41.1 , , , 187 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 1318 , 54.9 , , , 243 , , , , , H2O , not reported Fe3 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 847 , 35.3 , , , 205 , , , , , H2O , not reported Fe4 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 1265 , 52.7 , , , 133 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 4 , 311 , 77.7 , , , 51 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 48 , 1578 , 32.9 , , , 296 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 96 , 1593 , 16.6 , , , 300 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , , , 100:0 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 2 , not reported , , , 22 , , , , , , Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 90:10 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 1352 , 56.3 , , , 285 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 70:30 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 661 , 27.5 , , , 191 , , , , , H2O , not reported Fe2 , 50 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 50:50 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 621 , 25.8 , , , 77 , , , , , H2O , not reported Fe2 , 25 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 2086 , 86.9 , , , 123 , , , , , H2O , not reported Fe2 , 12.5 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 4259 , 177.4 , , , 276 , , , , , H2O , not reported Fe2 , 6.25 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 10168 , 423.7 , , , 862 , , , , , H2O , not reported Fe2 , 3.12 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 24 , 23138 , 964.1 , , , 2177 , , , , , H2O , not reported Fe2 , 3.12 , [Ru(bpy)3]2+ , 0.3 , BIH , 0.11 , MeCN , H2O , , 92.5:7.5 , , , CO2 , not reported , not reported , 35 , 462 , 4 , 9754 , 2438 , 8.24 , , 3310 , , , , , H2O , not reported ``` 09:47:09 1792571 PublicationImportJob - created investigation page: Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light - 2026.07.03/inv0 09:47:09 1792571 PublicationImportJob - generated text from AI: Imported from: /opt/uploadtmp/SI_6a4768b3e21fb.pdf, /opt/uploadtmp/Ferreira Jr. et al. - 2026 - Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO_6a4768b3e3707.pdf {{BaseTemplate}} {{DOI|doi=10.1016/j.jcat.2026.116673-2026.07.03}} == Abstract Summary == This article describes a visible-light-driven ''molecular'' photocatalytic system for reducing CO2 to CO using iron(II) bis(pyrazolyl)phenanthroline complexes as homogeneous catalysts. The catalyst series Fe1-Fe4 was combined with [Ru(bpy)3]2+ as photosensitizer and BIH as sacrificial electron donor in CO2-saturated MeCN/H2O. All four iron complexes were active for CO2-to-CO photoreduction. Fe2 gave the highest overall activity in the standard comparison experiments, while Fe4 gave the highest CO selectivity in that series. Under lower catalyst loading, Fe2 reached a much higher turnover number for CO, and the system operated with substantial CO selectivity in mixed aqueous organic solvent. The article also supports a homogeneous catalytic pathway and identifies photosensitizer deterioration as a major cause of deactivation. == Advances and Special Progress == A central advance is the introduction of a new family of ''iron(II) bis(pyrazolyl)phenanthroline'' molecular catalysts for visible-light CO2 photoreduction. The article presents this ligand platform as distinct from more commonly studied iron polypyridyl and salophen-type systems, allowing systematic comparison of substituent effects on catalytic behavior. The work also reports strong performance at very low catalyst loading. For Fe2, decreasing the catalyst concentration increased the CO turnover number substantially, reaching 23,138 under the lowest loading explicitly reported in the main text. The article identifies this as one of the stronger performances among molecular iron-based photocatalytic CO2-to-CO systems discussed in the paper. Another important advance is the demonstrated compatibility with water-containing solvent mixtures. The system was studied in MeCN/H2O, and the article shows that 7.5-10% water is essential for efficient catalysis and high CO selectivity. This is chemically significant because water both enables proton-coupled steps and competes with H2 evolution. The paper also provides mechanistic insight through combined photophysical, electrochemical, and computational analysis. Stern-Volmer quenching measurements, cyclic voltammetry, orbital analysis, and atmosphere-dependent electrochemistry support a mechanism in which the excited photosensitizer is quenched primarily by BIH, reduced iron species become accessible within the photosensitizer redox window, and single-electron-reduced catalyst states are implicated in CO2 activation. Durability was examined in a chemically informative way. The activity loss over time was linked mainly to degradation of [Ru(bpy)3]2+, not primarily to catalyst destruction, and replenishing the photosensitizer restored CO production. Mercury poisoning tests further supported the conclusion that catalysis remains homogeneous rather than nanoparticle-driven. == Additional Remarks == The chemistry is significant because CO2-to-CO photoreduction stores reducing equivalents in a useful C1 product. CO is a valuable synthetic intermediate, but selective photochemical formation is challenging because proton reduction to H2 competes strongly under many conditions. This system uses an earth-abundant catalytic metal center, iron, which is an advantage from a sustainability perspective. However, the photochemical system still depends on a ruthenium photosensitizer and a sacrificial electron donor, so it is not a fully sustainable closed-cycle solar fuel system. The article shows both strengths and limitations of sacrificial molecular photocatalysis. Strengths include clear molecular design, high CO selectivity, tunable ligand effects, and useful mechanistic observables. Limitations include reliance on BIH, sensitivity to photosensitizer degradation, and finite long-term durability under continuous irradiation. The role of water is chemically important but also highlights practical tradeoffs. Too little water suppresses productive CO2 reduction, while too much water lowers activity. The article attributes the decline at higher water content partly to limited BIH solubility and reduced efficiency of excited-state quenching. The study is mechanistically informative because it distinguishes supported observations from interpretation. Product analysis, control experiments, mercury poisoning, Stern-Volmer quenching, UV/Vis changes, and cyclic voltammetry directly support the main conclusions, whereas specific catalyst intermediates in the CO2 reduction sequence are proposed rather than directly isolated. == Content of the Published Article in Detail == The molecular photocatalytic system contains three main functional components: an iron(II) bis(pyrazolyl)phenanthroline complex as CO2 reduction catalyst, [Ru(bpy)3]2+ as visible-light photosensitizer, and BIH as sacrificial electron donor. The reaction medium is CO2-saturated MeCN/H2O in a sealed borosilicate photoreactor irradiated with blue light at 462 nm. Gas products were analyzed from the headspace by gas chromatography. The iron complexes Fe1-Fe4 are mononuclear Fe(II) species with tetradentate bis(pyrazolyl)phenanthroline ligands and two water ligands. Magnetic measurements and calculations support high-spin Fe(II) ground states. The article states that all complexes are active for photocatalytic CO2 reduction to CO, with H2 as the main competing side product. No significant formate or CH4 was detected. The optical role is assigned to [Ru(bpy)3]2+. Upon light absorption, the article discusses the excited metal-to-ligand charge-transfer state of the ruthenium photosensitizer. Quenching experiments and orbital-energy analysis were used to determine how this excited state interacts with BIH and the iron complexes. The mechanistic interpretation supported by the article is that ''reductive quenching by BIH is dominant''. Stern-Volmer experiments showed that BIH quenches the emission of [Ru(bpy)3]2+ much more efficiently than Fe1-Fe4. The reported quenching constant for BIH is about one order of magnitude larger than for the iron complexes. The article therefore supports the view that BIH primarily reduces the excited photosensitizer, generating a reduced ruthenium species capable of transferring electrons onward. The article also evaluates possible oxidative quenching by the iron catalysts. Based on the calculated energy-level alignment, the SOMO energies of Fe1-Fe4 do not favor reductive quenching of the excited photosensitizer by the iron complexes, but the SUMO levels lie below the photosensitizer LUMO, making oxidative quenching energetically feasible. Even so, the quenching data show BIH to be the dominant quencher under the studied conditions. Electrochemical data are used to connect photophysics to catalysis. Cyclic voltammetry showed two reduction waves for the iron complexes in acetonitrile. The article interprets these reductions as predominantly ''ligand-centered'' rather than formal Fe(II)/Fe(I)/Fe(0) metal-centered reductions, based on DFT orbital composition and correlation between calculated orbital energies and electrochemical potentials. Within the potential window accessible to reduced [Ru(bpy)3]+, the first reduction event is sufficiently stable to be chemically relevant. The article states that reduced iron species formed after single-electron reduction react with CO2. Under CO2 atmosphere, cyclic voltammograms differed from those under Ar, with progressive changes in current response and peak shape during repeated scans. These observations support the conclusion that the reduced iron complexes interact with CO2 to form catalytic intermediates that are not re-oxidized within the applied scan window. The paper does not report direct spectroscopic observation of a specific bound CO2 intermediate during photocatalysis, but it discusses catalyst reduction followed by CO2 activation as the productive pathway. It further states that water is essential for effective proton-coupled electron transfer and stabilization of intermediates. In particular, the absence of water nearly suppresses CO formation, while 7.5-10% water strongly increases activity and selectivity. For Fe4, the article proposes a structural feature that may contribute to selectivity: hydrogen-bonding interactions between coordinated water ligands and CF3-substituent fluorine atoms distort the coordination environment and may help proton management near the metal center. This is presented as an interpretation linked to its high CO selectivity, not as directly observed catalytic turnover chemistry. Control experiments strongly support the full photocatalytic assignment. Removing light, catalyst, photosensitizer, sacrificial donor, or CO2 suppressed productive CO formation. Replacing the molecular iron complex with Fe(ClO4)2 gave only minor amounts of CO and H2, showing that free Fe2+ is not responsible for the catalytic behavior. The article also addresses whether the active species are homogeneous or nanoparticulate. Mercury poisoning experiments did not suppress catalytic CO formation, and this is taken as evidence against catalysis by colloidal or heterogeneous metal particles. The authors therefore conclude that the active system is homogeneous. Catalyst lifetime was investigated indirectly through time-dependent product formation and UV/Vis monitoring. Activity rose strongly at early times and then approached a plateau. The article attributes most of this deactivation to deterioration of [Ru(bpy)3]2+, supported by hypochromism in the UV/Vis spectra of the reaction mixture over time. When fresh photosensitizer was added after 24 h, CO production resumed and the turnover number increased further, supporting the idea that the catalyst remains largely intact while the photosensitizer degrades. Overall, the data support the following chemistry in words: light excites [Ru(bpy)3]2+; BIH predominantly quenches the excited state reductively; the reduced photosensitizer transfers electrons to the iron catalyst; a singly reduced iron complex is implicated in CO2 activation; proton-coupled electron transfer steps in the presence of water lead to CO formation; H2 is the main side product; and the catalyst functions homogeneously under the reported conditions. == Catalyst == The catalysts are a series of ''molecular homogeneous mononuclear iron(II) bis(pyrazolyl)phenanthroline complexes'' labeled Fe1-Fe4. Their formulations are reported as [Fe(bpzRphen)(H2O)2]X2, where the bis(pyrazolyl)phenanthroline ligand bears different pyrazolyl substituents and X is BF4- or ClO4-. The article describes them as high-spin Fe(II) complexes with distorted octahedral geometries. The tetradentate bis(pyrazolyl)phenanthroline ligand occupies four coordination sites, and two water ligands occupy the remaining positions. The complexes are used as ''CO2 reduction catalysts'' in a homogeneous visible-light photocatalytic system. Their redox behavior is reported to be mainly ligand-centered. This is relevant because electron uptake by the catalyst appears to occur on the coordinated ligand framework while still enabling catalytically relevant reduced states that react with CO2. Catalyst performance depends on ligand substitution. In the standard 24 h comparison at 50 μM catalyst loading, Fe2 gave the highest CO activity, while Fe4 gave the highest CO selectivity. Fe4 also showed a structurally distinctive distortion associated with possible intramolecular hydrogen-bonding interactions involving coordinated water and CF3 substituents, which the article suggests may be linked to selectivity. Regarding stability, the article concludes that the catalysts are robust enough to remain active in solution and that major deactivation is due mainly to photosensitizer deterioration rather than catalyst failure. Mercury poisoning tests also support the conclusion that the catalysis is homogeneous rather than nanoparticle-based. == Photosensitizer == The photosensitizer is ''[Ru(bpy)3]2+''. It serves as the visible-light absorber and initiates the photoredox sequence upon irradiation at 462 nm. The article discusses its excited metal-to-ligand charge-transfer state as the relevant photoactive state. Photophysical measurements show that this excited state is quenched by both BIH and the iron complexes, but BIH is the more efficient quencher. The article therefore supports a mechanism in which [Ru(bpy)3]2+* is quenched primarily ''reductively'' by BIH, producing a reduced ruthenium species that can transfer electrons to the iron catalyst. The photosensitizer is chemically suitable here because its reduced form is sufficiently reducing to access the first catalyst reduction event. Electrochemical analysis explicitly compares the catalyst reduction window with the potential of the ruthenium couple. A major limitation is stability under prolonged irradiation. The article reports photodegradation of [Ru(bpy)3]2+, observed as hypochromism in UV/Vis spectra of the reaction mixture. Replenishment of the photosensitizer after 24 h restored catalytic CO production, identifying photosensitizer deterioration as a main cause of deactivation. == Investigation == {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=inv0}} [[Category:Photocatalytic CO2 conversion]] 09:47:13 1792571 AIClient - File deleted from OpenAI repo: file-JNvw3wpSmUDARy3dxpB525 09:47:13 1792571 AIClient - File deleted from OpenAI repo: file-JCp3joAbycvnM4r4p7CTKU 17:00:04 1810996 AIClient - Request to AI with prompt: 'please check if the given text is spam. answer with yes or no.' and documents [Imported from: /opt/uploadtmp/SI_6a4768b3e21fb.pdf, /opt/uploadtmp/Ferreira Jr. et al. - 2026 - Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO_6a4768b3e3707.pdf DOI could not be found: 10.1016/j.jcat.2026.116673-2026.07.03 Contents 1 Abstract Summary 2 Advances and Special Progress 3 Additional Remarks 4 Content of the Published Article in Detail 5 Catalyst 6 Photosensitizer 7 Investigation Abstract Summary[edit | edit source] This article describes a visible-light-driven molecular photocatalytic system for reducing CO2 to CO using iron(II) bis(pyrazolyl)phenanthroline complexes as homogeneous catalysts. The catalyst series Fe1-Fe4 was combined with [Ru(bpy)3]2+ as photosensitizer and BIH as sacrificial electron donor in CO2-saturated MeCN/H2O. All four iron complexes were active for CO2-to-CO photoreduction. Fe2 gave the highest overall activity in the standard comparison experiments, while Fe4 gave the highest CO selectivity in that series. Under lower catalyst loading, Fe2 reached a much higher turnover number for CO, and the system operated with substantial CO selectivity in mixed aqueous organic solvent. The article also supports a homogeneous catalytic pathway and identifies photosensitizer deterioration as a major cause of deactivation. Advances and Special Progress[edit | edit source] A central advance is the introduction of a new family of iron(II) bis(pyrazolyl)phenanthroline molecular catalysts for visible-light CO2 photoreduction. The article presents this ligand platform as distinct from more commonly studied iron polypyridyl and salophen-type systems, allowing systematic comparison of substituent effects on catalytic behavior. The work also reports strong performance at very low catalyst loading. For Fe2, decreasing the catalyst concentration increased the CO turnover number substantially, reaching 23,138 under the lowest loading explicitly reported in the main text. The article identifies this as one of the stronger performances among molecular iron-based photocatalytic CO2-to-CO systems discussed in the paper. Another important advance is the demonstrated compatibility with water-containing solvent mixtures. The system was studied in MeCN/H2O, and the article shows that 7.5-10% water is essential for efficient catalysis and high CO selectivity. This is chemically significant because water both enables proton-coupled steps and competes with H2 evolution. The paper also provides mechanistic insight through combined photophysical, electrochemical, and computational analysis. Stern-Volmer quenching measurements, cyclic voltammetry, orbital analysis, and atmosphere-dependent electrochemistry support a mechanism in which the excited photosensitizer is quenched primarily by BIH, reduced iron species become accessible within the photosensitizer redox window, and single-electron-reduced catalyst states are implicated in CO2 activation. Durability was examined in a chemically informative way. The activity loss over time was linked mainly to degradation of [Ru(bpy)3]2+, not primarily to catalyst destruction, and replenishing the photosensitizer restored CO production. Mercury poisoning tests further supported the conclusion that catalysis remains homogeneous rather than nanoparticle-driven. Additional Remarks[edit | edit source] The chemistry is significant because CO2-to-CO photoreduction stores reducing equivalents in a useful C1 product. CO is a valuable synthetic intermediate, but selective photochemical formation is challenging because proton reduction to H2 competes strongly under many conditions. This system uses an earth-abundant catalytic metal center, iron, which is an advantage from a sustainability perspective. However, the photochemical system still depends on a ruthenium photosensitizer and a sacrificial electron donor, so it is not a fully sustainable closed-cycle solar fuel system. The article shows both strengths and limitations of sacrificial molecular photocatalysis. Strengths include clear molecular design, high CO selectivity, tunable ligand effects, and useful mechanistic observables. Limitations include reliance on BIH, sensitivity to photosensitizer degradation, and finite long-term durability under continuous irradiation. The role of water is chemically important but also highlights practical tradeoffs. Too little water suppresses productive CO2 reduction, while too much water lowers activity. The article attributes the decline at higher water content partly to limited BIH solubility and reduced efficiency of excited-state quenching. The study is mechanistically informative because it distinguishes supported observations from interpretation. Product analysis, control experiments, mercury poisoning, Stern-Volmer quenching, UV/Vis changes, and cyclic voltammetry directly support the main conclusions, whereas specific catalyst intermediates in the CO2 reduction sequence are proposed rather than directly isolated. Content of the Published Article in Detail[edit | edit source] The molecular photocatalytic system contains three main functional components: an iron(II) bis(pyrazolyl)phenanthroline complex as CO2 reduction catalyst, [Ru(bpy)3]2+ as visible-light photosensitizer, and BIH as sacrificial electron donor. The reaction medium is CO2-saturated MeCN/H2O in a sealed borosilicate photoreactor irradiated with blue light at 462 nm. Gas products were analyzed from the headspace by gas chromatography. The iron complexes Fe1-Fe4 are mononuclear Fe(II) species with tetradentate bis(pyrazolyl)phenanthroline ligands and two water ligands. Magnetic measurements and calculations support high-spin Fe(II) ground states. The article states that all complexes are active for photocatalytic CO2 reduction to CO, with H2 as the main competing side product. No significant formate or CH4 was detected. The optical role is assigned to [Ru(bpy)3]2+. Upon light absorption, the article discusses the excited metal-to-ligand charge-transfer state of the ruthenium photosensitizer. Quenching experiments and orbital-energy analysis were used to determine how this excited state interacts with BIH and the iron complexes. The mechanistic interpretation supported by the article is that reductive quenching by BIH is dominant. Stern-Volmer experiments showed that BIH quenches the emission of [Ru(bpy)3]2+ much more efficiently than Fe1-Fe4. The reported quenching constant for BIH is about one order of magnitude larger than for the iron complexes. The article therefore supports the view that BIH primarily reduces the excited photosensitizer, generating a reduced ruthenium species capable of transferring electrons onward. The article also evaluates possible oxidative quenching by the iron catalysts. Based on the calculated energy-level alignment, the SOMO energies of Fe1-Fe4 do not favor reductive quenching of the excited photosensitizer by the iron complexes, but the SUMO levels lie below the photosensitizer LUMO, making oxidative quenching energetically feasible. Even so, the quenching data show BIH to be the dominant quencher under the studied conditions. Electrochemical data are used to connect photophysics to catalysis. Cyclic voltammetry showed two reduction waves for the iron complexes in acetonitrile. The article interprets these reductions as predominantly ligand-centered rather than formal Fe(II)/Fe(I)/Fe(0) metal-centered reductions, based on DFT orbital composition and correlation between calculated orbital energies and electrochemical potentials. Within the potential window accessible to reduced [Ru(bpy)3]+, the first reduction event is sufficiently stable to be chemically relevant. The article states that reduced iron species formed after single-electron reduction react with CO2. Under CO2 atmosphere, cyclic voltammograms differed from those under Ar, with progressive changes in current response and peak shape during repeated scans. These observations support the conclusion that the reduced iron complexes interact with CO2 to form catalytic intermediates that are not re-oxidized within the applied scan window. The paper does not report direct spectroscopic observation of a specific bound CO2 intermediate during photocatalysis, but it discusses catalyst reduction followed by CO2 activation as the productive pathway. It further states that water is essential for effective proton-coupled electron transfer and stabilization of intermediates. In particular, the absence of water nearly suppresses CO formation, while 7.5-10% water strongly increases activity and selectivity. For Fe4, the article proposes a structural feature that may contribute to selectivity: hydrogen-bonding interactions between coordinated water ligands and CF3-substituent fluorine atoms distort the coordination environment and may help proton management near the metal center. This is presented as an interpretation linked to its high CO selectivity, not as directly observed catalytic turnover chemistry. Control experiments strongly support the full photocatalytic assignment. Removing light, catalyst, photosensitizer, sacrificial donor, or CO2 suppressed productive CO formation. Replacing the molecular iron complex with Fe(ClO4)2 gave only minor amounts of CO and H2, showing that free Fe2+ is not responsible for the catalytic behavior. The article also addresses whether the active species are homogeneous or nanoparticulate. Mercury poisoning experiments did not suppress catalytic CO formation, and this is taken as evidence against catalysis by colloidal or heterogeneous metal particles. The authors therefore conclude that the active system is homogeneous. Catalyst lifetime was investigated indirectly through time-dependent product formation and UV/Vis monitoring. Activity rose strongly at early times and then approached a plateau. The article attributes most of this deactivation to deterioration of [Ru(bpy)3]2+, supported by hypochromism in the UV/Vis spectra of the reaction mixture over time. When fresh photosensitizer was added after 24 h, CO production resumed and the turnover number increased further, supporting the idea that the catalyst remains largely intact while the photosensitizer degrades. Overall, the data support the following chemistry in words: light excites [Ru(bpy)3]2+; BIH predominantly quenches the excited state reductively; the reduced photosensitizer transfers electrons to the iron catalyst; a singly reduced iron complex is implicated in CO2 activation; proton-coupled electron transfer steps in the presence of water lead to CO formation; H2 is the main side product; and the catalyst functions homogeneously under the reported conditions. Catalyst[edit | edit source] The catalysts are a series of molecular homogeneous mononuclear iron(II) bis(pyrazolyl)phenanthroline complexes labeled Fe1-Fe4. Their formulations are reported as [Fe(bpzRphen)(H2O)2]X2, where the bis(pyrazolyl)phenanthroline ligand bears different pyrazolyl substituents and X is BF4- or ClO4-. The article describes them as high-spin Fe(II) complexes with distorted octahedral geometries. The tetradentate bis(pyrazolyl)phenanthroline ligand occupies four coordination sites, and two water ligands occupy the remaining positions. The complexes are used as CO2 reduction catalysts in a homogeneous visible-light photocatalytic system. Their redox behavior is reported to be mainly ligand-centered. This is relevant because electron uptake by the catalyst appears to occur on the coordinated ligand framework while still enabling catalytically relevant reduced states that react with CO2. Catalyst performance depends on ligand substitution. In the standard 24 h comparison at 50 μM catalyst loading, Fe2 gave the highest CO activity, while Fe4 gave the highest CO selectivity. Fe4 also showed a structurally distinctive distortion associated with possible intramolecular hydrogen-bonding interactions involving coordinated water and CF3 substituents, which the article suggests may be linked to selectivity. Regarding stability, the article concludes that the catalysts are robust enough to remain active in solution and that major deactivation is due mainly to photosensitizer deterioration rather than catalyst failure. Mercury poisoning tests also support the conclusion that the catalysis is homogeneous rather than nanoparticle-based. Photosensitizer[edit | edit source] The photosensitizer is [Ru(bpy)3]2+. It serves as the visible-light absorber and initiates the photoredox sequence upon irradiation at 462 nm. The article discusses its excited metal-to-ligand charge-transfer state as the relevant photoactive state. Photophysical measurements show that this excited state is quenched by both BIH and the iron complexes, but BIH is the more efficient quencher. The article therefore supports a mechanism in which [Ru(bpy)3]2+* is quenched primarily reductively by BIH, producing a reduced ruthenium species that can transfer electrons to the iron catalyst. The photosensitizer is chemically suitable here because its reduced form is sufficiently reducing to access the first catalyst reduction event. Electrochemical analysis explicitly compares the catalyst reduction window with the potential of the ruthenium couple. A major limitation is stability under prolonged irradiation. The article reports photodegradation of [Ru(bpy)3]2+, observed as hypochromism in UV/Vis spectra of the reaction mixture. Replenishment of the photosensitizer after 24 h restored catalytic CO production, identifying photosensitizer deterioration as a main cause of deactivation. Investigation[edit | edit source] cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] . . solvent A . . . . . . λexc [nm] . TON CO . . TON H2 . . 1. Fe1 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 987 187 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 2. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 1318 243 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 3. Fe3 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 847 205 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 4. Fe4 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 1265 133 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 5. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 311 51 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 6. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 1578 296 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 7. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 1593 300 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 8. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 2 22 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 9. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 1352 285 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 10. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 661 191 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 11. Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 621 77 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 12. Fe2 25 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 2086 123 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 13. Fe2 12.5 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 4259 276 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 14. Fe2 6.25 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 10168 862 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 15. Fe2 3.12 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 23138 2177 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. 16. Fe2 3.12 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 462 9754 3310 Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process. "not reported" is not a number. Investigation-Name: inv0ExportRefresh] 17:00:07 1810996 AIClient - Response from AI: No. 17:00:08 1810996 AIClient - Request to AI with prompt: 'please check if the given text is spam. answer with yes or no.' and documents [cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include Fe1 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 987 41.1 187 84.1%; 0%; 15.9%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 1318 54.9 243 84.4%; 0%; 15.6%; 0%; 0% Fe3 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 847 35.3 205 80.5%; 0%; 19.5%; 0%; 0% Fe4 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 1265 52.7 133 90.5%; 0%; 9.5%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 4 311 77.7 51 85.9%; 0%; 14.1%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 48 1578 32.9 296 84.2%; 0%; 15.8%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 96 1593 16.6 300 84.2%; 0%; 15.8%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 MeCN 100:0 CO2 not reported not reported 35 462 24 2 not reported 22 8.3%; 0%; 91.7%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 90:10 CO2 not reported not reported 35 462 24 1352 56.3 285 82.6%; 0%; 17.4%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 70:30 CO2 not reported not reported 35 462 24 661 27.5 191 77.6%; 0%; 22.4%; 0%; 0% Fe2 50 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 50:50 CO2 not reported not reported 35 462 24 621 25.8 77 89.0%; 0%; 11.0%; 0%; 0% Fe2 25 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 2086 86.9 123 94.4%; 0%; 5.6%; 0%; 0% Fe2 12.5 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 4259 177.4 276 93.9%; 0%; 6.1%; 0%; 0% Fe2 6.25 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 10168 423.7 862 92.2%; 0%; 7.8%; 0%; 0% Fe2 3.12 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 24 23138 964.1 2177 91.4%; 0%; 8.6%; 0%; 0% Fe2 3.12 [[[Ru(bpy)3]2+ ]] 0.3 BIH 0.11 H2O not reported MeCN H2O 92.5:7.5 CO2 not reported not reported 35 462 4 9754 2438 8.24 3310 74.7%; 0%; 25.3%; 0%; 0% 8.24 ] 17:00:09 1810996 AIClient - Response from AI: no 20:07:16 1817997 OpenAlex - Fetching page 0... 20:07:17 1817997 OpenAlex - Fetching page 1... 20:07:18 1817997 OpenAlex - Fetching page 2... 20:07:19 1817997 OpenAlex - Fetching page 3... 20:07:20 1817997 OpenAlex - Fetching page 4... 20:08:02 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-688 20:08:02 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Planetesimal formation occurs in the optically thick mid-plane of protoplanetary disks. If planetesimals sequester material that is rich in volatile (C, O, S, N) and refractory (e.g., Fe, Si, Al) elements, then these abundances originating from the innermost disk regions (Rdisk ≤ 0.2 AU) are expected to be significantly depleted. Additionally, dust traps can further deplete these elements. We present a physical-chemical model that predicts atomic emission line ratios, given a range of depletion factors and mid-plane densities (15.75 ≤ log(nH [cm-3]) ≤ 16.25). We use the photoionization and chemistry code Cloudy (v25.00) to create a 1D radial slab model of the innermost disk within the dust sublimation rim of a classical T Tauri system. Our model can be applied to observed line ratios in disks in order to determine if rocky planet formation has begun.] 20:08:04 1818494 AIClient - Response from AI: no 20:08:04 1818494 CrossRefSearchJob - AI response: no 20:08:04 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-688 20:08:04 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3107455 20:08:04 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [METIS: grism spectroscopy in the mid-IR] 20:08:06 1818494 AIClient - Response from AI: no 20:08:06 1818494 CrossRefSearchJob - AI response: no 20:08:06 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3107455 20:08:06 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-942 20:08:06 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The recently announced L4 program is intended to be a flagship ESA mission that includes the Enceladus orbiter and lander modules with the capability of in-situ detection of prebiotic complex organic molecules (COMs) in the water ice. The preparatory study of the L4 payload [1], [2] defines an ultra-high resolution, up to mass-defect detection, Orbitrap-based mass spectrometer [3]that allows unambiguous identification of detected molecules by their exact molecular mass and isotopic pattern [4]. The Orbitrap-based spectrometer with the compatible laser ablation surface sampling system optimized for water ice, and laser parameters matching the Orbitrap detector operation sequence are suggested as key devices for the L4 payload.The laser development process must include a comparative study of the laser spectrum, pulse duration, and energy, to ensure detection of ions by the Orbitrap system, with optimal ion signal intensity, stability, and minimized discrimination of the sample compounds. This research will provide input data for the design of the minimalistic architecture laser system with optimized power, mass budget, and mergeable with the actual high TRL Orbitrap mass spectrometer, and pulse durations and wavelengths matching water ablation requirements.The definition of the L4-compatible laser requires laboratory measurements of the composition of the water ice samples with traces of Enceladus-relevant minerals and COMs, with the developed Laser-Orbitrap system, and verification of the possibility to adjust mass spectrometers with the resulting ion source. Parameters of the laser plasma are required to be adjusted to provide optimal ion bunch charge and pulse duration to utilize the detector dynamic range, while avoiding saturation and resulting nonlinear effects. The ion source time and kinetic energy structure defines the ion trapping (squeezing) [5] process, which may affect isotopic ratio measurement accuracy, and so must be adjusted and verified. Currently available laser systems are neither optimized to work with Orbitrap (pumping, pulse duration, and repetition rate requirements), remaining at low power and mass budget, nor is the absorption spectrum optimal for water ice. A simple diode-pumped solid-state laser with an active Q-switch with a fundamental medium emission spectrum is an optimal base for the development of such an Orbitrap-compatible sampling system.As a system performance evaluation and calibration tool, a recently developed multi-parametric Orbitrap output signal processing and analysis software will be used to verify the resulting performance and stability of parameters.Figure 1 – Concept of the laser ablation ice surface sampling for Orbitrap-based mass analyzerThe joint team of the ELI ERIC, the European largest laser and laser-driven radiation facility, with the group of Professor Bern Abel (Leipzig University and Heyrovsky Institute, Prague), will deliver a prototype of the laser optimized for Enceladus surface and Orbitrap detector, combining its unique experience on icy moon exploration, laser and radiation technology development. The proposed multi-institutional work group has demonstrated experience with the development of the best-in-class and world’s most intense lasers, and participation in space missions (Cassini-Huygens and Europa Clipper mission teams). Technical and research capabilities of ELI ERIC, on top of laser systems and laboratories, include unique radiation sources representing the radiation environment of Saturn’s radiation belts, and instrument development support infrastructure, such as clean rooms, optical, vacuum, and thermal validation instrumentation. References[1] V. A. Martins, “Report of the Expert Committee for the Large-class mission in ESA’s Voyage 2050 plan covering the science theme ‘Moons of the Giant Planets,’” 2025.[2] J. Helbert, T.-M. Bründl, M. Haag, M. Lindner, B. Ordoubadian, and S. Wittig, “The Mission to Enceladus – The ESA L4 mission ,” Jul. 09, 2025. doi: 10.5194/epsc-dps2025-1307.[3] I. Zymak et al., “A High-Resolution Mass Spectrometer for the Experimental Study of the Gas Composition in Planetary Environments: First Laboratory Results,” Aerospace, vol. 10, no. 6, 2023, doi: 10.3390/aerospace10060522.[4] F. Klenner et al., “Developing a Laser Induced Liquid Beam Ion Desorption Spectral Database as Reference for Spaceborne Mass Spectrometers,” Earth and Space Science, vol. 9, no. 9, p. e2022EA002313, Sep. 2022, doi: https://doi.org/10.1029/2022EA002313.[5] Q. Hu, R. J. Noll, H. Li, A. Makarov, M. Hardman, and R. Graham Cooks, “The Orbitrap: a new mass spectrometer,” Journal of Mass Spectrometry, vol. 40, no. 4, pp. 430–443, Apr. 2005, doi: https://doi.org/10.1002/jms.856.] 20:08:07 1818494 AIClient - Response from AI: no 20:08:07 1818494 CrossRefSearchJob - AI response: no 20:08:07 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-942 20:08:07 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74050-8 20:08:07 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Efficient algorithms are needed to segment vasculature in new 3D medical imaging datasets at scale for research and clinical applications. Manual segmentation of vessels in images is time-consuming and expensive whereas computational approaches have limited accuracy. We organize a global machine learning competition, engaging 1,401 participants, to promote development of deep learning methods for 3D blood vessel segmentation in Hierarchical Phase-Contrast Tomography (HiP-CT) datasets. This paper presents a meta-analysis of the top-performing solutions, focusing on segmentation accuracy and morphological analysis. The competition and subsequent analysis reveal convergent methodological innovations: pseudo-labeling approaches that exploit data distributions, metrics and loss functions that optimize for vessel surface and topology, and multi-scale approaches that handle data heterogeneity. Additionally, the paper presents techniques for building deep learning models for the defined task, metrics to assess and compare algorithm performance, and a dataset with manually annotated and curated gold standard segmentations for future studies in blood vessel segmentation within HiP-CT imaging.] 20:08:09 1818494 AIClient - Response from AI: no 20:08:09 1818494 CrossRefSearchJob - AI response: no 20:08:09 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74050-8 20:08:09 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-73050-y 20:08:09 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [High-sensitive glycomics using seGRAP-mass spectrometry uncovers a conserved N-glycome in single human oocytes] 20:08:09 1818494 AIClient - Response from AI: no 20:08:09 1818494 CrossRefSearchJob - AI response: no 20:08:09 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-73050-y 20:08:09 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-87 20:08:09 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The presentation covers the topics reported in our recent work published in Nature Rev. Chem. [1]. It covers 50 years of experiments dedicated to simulate radiation and thermally driven processes that occur on icy dust particles in space. The interstellar and protoplanetary ice composition is dominated by water and often contains CO, CO2, CH4, CH3OH, NH3, OCN-, OCS, and probably larger species which await identification. The harsh conditions in space (ultra-high vacuum, cryogenic temperatures, and radiation) are mimicked in the laboratory. UV photons/X-rays/ions impact on the ice covering microscopic pre-cometary dust particles in dense interstellar clouds and protoplanetary disks prior to the formation of cometesimals by agglomeration of the icy dust. Laboratory results show that radiation produces radicals and reactive species changing the initial composition of the ice to form complex organic molecules (COMs) of prebiotic interest (among them are several amino acids, nitrogen-heterocycles related to nucleobases, and sugars). Many of these molecules were also identified in Rosetta comet 67P, and infrared spectra of Ryugu samples delivered by Hayabusa2 are strikingly similar to those of refractory residues retrieved at room temperature after warmup of the irradiated ice [2]. First, recent experimental results on ice properties (density, infrared spectroscopy, optical constants, morphology) supported by DFT calculations will be presented with important updated values of the ice density and infrared band strengths. This allows a proper column density estimation of the various molecular ice components. For instance, the commonly used band strength of water ice was significantly lower than the actual value and did not take into account the variations due to ice temperature. Second, recent results obtained in our laboratory regarding COMs formation by ultraviolet irradiation of interstellar ice analogs will be unveiled. We will propose formation mechanisms of the heterocycles identified in the residues made by ice processing. Another talk by H. Carrascosa will discuss in more detail the important role played by water molecules in the ice chemistry that enables the synthesis of prebiotic species. References [1] G. M. Muñoz Caro, H. Carrascosa, & R. Martín-Doménech “Photochemistry of interstellar ice forming complex organic molecules”, 2025, Nature Rev. Chem. 9, 537 [2] J. Mathurin, et al. ¨AFM-IR nanospectroscopy of nanoglobule-like particles in Ryugu] 20:08:11 1818494 AIClient - Response from AI: no 20:08:11 1818494 CrossRefSearchJob - AI response: no 20:08:11 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-87 20:08:11 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75094-6 20:08:11 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Ultra flash cold events under global warming] 20:08:12 1818494 AIClient - Response from AI: no 20:08:12 1818494 CrossRefSearchJob - AI response: no 20:08:12 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75094-6 20:08:12 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76347 20:08:12 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Predicting soil carbon dynamics under warming is constrained by limited understanding of microbial thermal adaptation, particularly whether microbial carbon use efficiency (CUE) can adapt to warming and how plant diversity modulates this response. Using soils from a natural tree species diversity gradient in a subtropical forest, we combined a 365‐day laboratory incubation with regular substrate amendment and 18 O‐H 2 O labeling to quantify thermal responses of microbial respiration, growth, and CUE. High tree species diversity was associated with a strengthened compensatory thermal adaptation of microbial respiration and growth, effectively dampening their response to warming. Simultaneously, diversity promoted an enhanced thermal response of CUE, increasing microbial carbon retention capacity under warming. This dual regulation was mechanistically linked to a cascade of processes: higher tree species diversity was associated with lower soil organic matter stability (i.e., higher lability), minimizing bioenergetic costs of enzyme synthesis, facilitating a community‐wide shift toward r‐selected bacteria, and intensifying microbial competition as evidenced by network topology. Our findings reveal the potential of biodiversity to buffer soil carbon losses: conserving and restoring plant diversity can enhance soil capacity to mitigate climate change, both by reducing respiratory carbon losses and by increasing the potential for microbial carbon sequestration under warming. ] 20:08:13 1818494 AIClient - Response from AI: no 20:08:13 1818494 CrossRefSearchJob - AI response: no 20:08:13 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76347 20:08:13 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1021/jacsau.6c00604 20:08:13 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Z -Selective Synthesis of Trisubstituted Alkenes Bearing Allylic Tertiary Amines via Rhodium-Catalyzed Allylic Amination of 1,1-Disubstituted Fluoromethyl Trichloroacetimidates] 20:08:13 1818494 AIClient - Response from AI: no 20:08:13 1818494 CrossRefSearchJob - AI response: no 20:08:13 1818494 CrossRefSearchJob - Publication not relevant: 10.1021/jacsau.6c00604 20:08:13 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76389 20:08:13 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Programmed death‐ligand 1 (PD‐L1) blockade improves outcomes in patients with various malignancies; however, biomarkers for monitoring treatment responses are lacking. This study presents a surface‐enhanced Raman scattering (SERS)‐based platform for the ultrasensitive detection of PD‐L1 on circulating epithelial cell adhesion molecule‐positive (EpCAM + ) extracellular vesicles (EVs). The platform is validated using interferon‐gamma‐treated epithelial tumor cell line‐derived EVs. The platform is further applied to paired pre‐ and post‐treatment plasma samples from patients with non‐small‐cell lung cancer ( n = 140) and head and neck squamous cell carcinoma ( n = 73) receiving anti‐PD‐(L)1 immunotherapy. Dynamic changes in PD‐L1 expression on EV are shown to correlate with clinical outcomes. A post‐treatment decrease in PD‐L1 expression on EpCAM + EVs (EpCAM + EV PD‐L1) is associated with improved 5‐year progression‐free and overall survival. These results establish EpCAM + EV PD‐L1 as a dynamic, non‐invasive biomarker for monitoring immunotherapy responses and demonstrate the utility of SERS‐based profiling in predicting long‐term responses to immune checkpoint blockade. ] 20:08:15 1818494 AIClient - Response from AI: no 20:08:15 1818494 CrossRefSearchJob - AI response: no 20:08:15 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76389 20:08:15 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75184-5 20:08:15 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Sulfur-passivated Pt cluster edges on CeO2 for selective CO2-to-CO conversion] 20:08:16 1818494 AIClient - Response from AI: yes; CO2 conversion, CO conversion, Electrochemical CO2 conversion, Heterogeneous electrochemical CO2 conversion 20:08:16 1818494 CrossRefSearchJob - AI response: yes; CO2 conversion, CO conversion, Electrochemical CO2 conversion, Heterogeneous electrochemical CO2 conversion 20:08:16 1818494 CrossRefSearchJob - Publication relevant (yes): 10.1038/s41467-026-75184-5 20:08:17 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75016-6 20:08:17 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Direct extraction of bromine from seawater through an electrolysis-driven styrene enrichment process] 20:08:18 1818494 AIClient - Response from AI: no 20:08:18 1818494 CrossRefSearchJob - AI response: no 20:08:18 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75016-6 20:08:18 1818494 DEBUG DownloadPDFJob - Loading from URL: https://www.nature.com/articles/s41467-026-75184-5_reference.pdf 20:08:18 1818494 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:08:26 1818494 DEBUG DownloadPDFJob - URL: https://www.nature.com/articles/s41467-026-75184-5_reference.pdf Download location: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:08:19 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://www.nature.com/articles/s41467-026-75184-5_reference.pdf DONE. Final URL after redirect: https://www.nature.com/articles/s41467-026-75184-5_reference.pdf An error occurred: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf (Is a directory) java.io.FileNotFoundException: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf (Is a directory) at java.base/java.io.FileOutputStream.open0(Native Method) at java.base/java.io.FileOutputStream.open(FileOutputStream.java:289) at java.base/java.io.FileOutputStream.(FileOutputStream.java:230) at java.base/java.io.FileOutputStream.(FileOutputStream.java:118) at com.diqa.downloader.Main.downloadPdf(Main.java:195) at com.diqa.downloader.Main.main(Main.java:127) 20:08:26 1818494 DEBUG DownloadPDFJob - Loading from URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75184-5/MediaObjects/41467_2026_75184_MOESM1_ESM.pdf 20:08:26 1818494 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:08:32 1818494 DEBUG DownloadPDFJob - URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75184-5/MediaObjects/41467_2026_75184_MOESM1_ESM.pdf Download location: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:08:27 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75184-5/MediaObjects/41467_2026_75184_MOESM1_ESM.pdf DONE. Final URL after redirect: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75184-5/MediaObjects/41467_2026_75184_MOESM1_ESM.pdf An error occurred: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf (Is a directory) java.io.FileNotFoundException: /opt/downloadPDF/chemwiki_pubstore/b74d6052eb5dd9ca807905b1fd5a9581.pdf (Is a directory) at java.base/java.io.FileOutputStream.open0(Native Method) at java.base/java.io.FileOutputStream.open(FileOutputStream.java:289) at java.base/java.io.FileOutputStream.(FileOutputStream.java:230) at java.base/java.io.FileOutputStream.(FileOutputStream.java:118) at com.diqa.downloader.Main.downloadPdf(Main.java:195) at com.diqa.downloader.Main.main(Main.java:127) 20:08:32 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-261 20:08:32 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The volatile composition of icy bodies provides important clues to the chemical inheritance linking molecular clouds, protoplanetary disks, and forming planetary systems. While water ice is generally expected to dominate the volatile inventory of bodies formed in the outer Solar System, observations of comets and trans-Neptunian objects reveal substantial diversity in ice abundances, including unexpectedly high CO-to-water ratios in some objects. Understanding how such CO-rich reservoirs form and evolve is therefore essential for connecting disk ice chemistry with the volatile composition of planetesimals and planets.In this contribution, I present results of a recent study (Drazkowska 2026) using a one-dimensional disk model including dust coagulation, fragmentation, radial drift, volatile evaporation and recondensation, and planetesimal formation via the streaming instability. In particular, I explore how the disk buildup stage influences the chemical evolution of icy solids and the preservation of volatile-rich reservoirs.CO-rich pebbles naturally form near the CO snow line due to the cold-finger effect, where outward-diffusing CO vapor recondenses onto drifting grains. This process efficiently enhances the CO ice abundance in solids and occurs regardless of whether disk buildup is included. However, models incorporating the buildup phase produce significantly stronger CO enrichment relative to water in the outer disk, demonstrating that early disk evolution can substantially modify the volatile composition inherited by icy solids. Despite the formation of CO-rich pebbles, smooth disk models do not produce CO-rich planetesimals. This suggests that additional mechanisms are required to retain or trap CO-rich solids.These results highlight the importance of volatile transport and ice reprocessing in regulating the chemical inheritance of forming planetary systems. In particular, models aiming to connect disk chemistry with cometary compositions and exoplanet atmospheric C/O ratios should account for the disk buildup stage, which can significantly alter the spatial distribution and incorporation of volatile species into solids.] 20:08:34 1818494 AIClient - Response from AI: no 20:08:34 1818494 CrossRefSearchJob - AI response: no 20:08:34 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-261 20:08:34 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103312 20:08:34 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [AIRS: alignment and validation of the infrared spectrometer of ARIEL] 20:08:35 1818494 AIClient - Response from AI: no 20:08:35 1818494 CrossRefSearchJob - AI response: no 20:08:35 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103312 20:08:35 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1045 20:08:35 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Femtosecond lasers have in recent years been shown to be compact, robust and space qualified [1,2], thereby so called, time-domain spectroscopy (TDS) techniques, which allow to avoid complex detector systems and/or bulky opto-mechanics of conventional instruments such as Fourier-Transform Interferometers or grating spectrometers become viable options for more compact, energy/mass efficient and performant space instruments [3,4]. In this contribution we show how terahertz (THz) TDS emerges as an alternative to conventional infrared spectrometers in the spectral range of 10 – 1000 cm-1 (0.3 to 30 THz). Progress towards space qualification and chip integration is presented and future use cases such are THz TDS in attenuated total reflection (ATR) geometry are discussed. Figure 1: Plot showing the evolution of solid-state laser systems since 1975 and their corresponding spectral bandwidth.Figure 2: Broadband spectrum of spintronic THz emittersFigure 3: THz TDS in ATR geometry and schematic diagram of intergration of THz TDS for space exploration on fiber platform. References[1] J. Lee, K. Lee, Y. Jang, et al. “Testing of a femtosecond pulse laser in outer space,” Scientific Reports 4, 5134, (2014).[2] M. Lezius, T. Wilken, C. Deutsch, et al., “Space-borne frequency comb metrology,” Optica 3, 1381 (2016).[3] O. Gueckstock, N. Stojanovic, Y. Ha, et al, “Radiation hardness of ultrabroadband spintronic terahertz emitters: En-route to a space-qualified terahertz time-domain gas spectrometer,” Applied Physics Letters 124, 141103 (2024).[4] Y. Ha, S.G. Pavlov, M.D. Rabasovic, et al., “Time-Domain Raman Spectroscopy: An Emerging Technique in Space Exploration,” J. Raman Spectrosc. 56, 916 (2025).] 20:08:36 1818494 AIClient - Response from AI: no 20:08:36 1818494 CrossRefSearchJob - AI response: no 20:08:36 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1045 20:08:36 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103240 20:08:36 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A high-isolation wideband channelizer for MKID readouts: a custom HLS implementation on RFSoC] 20:08:37 1818494 AIClient - Response from AI: no 20:08:37 1818494 CrossRefSearchJob - AI response: no 20:08:37 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103240 20:08:37 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76366 20:08:37 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Photoacoustic tomography is uniquely capable of high‐resolution deep‐tissue blood‐oxygenation (sO 2 ) imaging (oximetry) due to its optical absorption contrast. However, wavelength‐dependent optical fluence changes within tissue, i.e., spectral coloring, have impeded the development of photoacoustic oximetry. We present the arterial prior method (APM+; + denotes intravascular fluence correction), which leverages the high arterial sO 2 to locally calibrate the optical fluence within tissue to circumvent spectral coloring and reliably estimate the sO 2 near the artery. In phantom experiments with ex vivo animal tissue, APM+ resulted in a median estimation error of 2.9% compared to 9.8% from the traditional linear unmixing method (LUM). In human imaging experiments of the radial artery‐vein pair in eight healthy adult volunteers, the estimated venous sO 2 s from APM+ (median: 72.3%, interquartile range/IQR: 8.9%) were concentrated around the typical 60%–80% range in healthy individuals, whereas those from LUM (median: 75.2%, IQR: 34.4%) varied widely. When imaging the wrists of the eight subjects through ex vivo animal tissue of thicknesses up to 1.5 cm, APM+ provided more consistent estimates than LUM, indicating its robustness with depth. ] 20:08:38 1818494 AIClient - Response from AI: no 20:08:38 1818494 CrossRefSearchJob - AI response: no 20:08:38 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76366 20:08:38 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76307 20:08:38 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Alkaline hydrogen evolution reaction (HER) is limited by slow water dissociation and by catalysts that degrade in saline electrolytes. Here we program vacancies to trigger selective Ni exsolution in multimetallic Prussian blue analogues (PBAs), creating cooperative defect–metal interfaces. Low‐temperature annealing of FeMn@CoNi PBAs forms hollow nanocages (PBA‐350) rich in cyanide vacancies and decorated with in situ exsolved Ni nanoparticles. Operando XRD/XAS, operando impedance, and theory reveal a dual‐site mechanism: vacancy‐stabilized Ni lowers the Volmer barrier, adjacent Co facilitates OH* removal, and the vacancy‐modified lattice tunes H* binding toward thermoneutrality. PBA‐350 delivers 28.4 mV at 10 mA cm −2 and a 56 mV dec −1 Tafel slope in 1.0  m KOH with negligible degradation over 100 h at −50 mA cm −2 . An anion‐exchange membrane electrolyzer reaches 1.76 V at 1.0 A cm −2 , and PBA‐350 remains stable in simulated seawater (1.0  m KOH + 0.5  m NaCl) by physically repelling chloride ions via hydration layers, establishing vacancy‐assisted exsolution as a design rule for HER. ] 20:08:38 1818494 AIClient - Response from AI: no 20:08:38 1818494 CrossRefSearchJob - AI response: no 20:08:38 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76307 20:08:38 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3102832 20:08:38 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Improved data reduction procedure for the mid-infrared slit spectroscopy of AKARI/IRC LG2] 20:08:39 1818494 AIClient - Response from AI: no 20:08:39 1818494 CrossRefSearchJob - AI response: no 20:08:39 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3102832 20:08:39 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75059-9 20:08:39 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Intracellular assembly of artificial enzymes for cytoplasmic enantioselective Mannich reactions] 20:08:40 1818494 AIClient - Response from AI: no 20:08:40 1818494 CrossRefSearchJob - AI response: no 20:08:40 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75059-9 20:08:40 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75103-8 20:08:40 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Field angle-independent high magnetoresistance and field angle-dependent coercivity in Fe3GaTe2/Phosphorus all-van der Waals spin valves at room temperature] 20:08:41 1818494 AIClient - Response from AI: no 20:08:41 1818494 CrossRefSearchJob - AI response: no 20:08:41 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75103-8 20:08:41 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74608-6 20:08:41 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [DNA transposon expansion drives genome plasticity in Diutina catenulata] 20:08:42 1818494 AIClient - Response from AI: no 20:08:42 1818494 CrossRefSearchJob - AI response: no 20:08:42 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74608-6 20:08:42 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104720 20:08:42 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [SPACE-MOF: a first step towards an imaging MOF for space applications] 20:08:43 1818494 AIClient - Response from AI: no 20:08:43 1818494 CrossRefSearchJob - AI response: no 20:08:43 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104720 20:08:43 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3389/fmolb.2026.1703547 20:08:43 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ Background Metabolic dysfunction-associated steatotic liver disease (MASLD) is estimated to affect 38% of the global population, with limited options for treatment. It could progress to metabolic-associated steatohepatitis (MASH), fibrosis, and hepatocellular carcinoma. Agonists for farnesoid X receptor (FXR), peroxisome proliferation-associated receptors (PPARs), and sirtuin1 (SIRT1) are currently investigated for MASLD treatment. The subcellular localization of those proteins was shown to affect their function and could possibly be affected by different metabolites. Moreover, while those protein targets were found to be affected by the gut microbiome in mice, they have not yet been investigated in humans. Existing evidence independently links the gut microbiome to MASLD onset and demonstrates that host proteins are impacted by the microbiome. Therefore, we aimed at using integrative multi-omics analysis to investigate the interrelationship between the gut microbiome, fecal and serum metabolomes, and those selected protein targets in a cohort of patients with MASLD to identify potential markers differentiating MASLD and MASH. Methods Serum and stool samples were collected from patients with MASLD and healthy controls, while formalin-fixed paraffin-embedded (FFPE) liver biopsies and clinical laboratory tests were obtained from patients only. Expression of the protein targets was analyzed by immunohistochemistry (IHC). Microbiome and metabolome analyses were performed, followed by bioinformatics, correlation, and multivariate and integrated multi-omics analyses. Results SIRT1 and FXR subcellular localizations were correlated with multiple bacteria and metabolites, respectively. Three genera ( Rothia , Haemophilus , and Acetatifactor ) correlated with NAFLD activity score (NAS), and a signature of 20 bacterial genera, 10 fecal and 30 serum metabolites, and 3 host proteins differentiated between MASLD and MASH. Moreover, in silico analysis suggested myristic, lauric, octanoic, and nonanoic acids to putatively affect peroxisome proliferator-activated receptor alpha (PPARA) and FXR, and Coprobacter as an important contributor in our multi-omics model. Conclusion Our data suggest bacteria and metabolites which potentially affect the subcellular localization, and hence activity, of anti-lipogenic proteins in MASLD patients. We also propose novel discriminatory markers between MASLD and MASH. Our findings form the groundwork for future mechanistic studies of both host and microbial factors possibly contributing to the multifaceted disease outcome and offer potential diagnostic markers. ] 20:08:44 1818494 AIClient - Response from AI: no 20:08:44 1818494 CrossRefSearchJob - AI response: no 20:08:44 1818494 CrossRefSearchJob - Publication not relevant: 10.3389/fmolb.2026.1703547 20:08:44 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1129 20:08:44 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The characterisation of cosmic dust properties is key for understanding, among other things, planet formation processes. Astronomical observations provide us information from which it is possible, but not trivial, to deduce physical properties of cosmic dust. For instance, recent observations of 12 young protostars found dust emissivity indices with values β < 1 [Maury et al. 2019, Galametz et al. 2019, Cacciapuoti et al. 2025], which would imply that dust coagulated into grains over 100µm in size [Ysard et al. 2019], much larger than what predicts actual paradigms of planet formation at this stage of stellar evolution. However, relating the grain sizes to their opacity measured in the millimetre bands is not straightforward and rely heavily on the validity of current dust models used as astrophysical analogues in the community. For example, the optical properties of large dust aggregates in cold environments, as observed in millimetre wavelengths were not explored in a systematic way, limiting the astrophysical interpretation that can be done from the measurements, especially for the dense ISM. Our work addresses this blind spot, building new physically-motivated dust models to interpret the dust signatures in protostellar environments.Our study concentrates on building realistic dust models of evolved, structurally detailed aggregate dust grains. We use the Discrete Dipole approximation (DDA) code ADDA [Yurkin et al. 2011] to compute the optical properties in extinction, absorption and scattering of our grains, based on laboratory-measured material properties from the THEMIS 2 dust model [Ysard et al. 2024]. Our first study [Carpine et al. 2025] highlighted the heavy dependence of dust optical properties on the shape, but also on the composition of dust grains. We stress here the importance of correct representation of potentially large fluffy aggregates in protostars, when current models in the literature include mostly small compact grains, fitted for the diffuse ISM. Radiative transfer simulations we conducted [Carpine et al. 2026, subm.] showed that none of the various existing ISM dust models are able to reproduce the low emissivity indices values observed in some protostars. Using discrete dipole approximation, along with a novel method we developed to speed up drastically the computation of aggregates optical properties [Carpine et al. 2026b, subm.], we are creating the first dense medium dust database of complex aggregates, based on laboratory-measured material properties THEMIS 2 [Ysard et al. 2024], to provide a physically motivated model to precisely interpret protostellar observations.Building reliable dust models is decisive in the interpretation of observations of the dense ISM, in our understanding of dust evolution towards planet formation. With our models for aggregate dust grain, different optical properties are inferred, challenging fiducial interpretation and opening the path to robust interpretation of the dust properties during the disk formation stage] 20:08:45 1818494 AIClient - Response from AI: no 20:08:45 1818494 CrossRefSearchJob - AI response: no 20:08:45 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1129 20:08:45 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75065-x 20:08:45 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Time-staggered chemo-immunotherapy via engineered nanofiber resists postoperative dynamic immunosuppression in glioblastoma] 20:08:46 1818494 AIClient - Response from AI: no 20:08:46 1818494 CrossRefSearchJob - AI response: no 20:08:46 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75065-x 20:08:46 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-347 20:08:46 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ContextThe formation of planets such as Earth starts with the recondensation of refractory minerals from hot gas close to a protostar. Recently, crystalline silicates were found to be recondensing from a reservoir of hot SiO gas around Class I protostar HOPS-315 (McClure+25), making it the first detection of this so-called t=0 phase of planetesimal formation. A depletion of iron and silicon in the protostellar jet suggests this t=0 moment may be associated with the formation of the first planetesimals in this disk, similar to the association of refractory inclusions and iron-meteorite parent bodies in the Solar System.AimsIn this work, we explore whether an even younger Class I protostar with similar properties and system geometries, is engaged in such refractory recondensation as well. A detection of cool gas-phase SiO in absorption above a hot disk midplane would allow us to achieve this goal, thanks to a previous Spitzer detection of crystalline silicates.MethodsThe protostar was observed with the JWST Mid-Infrared Instrument and Near Infrared Spectrograph, showing multiple bands of molecular absorption similar to HOPS-315. We use local thermal equilibrium slab models to measure the temperature, column density, velocity, and radial location of these bands.ResultsThe molecular absorption bands of gaseous SiO, H2O, CO, CO2, HCN, and C2H2 trace a warm molecular inversion layer (~ 300 - 500 K) at mid-altitudes above the hot disk midplane from 0.3 - 19 AU, which is consistently blue-shifted with respect to the system velocity by 33-53 km s-1. ALMA observations of this protostar kinematically resolve an SiO-rich jet and wind. Unlike for HOPS-315, the infrared SiO velocity for this source matches the velocity of the disk wind.We find that the young protostar is more carbon-rich than HOPS-315, as we detect multiple additional hydrocarbon species, that were not detected in HOPS-315ConclusionsWe confirm that this protostar, like HOPS-315, is undergoing an epoch analogous to the t=0 moment in the Solar System's planet formation timeline. The detected warm molecular layer traces the base of a disk wind, which carries sublimated silicates and soot from the thermostat region near 2 AU up into the outer disk. We sketch out this proposed mechanism in the figure below.We find that this source is likely younger than HOPS-315. Therefore, the differences in carbon-rich chemistry between them may be age-related. Its carbon-rich chemistry is likely caused by carbon-rich material being sublimated off the grains in the inner disk and then transported outwards via the detected disk wind. Confirming such a scenario would require higher-resolution (sub)-mm observations of this source. Future identifications of more sources undergoing refractory recondensation will allow us to determine how source age influences the presence and detectability of the t=0 phase.] 20:08:47 1818494 AIClient - Response from AI: no 20:08:47 1818494 CrossRefSearchJob - AI response: no 20:08:47 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-347 20:08:47 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-72148-7 20:08:47 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [PCSK5 promotes angiogenesis and cardiac repair after myocardial infarction] 20:08:48 1818494 AIClient - Response from AI: no 20:08:48 1818494 CrossRefSearchJob - AI response: no 20:08:48 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-72148-7 20:08:48 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-438 20:08:48 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Grain charging and gas ionization are important processes in protoplanetary disks. Both occur in mutual collisions between grains, as charge is exchanged between grain surfaces but also released into the surrounding gas as ions. The charge carrier for tribocharging, the origin of the gaseous ions, and their composition are currently unknown. However, they are important to know to validate the significance of these processes under disk conditions. In this work, we approach these questions by detecting molecules ejected during grain collisions by mass spectroscopy. As tribocharging works well under normal atmospheric conditions, we use untreated „dirty" particles here. Without collisions, our measurements show a background mix of molecules. Among these are organics, but especially water related molecules. During collisions, the abundances of not all but quite a few molecules change. Water related in molecules are among the largest fractions that change. These results suggest that particle collisions release adsorbates even at very low pressure, which is relevant for protoplanetary disks. As monolayers of water and organics are present on all surfaces in cool to moderately tempered parts of protoplanetary disks, this supports the importance of triboionization in disks.] 20:08:49 1818494 AIClient - Response from AI: no 20:08:49 1818494 CrossRefSearchJob - AI response: no 20:08:49 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-438 20:08:49 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10547-8 20:08:49 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A pore-facing glycan constrains GABAA receptor subunit stoichiometry and gating behavior] 20:08:50 1818494 AIClient - Response from AI: no 20:08:50 1818494 CrossRefSearchJob - AI response: no 20:08:50 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10547-8 20:08:50 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1169 20:08:50 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The detection of molecular chirality in planetary environments is a fundamental objective of planetary exploration, both for its astrobiological implications as a possible biosignature [1], and as a tracer of pre-biotic chemistry shedding light on the distribution of enantiomeric excess across the Solar System and the origins of biological homochirality on Earth. Yet direct chirality measurements remain scarce across Solar System bodies, limited to laboratory analyses of meteorites and returned samples from Bennu and Ryugu. Among meteorites, notable enantiomeric excesses have been measured in Murchison (L-isovaline ~18% ee, L-glutamic acid ~16–40% ee), Orgueil (L-isovaline ~15% ee), and Tagish Lake (L-aspartic acid, up to ~60% ee) [2,3]. The current state of the art for in-situ chirality detection relies on chiral columns within Gas Chromatography-Mass Spectrometers (GC-MS), as deployed on COSAC for comet 67P/Churyumov-Gerasimenko, MOMA for Mars, and DraMS for Titan. Despite their high sensitivity, these instruments are complex to implement, require a destructive derivatization process, and allow only a limited number of measurements over a mission lifetime.In terrestrial chemistry, chirality is routinely probed non-destructively through mid-infrared spectropolarimetry via Vibrational Circular Dichroism (VCD) [4]. This well-established optical technique operates on the principle of detecting the differential absorption of left- and right-circularly polarized infrared light [5]. It is sensitive to the exact molecular conformation of chiral compounds [6] and to their local chemical environment (solvent, hydrogen bonding, aggregation, pH), all of which influence the VCD signal. VCD spectroscopy is applicable to samples in solid, liquid, and gas phases but usually requires sample preparation in the lab. Its application to planetary exploration has, however, not yet been demonstrated. In this work, we investigate the VCD response to Solar System analogue material that is applicable to carbonaceous small bodies and the surface of Mars. We use L- and D-phenylalanine as a plausible chiral organic compound, embedded in a variety of hydrated mineral matrices (gypsum, serpentine, carbonates, and opals) as well as in established Mars and asteroid (CM-E) simulants [7, 8]. Minerals were selected based on surface compositions inferred from the Bennu and Ryugu sample return missions, as well as from ongoing and planned Mars exploration.Solid-state samples are prepared as KBr pellets and measured in transmission across 2.5–12.0 µm using a Bruker Vertex 70 FTIR spectrometer with a PMA50 VCD accessory. This spectral range was selected to match the capabilities of current and future in-situ planetary spectrometers. We focus on two regions: the MWIR (C-H stretching near 3.4 µm), accessible to current in-situ spectrometers [9], and the LWIR (6–12 µm), which hosts numerous diagnostic bands and is expected to be accessible to future instruments. Measurements are performed at organic:mineral concentrations ranging from 10% to 50% (Figures 1 and 2), with preliminary results indicating detection thresholds below this level, consistent with organic abundances reported from Ryugu sample analyses.Figure 1: Infrared absorbance and VCD signal in transmission of pure serpentine mixed with the L- and D- form of phenylalanine respectively in a 2:1 ratio. Gray regions indicate spectral ranges excluded due to high mineral absorbance combined with low instrument throughput (A > 1).Figure 2: Infrared absorbance and VCD signal in transmission of a clay-rich Mars simulant MGS-1C mixed with the L- and D- form of phenylalanine respectively in a 10:1 ratio. Gray regions indicate spectral ranges excluded due to high mineral absorbance combined with low instrument throughput (A > 1). Our results (Figures 1 and 2) demonstrate that the chiral VCD signature of both L- and D-phenylalanine remains detectable within these mineral matrices, establishing the feasibility of a chirality diagnostic inherently inaccessible to conventional IR spectroscopy. Signal averaging was optimised for the MWIR to resolve the fainter and broader O-H, NH3+, and C-H stretch signals, at the cost of saturation in the LWIR. Despite this, the NH3+ deformation and COO- stretching features remain identifiable in the LWIR. Both serpentine and the clay-rich Mars simulant MGS-1C exhibit low absorbance across most of the MWIR and LWIR, enabling detection of a VCD signal of 10⁻⁵ at an organic:mineral concentration of 10%. LWIR bands remain comparatively easier to detect, requiring fewer averaged measurements and lower concentrations.These findings establish VCD spectropolarimetry as a promising approach for the non-destructive characterisation of organic matter in planetary analogue materials, preserving the native solid-state relationship between organics and their host mineral matrix. Future work will broaden the range of chiral organics and mineral matrices studied and refine sample preparation protocols. Together, these laboratory results provide the scientific foundation for the development of a space-qualified VCD instrument capable of probing chirality and organic–mineral interactions directly on the surfaces of asteroids, comets, and other small bodies [10]. References: [1] Glavin, D., et al. (2019). The Search for Chiral Asymmetry as a Potential Biosignature in our Solar System.. Chemical reviews. https://doi.org/10.1021/acs.chemrev.9b00474.[2] Glavin, D., et al. (2020). Extraterrestrial amino acids and L‐enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison. Meteoritics & Planetary Science, 56. https://doi.org/10.1111/maps.13451.[3] Chan, Q., et al (2023). The amino acid and polycyclic aromatic hydrocarbon compositions of the promptly recovered CM2 Winchcombe carbonaceous chondrite. Meteoritics & Planetary Science, 59. https://doi.org/10.1111/maps.13936.[4] Keiderling, T. (2018). Instrumentation for Vibrational Circular Dichroism Spectroscopy: Method Comparison and Newer Developments. Molecules : A Journal of Synthetic Chemistry and Natural Product Chemistry, 23. https://doi.org/10.3390/molecules23092404.[5] Nafie, L. (2020). Vibrational optical activity: From discovery and development to future challenges.. Chirality. https://doi.org/10.1002/chir.23191.[6] He, Y., et al. (2011). Determination of Absolute Configuration of Chiral Molecules Using Vibrational Optical Activity: A Review. Applied Spectroscopy, 65, 699 - 723. https://doi.org/10.1366/11-06321.[7] Cannon, K. M., et al (2019). Mars global simulant MGS-1: A Rocknest-based open standard for basaltic martian regolith simulants. Icarus, 317, 470-478.[8] Britt, D. T., et al. (2019). Simulated asteroid materials based on carbonaceous chondrite mineralogies. Meteoritics & Planetary Science, 54(9), 2067-2082.[9] Bibring, J. P., et al. (2017). The micrOmega investigation onboard ExoMars. Astrobiology, 17(6-7), 621-626.[10] Krasteva, M., et al. (2024). CHirality Analyzer In-Situ (CHAIS)-A Novel Approach to Planetary Surface Characterisation (No. EPSC2024-881). Copernicus Meetings.] 20:08:51 1818494 AIClient - Response from AI: no 20:08:51 1818494 CrossRefSearchJob - AI response: no 20:08:51 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1169 20:08:51 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76060 20:08:51 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT High‐fat diet (HFD)‐induced hepatic injury represents a pathology observed across vertebrates, yet the underlying mechanisms remain incompletely understood. Herein, the present study identifies phosphatidylethanolamine methyltransferase (Pemt), a key enzyme in phosphatidylcholine synthesis, as a critical regulator of mitochondrial homeostasis in HFD‐driven liver injury. Our findings demonstrate that knockdown or knockout of pemt in hepatocytes from large yellow croaker ( Larimichthys crocea ) and in zebrafish ( Danio rerio ) liver markedly induces apoptosis, NOD‐like receptor protein 3 (Nlrp3) inflammasome activation, and mitochondrial dysfunction. Conversely, PEMT overexpression in large yellow croaker hepatocytes effectively attenuates palmitic acid‐induced apoptosis, Nlrp3 inflammasome activation, and mitochondrial dysfunction. Crucially, the present study reveals a direct protein–protein interaction between Pemt and voltage‐dependent anion channel 1 (Vdac1). Notably, VDAC1 overexpression significantly induces reactive oxygen species (ROS)‐dependent apoptosis and Nlrp3 inflammasome activation. Mechanistically, pemt deficiency enhances Vdac1 oligomerization, which in turn triggers apoptosis and Nlrp3 inflammasome activation in hepatocytes. Collectively, our results establish that HFD‐induced downregulation of Pemt promotes mitochondrial dysfunction and Vdac1 oligomerization, thereby exacerbating ROS‐dependent apoptosis and Nlrp3 inflammasome activation, ultimately leading to liver injury. Our findings establish the Pemt‐Vdac1 regulatory axis as a fundamental protective mechanism against overnutrition‐induced liver injury in vertebrates. ] 20:08:51 1818494 AIClient - Response from AI: no 20:08:51 1818494 CrossRefSearchJob - AI response: no 20:08:51 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76060 20:08:51 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3390/inorganics14070180 20:08:51 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [In sulfide-based all-solid-state battery (ASSB) composite cathodes, incomplete solid–solid contact and tortuous ionic/electronic transport pathways increase internal electrode resistance and complicate the interpretation of apparent impedance responses. Here, we present a distribution of relaxation times (DRT)-assisted phenomenological impedance approach for analyzing apparent impedance responses in terms of operational resistance components in composite cathodes based on LiNbO3-coated Ni-rich layered oxide cathode active materials. Electrochemical impedance spectroscopy was performed under controlled electrode loading, state of charge (SoC), and temperature conditions. Loading-dependent DRT analysis parameterized the apparent impedance response into five operational resistance components. The high-frequency components remained nearly unchanged or increased with increasing loading, whereas the mid- to low-frequency components generally decreased, suggesting opposite loading dependences between components tentatively associated with electrode-structural constraints and interface-related processes. SoC-dependent analysis compared relatively SoC-insensitive and SoC-sensitive operational components, while temperature-dependent analysis provided additional comparative constraints for their proposed operational interpretations by comparing their apparent activation energies. Based on these operational component correlations, a semi-empirical framework was developed to describe how the loading-dependent evolution of the DRT-deconvoluted components is reflected in the apparent impedance response. This framework helps reduce the risk of misinterpreting apparent impedance as a uniquely defined interfacial resistance and provides a practical basis for diagnosing structural limitations in high-loading ASSB composite cathodes.] 20:08:52 1818494 AIClient - Response from AI: no 20:08:52 1818494 CrossRefSearchJob - AI response: no 20:08:52 1818494 CrossRefSearchJob - Publication not relevant: 10.3390/inorganics14070180 20:08:52 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-929 20:08:52 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Stars and planets form in dense cores within molecular clouds. These cosmic nurseries are where we see the first formation of interstellar ices. Composed mainly of H2O, CO2 and CO, these ice species and their reaction products are the likely precursors to the complex organic molecules (COMs) that enable the development of life on planets such as our own. Yet their origin and evolution, and the survival of the volatile material trapped within them through the violent star formation process, remain poorly understood. This fundamentally limits our ability to determine how molecules of great astrobiological significance are delivered to planetary bodies. Figure 1: The likely dominant fractionation mechanisms that determine the carbon isotope ratio imprinted in the ice observed in pre- and protostellar environments.The 12C/13C ratio is a sensitive probe of the physical and chemical conditions under which carbon-bearing ices form and evolve. The initial ratio is set by the distinct origins of the two isotopes: 12C is produced rapidly in massive stars, while a fraction of 12C is converted to it’s weaker counterpart 13C via the CNO cycle in later stellar generations. After injection into the interstellar medium (ISM), fractionation processes enrich or deplete one isotope relative to the other. In star-forming regions the isotope fractionation is driven by a combination of gas-phase and grain-surface processes that dominate during different physical and chemical epochs. For the abundant carbon-bearing ices, CO and CO2, the isotope ratio is therefore thought to preserve a chemical memory of the environment in which they formed, making it a valuable diagnostic of chemical evolution across the star-forming process. Understanding carbon isotope fractionation can shine a light on the inheritance or in-situ formation of molecules during different stages of star and planet formation. If the fractionation patterns established in molecular clouds are preserved through the protostellar phase, they may be inherited by protoplanetary disks and ultimately by planetary bodies. Conversely, if isotope ratios are significantly reprocessed during star formation, they instead reflect local conditions rather than primordial inheritance. Distinguishing between these scenarios has important implications for tracing the chemical origin of complex molecules across evolutionary stages, from cold molecular clouds to protostellar environments and planetary systems. Figure 2: JWST WFSS observations allow us to obtain spectra along lines of sight towards tens to hundreds of background sources in a single observation.The unrivalled sensitivity and multiplexing capabilities of The James Webb Space Telescope (JWST), now allows us to probe the chemical environment across star-forming regions with a resolution like never before. I will present 12C/13C ratios derived from JWST NIRCam Wide Field Slitless Spectroscopy (WFSS) observations towards the Chamaeleon I molecular cloud, obtained as part of the Ice Age Early Release Science programme (PID 1309; P.I. M. McClure). Spectra were extracted for 33 background sources along pencil-beam lines of sight through the cloud, in the vicinity of the deeply embedded class 0 protostar Cha MMS1, providing the largest sample of co-spatial ice isotope measurements within a single star-forming region to date. I will examine whether the carbon isotope ratio varies between ice species, whether it shows spatial dependence across the cloud, what this tells us about the chemical evolution across the region, and how the values derived in this study relate to those observed across the broader star and planet formation sequence.] 20:08:53 1818494 AIClient - Response from AI: maybe; CO2 conversion, CO conversion 20:08:53 1818494 CrossRefSearchJob - AI response: maybe; CO2 conversion, CO conversion 20:08:53 1818494 CrossRefSearchJob - Publication relevant (maybe): 10.5194/epsc2026-929 20:08:53 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76454 20:08:54 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Passive radio‐frequency identification technology (RFID) shows potential for non‐line‐of‐sight (NLoS) sensing, but electromagnetic attenuation and reflection losses caused by dielectric absorption and multipath effects reduce detection accuracy and stability. In this work, a flexible passive RFID sensor for NLoS ammonia detection is developed by integrating a spiral antenna with an LC interdigital electrode. MXene is modified with In 2 O 3 nanoparticles to form a gas‐sensitive layer with enhanced surface activity and electronic modulation, thereby strengthening the ammonia‐induced frequency response. Moreover, structural separation of electromagnetic coupling and sensing functions mitigates the nonuniform distribution of coupled electromagnetic energy in the sensing tag. The experimental results demonstrate response characteristics under NLoS dielectric interference, with an S 11 amplitude attenuation of Δ|S 11 |  = 9.19 dB and an ammonia‐induced resonance frequency shift of Δ | f | = 0.48 MHz. On this basis, an S 11 amplitude‐frequency signal separation strategy is innovatively proposed to decouple NLoS dielectric interference signals from gas‐induced response signals, thereby clarifying the frequency perturbation effect of dielectric interference on ammonia sensing signals. Combined with electromagnetically decoupled signals, dielectric interference compensation is performed under conditions of 25°C and 40% RH. NLoS dielectric compensation stabilizes ammonia‐induced frequency shifts, suppresses interference, and enables reliable, rapid, nondestructive detection of quality deterioration in sealed fresh‐food packaging. ] 20:08:54 1818494 AIClient - Response from AI: no 20:08:54 1818494 CrossRefSearchJob - AI response: no 20:08:54 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76454 20:08:54 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76404 20:08:54 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Correction to “Multifunctional Tailoring of Fertilizer Composites Directly Derived From Phosphate Rock”] 20:08:55 1818494 AIClient - Response from AI: no 20:08:55 1818494 CrossRefSearchJob - AI response: no 20:08:55 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76404 20:08:55 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76445 20:08:55 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Micro‐silicon (m‐Si) is a promising next‐generation anode material for lithium‐ion batteries (LIBs), but its practical use is limited by severe volume expansion, particle pulverization, and unstable solid electrolyte interphase (SEI) formation. Recently, solidelectrolyte (SE)‐free m‐Si electrodes in all‐solid‐state batteries (ASSBs) have attracted attention as a strategy to reduce direct contact between SEs and electrode components. This architecture can suppress parasitic interfacial reactions while maximizing the active Si content. However, whether SE‐free m‐Si electrodes can deliver sufficient electrochemical performance and interfacial stability to replace conventional LIB systems remains unclear. Here, we systematically compare the degradation behavior of m‐Si electrodes in liquid‐ and solid‐electrolyte systems by correlating electrochemical performance with interface‐level structural evolution. The results reveal distinct degradation pathways depending on the electrolyte environment. In LIBs, m‐Si undergoes continuous pulverization accompanied by repeated SEI rupture and unstable SEI growth at the particle–electrolyte interface. In contrast, ASSBs promote a film‐like transformation of m‐Si with limited interfacial reactivity, improved structural integrity, and enhanced electrochemical stability. These findings clarify the critical role of electrolyte type in governing Si anode degradation and provide design guidelines for high‐energy‐density Si‐based batteries.] 20:08:56 1818494 AIClient - Response from AI: no 20:08:56 1818494 CrossRefSearchJob - AI response: no 20:08:56 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76445 20:08:56 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1048 20:08:56 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The protostellar stage is a critical phase, early in stellar evolution (less than 0.5 Myr), during which a disk of gas and dust forms, setting the chemical budget forplanet formation. However, unlike the older Class II disks, Class I protostars are deeply embedded in their natal envelopes. With the spectral range, sensitivity, and resolution of JWST-MIRI, we are now capable of characterizing these warm inner (< 10au) planet-forming regions for the first time for the young disks.I will present new JWST-MIRI Cycle 4 observations of Class I protostars in the Ophiuchus, Taurus, and Corona Australis star-forming regions. Spectra showa large variety of molecular emission and absorption features. We apply LTE slab models to determine the column densities and excitation temperatures ofdetected species. By comparing the data with previous VLT-CRIRES observations that spectrally resolve CO emission, we can pinpoint the exact origin of the molecular emission. Only then can we assess the molecular content of the gas in the disks at the earliest stages of planet formation. I will show how we can use the fitted properties of the molecular lines to locate the emission and disentangle disks, outflows, hot corinos, and the range of excitation conditions present in each component. Preliminary results show the presence of H2O, CO2, HCN, and C2H2 species. RNO91, a Class I protostar, is particularly interesting as it is a clear example of a very prominent disk in a Class I system. Overall, our new data reveal the crucial transition between young embedded disks and mature T-Tauri disks.] 20:08:57 1818494 AIClient - Response from AI: no 20:08:57 1818494 CrossRefSearchJob - AI response: no 20:08:57 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1048 20:08:57 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76408 20:08:57 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT The potential of pyroptosis in antitumor immunity is well‐established; however, its clinical translation is hindered by the lack of safe and effective pyroptosis inducers. Here, using a high‐throughput screen of 240 antipsychotic agents approved by the Food and Drug Administration (FDA), we identify the antipsychotic agent penfluridol (PF) as a potent inducer of pyroptosis via a previously unreported molecular pathway. Mechanistically, PF directly binds to and inhibits TTI1, leading to activation of the TNFA signaling via NFKB and subsequent caspase‐8/caspase‐3‐dependent cleavage of GSDME, culminating in pyroptotic cell death. Preclinically, PF not only exhibits monotherapy efficacy in immunocompetent hosts but also acts synergistically with anti‐PD‐1 therapy in both transplanted and spontaneous melanoma and HCC models without inducing systemic toxicity. Clinically, low TTI1 expression coupled with activated TNFA signaling via NFKB correlates with improved immunotherapy response and prolonged overall survival, suggesting its potential utility as a predictive biomarker. Collectively, our work establishes a compelling paradigm for repurposing pyroptosis inducers to stimulate antitumor immunity.] 20:08:58 1818494 AIClient - Response from AI: no 20:08:58 1818494 CrossRefSearchJob - AI response: no 20:08:58 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76408 20:08:58 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75317-w 20:08:58 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Kat5 deficiency in alveolar type II cells licenses STAT6-driven glycolytic reprogramming and pulmonary fibrosis] 20:08:58 1818494 AIClient - Response from AI: no 20:08:58 1818494 CrossRefSearchJob - AI response: no 20:08:58 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75317-w 20:08:58 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76341 20:08:58 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Piezotronics, which enables mechanical stimuli to actively shape adaptive and seamless interactions between electronic systems and ambient environments, is becoming increasingly valuable in the Internet of Things, human‐machine interfaces, and wearable electronics. Interface‐dominated polarization underpins efficient electromechanical transduction in piezotronic sensors; however, it enforces limited performance tunability and hampers multifunctional applications. Here, we use a macroscale tip‐induced strain gradient to trigger a bulk‐dominated polarization in GaN for realizing a tunable piezotronic effect. Such a mechanism uses interface polar symmetry and shielding of bulk piezo‐charges to drive an electrical switching between high‐ and low‐strain sensitivity states. The tunability is preserved across different indenter sizes, while spherical tips with larger radii further enhance the modulation and tuning range due to strain‐gradient size effects. Our piezotronic device has a wide sensitivity tunability window of 24 403, a large pressure sensitivity of 223.2 meV·MPa −1 , and ultrahigh strain sensitivity of 1.43 × 10 8 . Moreover, the piezotronic device shows exceptional mechanical durability up to 10 000 loading cycles and preserves electrical tunability even under dynamic operation. This study enriches piezotronic physics by uncovering the cooperative roles of bulk polarization and interface symmetry in transport modulation, and establishes a viable strategy for continuous and wide‐range performance tunability in a single mechanical sensor. ] 20:08:59 1818494 AIClient - Response from AI: no 20:08:59 1818494 CrossRefSearchJob - AI response: no 20:08:59 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76341 20:08:59 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10501-8 20:08:59 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Myofiber-specific knockout of TGF-β type I receptors in mice concurrently drives muscle hypertrophy, oxidative metabolism, and absolute force] 20:09:01 1818494 AIClient - Response from AI: no 20:09:01 1818494 CrossRefSearchJob - AI response: no 20:09:01 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10501-8 20:09:01 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76312 20:09:01 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Current myocardial infarction (MI) biomaterials often fail to dynamically adapt to the evolving pathological microenvironment (e.g., ROS bursts, hypoxia), lacking both mechanical compatibility and in situ feedback. To overcome these limitations, we developed an albumin hydrogel platform (BST) with a closed‐loop pathological response system. BST is a pH‐responsive hydrogel, functionalized with MRI/CT probes and loaded with mitochondria‐targeted CAT‐SOD enzyme nanogels (CSDT). It forms a self‐repairing scaffold with high shear viscosity (∼300 Pa·s), elasticity, and cardiac‐like mechanics (∼7.5 kPa), stabilizing the infarct wall. Hypoxia‐induced acidosis triggers the release of CSDT nanogels and albumin, enabling mitochondrial ROS scavenging and O 2 generation, while albumin restores tissue osmotic balance. These actions collectively alleviate oxidative stress, modulate immune responses, and promote cardiomyocyte survival by enhancing autophagy and anti‐apoptotic pathways. This inside‐out feedback mechanism reverses oxidative stress and hypoxia, shifts macrophages to a reparative M2 phenotype, and increases angiogenesis by ∼2.5‐fold. In an MI mouse model, BST, with programmable biodegradation (∼3 weeks), restored left ventricular ejection fraction to ∼70% of sham group and improved 28‐day survival by ∼2.5‐fold. Furthermore, BST enables real‐time MRI/CT tracking of material retention and tissue repair dynamically, permitting spatiotemporal control of the infarct microenvironment and advancing precision MI therapy toward clinical translation. ] 20:09:02 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75174-7 20:09:02 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Thermally stable 2D YMnO3 enabling blue visible camouflage with mid-infrared transparency] 20:09:02 1818494 AIClient - Response from AI: no 20:09:02 1818494 CrossRefSearchJob - AI response: no 20:09:02 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76312 20:09:02 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76319 20:09:02 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Intratumoral microbiota‐related metabolites are emerging regulators of tumor immunity, yet their therapeutic potential remains largely unexplored. Here, indole‐3‐pyruvic acid (I3P), a Lactobacillus‐associated tryptophan metabolite, is identified as a molecule associated with immunotherapy response in bladder cancer. Mechanistically, I3P suppresses macrophages ferroptosis and sustains CD8 + T cell activity through an AHR–NF‐κB–SLC7A11 signaling axis that maintains macrophages redox homeostasis. Disruption of AHR or NF‐κB signaling abolishes these effects. Notably, liposomal delivery of I3P facilitates efficient targeting of tumor‐associated macrophages and enhances immunotherapy response without apparent toxicity. Together, these findings identify I3P as an immunoregulatory metabolite that potentiates anti‐tumor immunity and support nanoparticle‐mediated delivery as a promising strategy for immunotherapy sensitization in bladder cancer. ] 20:09:03 1818966 AIClient - Response from AI: no 20:09:03 1818966 CrossRefSearchJob - AI response: no 20:09:03 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75174-7 20:09:03 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75145-y 20:09:03 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Perturbations in lysosome integrity are tightly linked to neurological disorders and ageing, but the underlying pathogenic mechanisms are incompletely understood. Using an unbiased proteomic approach, we here identified the bridge-like lipid transport protein VPS13C/PARK23 as a key component of a global early response pathway to lysosome damage. VPS13C readily binds lysosomes under mechanical or osmotic tension in anticipation of membrane lesions. The latter trigger a conformational change in the protein’s C -terminus, involving its ATG2C domain acting as sensor of damage-induced lipid packing defects. We show that ER-lysosome contacts formed by VPS13C provide critical binding platforms for OSBP/ORPs to enable efficient ER wrapping of damaged lysosomes. A chemical approach to assess directional ER-to-lysosome lipid transport revealed that VPS13C is essential for large-scale lipid delivery to acutely damaged lysosomes to facilitate their repair. Our findings offer new mechanistic insights into how loss-of-function mutations in VPS13C may enhance the risk of Parkinson’s disease. ] 20:09:03 1818494 AIClient - Response from AI: no 20:09:03 1818494 CrossRefSearchJob - AI response: no 20:09:03 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76319 20:09:03 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-950 20:09:03 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The Galilean moon Europa will be intensively explored in a few years by two upcoming space missions: JUICE and Europa Clipper. This icy moon, whose surface is covered by a thick ice shell, has attracted considerable attention because of its potential habitability and the likely presence of a subsurface liquid-water ocean. Despite the detection of potentially endogenic compounds on its surface such as salts or trapped volatiles (e.g. McCord et al. 2002, Fisher et al. 2015, Villanueva et al. 2023, Trumbo and Brown 2023…) the evolution and the current composition of such a subsurface ocean remain poorly constrained.The evolution of Europa’s subsurface ocean was likely shaped by a combination of physical and chemical processes. In particular, interactions between the rocky mantle and the overlying water ocean may have strongly influenced the volatile inventory of the hydrosphere, as well as its pH and salinity. In addition, if Europa’s surface temperature remained sufficiently high shortly after accretion, equilibrium with a primordial atmosphere could also have modified the volatile distribution within the early ocean.In the context of upcoming missions exploring the Galilean system, this study aims to establish links between future observations potentially probing Europa’s ocean composition and the moon’s formation and evolutionary history. Specifically, assuming Europa’s hydrosphere formed from the delivery of ice-rich planetesimals and solids, we investigate how the primordial volatile inventory evolved during the early stages of accretion by modeling the chemical evolution of its hydrosphere.As Europa accumulates mass through accretion of surrounding material and bombardment by impactors, the surface temperature is calculated from a combination of impact heating and thermal input from the circumjovian disk (Bennacer et al. 2025). At each time step, we compute the composition of the primordial atmosphere and ocean, considering:The liquid-vapor equilibrium at the atmosphere-ocean interfaceThe water-rock interactions occurring at the ocean-rocky mantle interfaceThe influence of the rocks remaining in suspension in the ocean as Europa accretes materialChemical equilibria associated with water-rock interactions are calculated using PHREEQ-C (Parkhurst and Appelo, 2013), while atmosphere-ocean exchange is modelled following the framework of Amsler Moulanier et al. (2025). The transport of species throughout the water column is modelled as well, using the diffusion transport scheme available in PHREEQ-C.Our results provide an overview of how Europa’s accreted volatile inventory in the hydrosphere was influenced by the processes occurring during its early evolution. In particular, we highlight the key role of water-rock interactions in controlling the composition of the primordial atmosphere, the chemical evolution of the ocean, as well as its pH and salinity. In the context of the upcoming JUICE and Europa Clipper missions, this work provides various evolutionary pathways for Europa’s ocean composition, depending on the conditions of accretion, the initial volatile inventory and the composition of the rocky mantle. Comparing these results to future measurements potentially indicative of today’s ocean composition, we may better constrain and understand Europa’s evolution and formation conditions.Figure 1 : Evolution of pH (left panel), species abundances (middle panel) and precipitated minerals (right panel) in one of the ocean’s layer during Europa’s accretion process (assuming a slow accretion in a warm CPD). During the modelling process, the ocean is divided in n layers, with here n=10. The results shown in this plot are for the modelled ocean layer highlighted in red on the left-hand side of the figure.Acknowledgement:The authors acknowledge the financial support of the SNSF under SNSF starting grant 218336.References: - McCord, B. T. et al. , J. Geophys. Res., 107(E1), doi:10.1029/2000JE001453, 2002.- P. D. Fischer et al 2015 AJ 150 164- G. L. Villanueva et al., Endogenous CO2 ice mixture on the surface of Europa and no detection of plume activity.Science381,1305-1308(2023).DOI:10.1126/science.adg4270- Samantha K. Trumbo, Michael E. Brown, The distribution of CO2 on Europa indicates an internal source of carbon.Science381,1308-1311(2023).DOI:10.1126/science.adg4155- Alizée Amsler Moulanier et al 2025 Planet. Sci. J. 6 1- Yannis Bennacer et al 2025 Planet. Sci. J. 6 138- Parkhurst, D.L., and Appelo, C., 2013, Description of input and examples for PHREEQC version 3: A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations: U.S. Geological Survey Techniques and Methods 6-A43, xx, 497 p., https://doi.org/10.3133/tm6A43.] 20:09:04 1818966 AIClient - Response from AI: no 20:09:04 1818966 CrossRefSearchJob - AI response: no 20:09:04 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75145-y 20:09:04 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75109-2 20:09:04 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Formation of the activated human spliceosome (B act ) involves major structural rearrangements, leading to the catalytically active U2/U6 RNA core. This process involves at least two intermediates, pre-B act-1 and pre-B act-2 , and is regulated by CDK11-mediated phosphorylation of the U2 snRNP protein SF3B1. However, the mechanisms of this essential step are poorly understood. Here we present the cryo-EM structure of a spliceosome stalled – by the CDK11 inhibitor OTS964 – in a previously undescribed early-activated state, termed pre-B act-OTS , shortly after dissociation of U4 snRNP. In pre-B act-OTS , the U2-SF3B6 protein is retained in a C-terminal region of the super-helical U2-SF3B1 HEAT domain (SF3B1 HEAT ) that clamps the U2/branch-site helix. In contrast, in pre-B act-1 , SF3B6 is repositioned to SF3B1’s N-terminal HEAT repeats, thereby preventing a steric clash of SF3B6 with PRP8 during the pre-B act-OTS -to-pre-B act-1 transition. We infer that the CDK11-mediated phosphorylation of SF3B1 drives the relocation of SF3B6, gating progression to B act formation. In pre-B act-OTS , we also located the RNA helicase DHX15 at the N-terminal region of SF3B1 HEAT , assisted by the SR140/SPF45/CHERP/SUGP1 protein complex. These results suggest the involvement of DHX15 in kinase-mediated proofreading of the early-activated spliceosome, by competing with CDK11’s phosphorylation of SF3B1, and thus with relocation of SF3B6 at SF3B1 HEAT . ] 20:09:04 1818494 AIClient - Response from AI: no 20:09:04 1818494 CrossRefSearchJob - AI response: no 20:09:04 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-950 20:09:04 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-803 20:09:04 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Raman spectroscopy is an established technique for identifying planetary materials through their unique vibrational fingerprints, which also reveal information about their structure and composition [1]. Accordingly, Raman instruments have been proposed for space missions [2-4] and are by now operational, e.g., on the Perseverance rover [5]. With the advent of space-qualified femtosecond lasers [6, 7], techniques such as Time-Domain Raman spectroscopy (TDRS) and Rotational Coherent Raman Scattering (RCRS) have become viable alternatives to detect the Raman-active vibrational fingerprints of solids and gases in space applications. Since these techniques can intrinsically be much more compact, robust, and performant (e.g., because they are not affected by photoluminescence or background illumination), their merits will be discussed in this contribution.In TDRS, ultrafast lasers with pulse durations shorter than the phonon period are used to excite coherent lattice vibrations. Coherent phonons subsequently induce measurable changes in the optical properties of the sample, which are probed subsequently by probe laser pulses in the femtosecond time-domain. In this work, we show that, for different planetary-relevant materials, the Raman-active fingerprints can be detected in transmission, reflection, or scattering geometries (see Figure 1).In RCRS, one utilizes the fact that ultrashort pulses can excite coherent rotational wavepackets of molecules. The RCRS response manifests as periodic bursts called “rotational revivals.” As revivals have periodicities that depend on the molecular constant B, the excited molecules can be clearly identified. In this work, with essentially the same instrumentation as TDRS, we demonstrate that N2 and O2 in air at 295 K and 1 bar can be easily detected in good agreement with simulations [8] (Figure 2). As a result of our work, we envision a novel instrument design that enables the detection of Raman-active fingerprints of planetary materials and atmospheres based on a single ultra-compact femtosecond laser [9].Figure 1. TDRS measurement on α-Quartz. (a) Time-domain changes with isotropic detection in the top panel. (b) Time-domain changes with anisotropic detection in the top. In both figures, the bottom panel shows the corresponding Fourier transform of the time-domain signal with the expected Raman modes marked with an asterisk (*). Figure 2. RCRS measurement in laboratory air at 295 K and 1 bar. Experimental time-domain signal showing rotational revivals of N2 and O2 compared to the simulations (top panel). Corresponding Fourier transformation with rotational level transitions of N2 and O2, shown in green and orange vertical lines, respectively.References [1] J. Blacksberg, G. Rossman, and A. Gleckler, "Time-resolved Raman spectroscopy for in situ planetary mineralogy", Applied Optics 49, 4951-4962 (2010).[2] F. Rull, S. Maurice, I. Hutchinson et. al., "The Raman laser spectrometer for the ExoMars rover mission to Mars", Astrobiology, 17, 627–654 (2017).[3] Y. Cho, U. Böttger, F. Rull et. al., "In situ science on Phobos with the Raman spectrometer for MMX (RAX): preliminary design and feasibility of Raman measurements", Earth Planets Space, 73, 232 (2021).[4] E.A. Cloutis, C. Caudill, E.A. Lalla et. al., "LunaR: Overview of a versatile Raman spectrometer for lunar exploration", Frontiers in Astronomy and Space Sciences, 9, 1016359 (2022).[5] R. Bhartia, L. W. Beegle, L. DeFlores, et al., “Perseverance’s Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) Investigation”, Space Science Reviews 217, 58 (2021).[6] J. Lee, K. Lee, Y.S. Jang et. al., "Testing of a femtosecond pulse laser in outer space", Scientific Reports, 4, 5134 (2014).[7] M. Lezius, T. Wilken, C. Deutsch et. al., "Space-borne frequency comb metrology", Optica, 3, 1381 (2016).[8] T. Szidarovszky, M. Jono, K. Yamanouchi, “LIMAO: Cross-platform software for simulating laser-induced alignment and orientation dynamics of linear-, symmetric- and asymmetric tops”, In: Computer Physics Communications 228, pp. 219–228 (2018).[9] Y. Ha, S.G. Pavlov, G. Rabasovic et. al., "Time-Domain Raman Spectroscopy: An Emerging Technique in Space Exploration?", Journal of Raman Spectroscopy, 56, 9 (2025).] 20:09:04 1818966 AIClient - Response from AI: no 20:09:04 1818966 CrossRefSearchJob - AI response: no 20:09:04 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75109-2 20:09:04 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-431 20:09:05 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Planets form in protoplanetary disks, and their composition reflects the physical and chemical conditions of the regions where they are assembled. Protoplanetary disks partially inherit their chemical content from the parent molecular cloud, but this composition can be substantially altered by chemical reprocessing within the disk. Distinguishing between inheritance and in situ reprocessing is therefore a key step toward understanding the diversity of planetary atmospheres. Class I sources provide an ideal framework to investigate this problem, as they simultaneously host a protoplanetary disk and a protostellar envelope. Since the envelope material is expected to retain a chemical composition closer to that of the natal molecular cloud, comparing the chemistry of the disk and the envelope can provide insights into the relative importance of inheritance and reprocessing. However, disentangling the disk and envelope contributions is challenging and often relies on detailed chemical modeling, where assumptions and uncertainties in the adopted parameters may affect the interpretation of the results. HL Tau is an excellent laboratory in which to study these processes. It is a well-known Class I protostar in Taurus hosting a protoplanetary disk with prominent substructures in the form of concentric rings and gaps. The system also remains embedded within an infalling envelope. Furthermore, a streamer is feeding the system with fresh material. Understanding the role of these streamers in the mass buildup of young disks is crucial, as they may also alter their molecular composition.We present interferometric observations of the molecular content of the HL Tau envelope and protoplanetary disk. These observations allow us to compare molecular abundances and abundance ratios between both components and investigate possible evolutionary signatures. The dataset traces sulfur-bearing molecules (CS, H2S, and SO2, see Figs. 1 and 2), formaldehyde, and deuterated species, all of which are sensitive to the evolutionary stage of the source. In particular, the SO2 emission traces gas released from grain surfaces, likely associated with the impact of the streamer onto the disk. We find strong variations in both column densities and molecular ratios between the envelope and the disk. In particular, the N(CS)/N(H2S) ratio is nearly 50 times larger in the envelope than in the disk. This result suggests that molecular ratios can be used to disentangle envelope emission from that arising in the protoplanetary disk. Overall, the observed chemical differences point to significant chemical evolution between both components. Furthermore, we detect azimuthal variations in several molecular ratios across the disk, which may arise from local differences in the excitation conditions. The detected deuterated species are DCN and DCO+ (J=4-3, see Fig. 3). The two molecules exhibit complementary spatial distributions: DCN shows centrally peaked emission, whereas DCO+ is predominantly concentrated toward the northern part of the disk. This contrasting morphology is consistent with the expected chemical differentiation between both species. DCN is concentrated toward the inner disk, where warmer gas-phase chemistry can efficiently enhance its abundance, while DCO+ preferentially traces colder regions in which deuterium fractionation remains efficient and CO is still present in the gas phase. The north-south asymmetry observed in DCO+ suggests that the physical conditions in the outer disk are not azimuthally uniform, possibly reflecting localized variations in temperature, density, or illumination. Overall, the distinct spatial distributions of DCN and DCO+ indicate that these molecules trace different thermal and chemical regimes within the HL Tau disk. In summary, HL Tau provides evidence for chemical reprocessing at an early evolutionary stage, at least for the species surveyed in this work. A broader observational study is required to fully characterize the observed chemical differences. In addition, a detailed comparison with astrochemical models including deuteration and sulfur chemistry would provide important constraints on the relative roles of inheritance and chemical reprocessing.] 20:09:05 1818494 AIClient - Response from AI: no 20:09:05 1818494 CrossRefSearchJob - AI response: no 20:09:05 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-803 20:09:05 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3389/fchem.2026.1864044 20:09:05 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ The incorporation of artificial intelligence (AI) into energy systems has become a transformative strategy for tackling global energy related challenges, particularly energy vulnerability (EVI). This work examines how AI contributes to mitigating EVI by evaluating its influence across several dimensions, including energy availability, operational efficiency, consumption patterns, renewable energy integration, and overall energy security. Based on insights derived from machine learning (ML) enabled developments in catalytic materials and CO 2 capture technologies, this study demonstrates how data-centric approaches expedite material discovery, refine energy processes, and strengthen system resilience. ML methodologies, including artificial neural networks (ANN), support vector regression (SVR), and ensemble learning techniques, exhibit strong predictive performance in estimating activation energies, adsorption properties, and catalytic efficiencies. These methods substantially decrease reliance on computationally intensive density functional theory (DFT) simulations, thereby enabling rapid identification of high-performance catalyst. Moreover, ML-assisted framework supports the detection of active catalytic sites, these optimization of electrocatalytic processes, and the design of materials for hydrogen evolution, CO 2 reduction, and ammonia synthesis. Simultaneously, ML applications in CO 2 capture systems particularly in metal-organic frameworks (MOFs) facilitate high throughput screening and predictive evaluation of adsorption capacity and structural behaviour. Through the application of quantitative structure-property relationships and feature importance analyses, ML models identify key variables governing CO 2 capture performance, thus lowering computational demands and accelerating material development. The study highlights the rise of integrated, closed-loop systems that combine ML, theoretically modelling, and automated experimentation to streamline catalyst development and carbon capture process. Collectively, the results indicate that AI-driven methodologies substantially improve the efficiency, sustainability, and scalability of advanced energy technologies. These developments not only help mitigate energy vulnerability but also promote the global shift toward low-carbon, resilient energy systems. ] 20:09:05 1818966 AIClient - Response from AI: no 20:09:05 1818966 CrossRefSearchJob - AI response: no 20:09:05 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-431 20:09:05 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76390 20:09:05 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Mucosa, a vital interface between the body and external environment, often suffers from reactive oxygen burden within its microenvironment, leading to various mucosal inflammatory diseases. Drug delivery directly to inflamed mucosal regions offers a promising therapeutic approach, yet efficacy is compromised by inherent physiological clearance mechanisms. Herein, we developed a covalent mucoadhesive nanoantioxidant self‐assembled by a cysteine‐modified short peptide (CR 8 L 10 ) and catalase (CAT) for the treatment of mucosal inflammatory diseases. The obtained CR 8 L 10 @CAT nanocomplexes with a cysteine‐decorated surface enable robust mucoadhesion by forming dynamic disulfide bonds with mucin‐rich mucosa, leading to significantly enhanced CAT retention. Upon intravesical instillation, CR 8 L 10 @CAT with improved urine‐resistant bladder retention, could be used to treat hard‐to‐manage interstitial cystitis/bladder pain syndrome (IC/BPS). Notably, intravesically administered CR 8 L 10 @CAT effectively eliminated excessive reactive oxygen species (ROS) in the bladder mucosa, thereby inhibiting pro‐inflammatory responses, restoring urothelial integrity, and alleviating pain and voiding dysfunction, demonstrating significantly better analgesic effects and superior functional improvement than clinically used intravesical agents. Additionally, inhalation of the mucoadhesive CR 8 L 10 @CAT nanoantioxidant also showed enhanced pulmonary retention to effectively mitigate ROS‐associated inflammation in treating acute lung injury (ALI). This mucoadhesive CR 8 L 10 @CAT nanoantioxidant represents an effective therapeutic strategy to manage different mucosal inflammatory diseases, holding great promise for clinical translation. ] 20:09:06 1818494 AIClient - Response from AI: maybe; CO2 conversion, Electrochemical CO2 conversion 20:09:06 1818494 CrossRefSearchJob - AI response: maybe; CO2 conversion, Electrochemical CO2 conversion 20:09:06 1818494 CrossRefSearchJob - Publication relevant (maybe): 10.3389/fchem.2026.1864044 20:09:06 1818966 AIClient - Response from AI: no 20:09:06 1818966 CrossRefSearchJob - AI response: no 20:09:06 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76390 20:09:06 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76402 20:09:06 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Anaplastic thyroid carcinoma (ATC) is an exceptionally aggressive malignancy with dismal survival, largely due to intrinsic cisplatin resistance. This study identifies a novel mechanism by which small extracellular vesicles (sEVs) promote chemoresistance by enhancing DNA repair via protein lactylation. ATC cells secrete sEVs enriched with Annexin A2 (ANXA2). Upon delivery to recipient ATC cells, ANXA2 stabilizes the interaction between SRC kinase and lactate dehydrogenase A (LDHA), leading to increased LDHA phosphorylation (Y10), enzyme activity, and lactate production. The resulting lactate surge serves as a substrate for lysine lactylation. Ku80 (XRCC5) is identified as a key lactylation target at K265, catalyzed by the acyltransferase KAT5. This lactylation modification strengthens the interaction between Ku80 and its partner Ku70 (XRCC6), stabilizing the initial DNA‐end binding complex in the non‐homologous end‐joining (NHEJ) repair pathway. Consequently, NHEJ efficiency is significantly enhanced, enabling ATC cells to rapidly repair cisplatin‐induced DNA double‐strand breaks and survive treatment. Genetic disruption of the XRCC5‐K265 lactylation site or pharmacological inhibition of LDHA sensitizes ATC xenograft tumors to cisplatin, while in vitro, inhibition of the SRC/LDHA axis produces a similar chemosensitizing effect. This work unveils the ANXA2 + sEV/SRC/LDHA/lactate/XRCC5‐lactylation axis as a critical driver of NHEJ‐mediated chemoresistance in ATC, offering new potential therapeutic targets. ] 20:09:07 1818966 AIClient - Response from AI: no 20:09:07 1818966 CrossRefSearchJob - AI response: no 20:09:07 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76402 20:09:07 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3112726 20:09:07 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Screening and prediction of CO2/CH4 adsorption separation by metal organic frameworks] 20:09:08 1818494 DEBUG DownloadPDFJob - Loading from URL: https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2026.1864044/pdf 20:09:08 1818494 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:09:08 1818966 AIClient - Response from AI: maybe; Host-Guest interactions in supramolecular chemistry 20:09:08 1818966 CrossRefSearchJob - AI response: maybe; Host-Guest interactions in supramolecular chemistry 20:09:08 1818966 CrossRefSearchJob - Publication relevant (maybe): 10.1117/12.3112726 20:09:09 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-564 20:09:09 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The ability to determine the composition of extraterrestrial material directly in space is fundamental for future planetary and astrobiological research. Mass spectrometry provides a versatile approach for the analysis of micrometeorites, cosmic dust, and particles originating from atmospheres and surfaces of distant planetary bodies.HANKA (~ Mass Analyzer for Cosmic Applications ) is a next-generation high-resolution mass spectrometer developed for in-situ space applications under strict resource constraints. It represents a versatile payload candidate for CubeSats up to large-scale missions. HANKA employs an Orbitrap™ electrostatic ion trap analyzer known for exceptional high mass resolution, accuracy and wide mass range (up to 2000 amu).A laboratory prototype of HANKA has been constructed, and its capability to meet the requirements of high-resolution mass spectrometry has been proved experimentally. Measurements of solid particles produced detailed mass spectra with a resolving power exceeding 100 000 (m/ΔmFWHM)​ at the m/z 200, together with valid mass accuracy and isotopic ratio determination.In addition to its analytical performance, the instrument was designed with emphasis to minimize the size, weight, and power requirements. A proposed 4U CubeSat configuration of HANKA incorporates a hypervelocity impact ionization source, the concepts previously demonstrated by the CDA space instrument. Current development efforts to reduce power consumption and size of the electronics.HANKA laboratory prototype (left), and proposed 4U CubeSat configuration (right).In summary, HANKA combines high-resolution mass spectrometry and compact design. The instrument has the potential to provide comprehensive chemical characterization of complex space dust and micrometeorite particles during future space missions. The analytical performance and capabilities of the instrument will be demonstrated through experimental results obtained by the laboratory prototype.Acknowledgements: This work was supported by European Union ERA-Chair Project 101186661 ─ SPACE, and the Czech Science Foundation through grant No. 24-13757L.ReferencesBriois C., Thissen R., Thirkell L., et al.; Planet Space Sci. 2016, 131, 33‐45.Makarov A.; Anal. Chem. 2000, 72, 1156–1162.Sanderink A., Klenner F., Zymak I., et.al.; Anal. Chem. 2023, 95, 3621−3628.Zymak Y., Zabka J., Polášek M., et al.; al.; Aerospace 2023, 10(6), 522.J. Goldsworthy et al., A&A 2003, 409, 1151–1167] 20:09:09 1818966 AIClient - Response from AI: no 20:09:09 1818966 CrossRefSearchJob - AI response: no 20:09:09 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-564 20:09:09 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74986-x 20:09:09 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Mitigating polymer-induced self-inhibition with microenvironment-decoupled Sn(II) single-atom catalysts for pollutant polymerization] 20:09:10 1818966 AIClient - Response from AI: no 20:09:10 1818966 CrossRefSearchJob - AI response: no 20:09:10 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74986-x 20:09:10 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76335 20:09:10 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Germinal centers (GCs) are transient microanatomical structures that coordinate humoral immune responses through dynamic interactions between antigen presenting cells, T follicular helper cells, and B cells. Despite their central importance to immune protection, GC human biology remains difficult to interrogate due to significant inter‐species variability, limited experimental accessibility to primary human tissues, and high interindividual variability. We developed a human immune culture platform that supports spontaneous multicellular organization of human peripheral blood mononuclear cells derived from primary CD19+ B cells, memory CD4+ T cells, and monocyte‐derived dendritic cells into Germinal Center‐like Organoids (GCLOs). These bioengineered GCLOs self‐organize into stable clusters that exhibit stimulus and donor dependent differences in cellular composition and function. We observed the emergence of GC‐like T and B cell subsets, functional IgG output, and the appearance of plasmablast‐like populations. Notably, the age of the donors and the type of stimuli influenced GCLOs architecture, immune subsets, and antibody output. Platform outputs showed correspondence with clinical vaccine responsiveness across human donors, capturing inter‐individual differences in humoral GCLO immune responses to the flu vaccine, including age‐associated trends consistent with immunosenescence. This platform allows scalable investigation of human GC‐associated immune features and provides a tractable framework for studying donor heterogeneity in humoral immunity.] 20:09:12 1818966 AIClient - Response from AI: no 20:09:12 1818966 CrossRefSearchJob - AI response: no 20:09:12 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76335 20:09:12 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76411 20:09:12 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Metabolism alterations significantly influence the behavior of both bacteria and immune cells in the microenvironment of diabetes‐associated biofilm infections, ultimately determining the outcome of infections. Here, we propose a dual‐target nano‐metabolic therapy based on a biomimetic nanoplatform to combat these infections. The nanoplatform, coated with cellular membranes from pre‐infected macrophages and loaded with glucose oxidase (GOx) and L‐arginine (Arg), facilitates targeted drug delivery. Nitric oxide (NO), generated in situ through the catalytic cascade reaction of GOx and Arg, acts as a dual‐target metabolic regulator. It disrupts bacterial carbon and nitrogen metabolism, particularly the tricarboxylic acid (TCA) cycle and amino acid metabolism, effectively eliminating biofilms. Simultaneously, NO modulates macrophage metabolism, shifting it from oxidative phosphorylation to aerobic glycolysis by suppressing TCA cycle enzymes and electron transport chain complexes, while preserving mitochondrial integrity. This energy metabolism transition reverses macrophage immunosuppression, enhancing their phagocytic and invasive functions to promote infection clearance. Experiments with multiple clinical bacterial strains and various diabetic infection models highlight the therapeutic potential of combining metabolism interference with immune modulation, offering new insights for the treatment of diabetes‐associated biofilm infections.] 20:09:13 1818966 AIClient - Response from AI: no 20:09:13 1818966 CrossRefSearchJob - AI response: no 20:09:13 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76411 20:09:13 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1202 20:09:13 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Complex organic molecules are thought to form on icy dust grains in interstellar environments, through a combination of energetic and non-energetic processes driven by photons, electrons, ions, and atoms. Thanks to the James Webb Space Telescope (JWST) and the Atacama Large Millimeter/submillimeter Array (ALMA), we can now map and characterize ices and gases across various star-forming regions, enhancing our understanding of star formation and chemical evolution.European large-scale experimental facilities are crucial for interpreting these observations, especially in simulating space-like conditions. In this presentation, I will discuss recent laboratory findings on the formation and stability of prebiotic molecules on ice grain analogs, which mimic the icy surfaces in space. These studies are key to understanding the potential pathways for the origin of life on Earth, and how we can bridge the gap between experimental data and astrochemical theory.] 20:09:13 1818966 AIClient - Response from AI: no 20:09:13 1818966 CrossRefSearchJob - AI response: no 20:09:13 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1202 20:09:13 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75083-9 20:09:13 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Inhibition of PARPs is a key strategy to treat tumours with defects in homologous recombination (HR), including those with mutations in the tumour suppressor gene BRCA2 . PARP inhibitors generate replication stress, creating a dependence on HR to repair the resulting DNA damage. However, the DNA lesions generated upon PARP inhibition that impede replication fork progression and trigger a requirement for BRCA2 in cell survival are poorly defined. Here, we demonstrate that elevated levels of G-quadruplex (G4) DNA structures is a determinant of genome instability and PARP inhibitor toxicity, while suppressing these structures results in PARP inhibitor resistance. The HUWE1-associated stress response protein HAPSTR1 and BRCA2 function in parallel pathways to PARP1/PARP2 to suppress G4 levels during S-phase. Mechanistically, PARP1/PARP2 disruption in HAPSTR1 or BRCA2-deficient cells leads to G4-replication conflicts, ssDNA gaps, replication-associated DNA damage and genome instability. HAPSTR1 turnover is regulated through HUWE1-dependent proteasome degradation. As such, HUWE1 disruption results in elevated HAPSTR1 and suppression of elevated G4 levels in BRCA2-deficient cells, resulting in PARP inhibitor resistance. Together, these data identify G4 structures as a determinant of PARP inhibitor toxicity, while the HAPSTR1/HUWE1 axis is essential to suppress these structures and confer PARP inhibitor resistance. ] 20:09:14 1818966 AIClient - Response from AI: no 20:09:14 1818966 CrossRefSearchJob - AI response: no 20:09:14 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75083-9 20:09:14 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76002 20:09:14 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Reliably monitoring epidermal electrophysiological signals with precision is essential for advanced healthcare systems and next‐generation human‐machine interfaces. Although stretchable thin‐film electrodes have shown promise for accurate electrocardiogram signal acquisition, the issue of pressure‐induced drift artifacts remains largely overlooked. We developed a stretchable LM thin‐film electrode integrated with an LM strain sensor to quantitatively investigate the drift artifact alongside skin deformation simultaneously and in situ. While most existing research focuses on strain‐induced drift, our findings reveal that the pressure‐induced drift artifact is more significant in stretchable LM electrodes. This work further emphasizes the limitations of the skin‐electrode impedance model in explaining the pressure‐induced drift, and confirms that its primary origin lies in skin potential change. Based on this, we validated an adaptive filtering method using the noise signal reconstructed from strain sensor data to calibrate pressure‐induced drifts. Compared to traditional static filtering methods, it demonstrates superior performance in suppressing irregular pressure‐induced drift artifacts] 20:09:15 1818494 DEBUG DownloadPDFJob - URL: https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2026.1864044/pdf Download location: /opt/downloadPDF/chemwiki_pubstore/fa632a7225130c79605b3999cf7d7786.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:09:09 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2026.1864044/pdf DONE. Final URL after redirect: https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2026.1864044/pdf An error occurred: /opt/downloadPDF/chemwiki_pubstore/fa632a7225130c79605b3999cf7d7786.pdf (Is a directory) java.io.FileNotFoundException: /opt/downloadPDF/chemwiki_pubstore/fa632a7225130c79605b3999cf7d7786.pdf (Is a directory) at java.base/java.io.FileOutputStream.open0(Native Method) at java.base/java.io.FileOutputStream.open(FileOutputStream.java:289) at java.base/java.io.FileOutputStream.(FileOutputStream.java:230) at java.base/java.io.FileOutputStream.(FileOutputStream.java:118) at com.diqa.downloader.Main.downloadPdf(Main.java:195) at com.diqa.downloader.Main.main(Main.java:127) 20:09:15 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3112703 20:09:15 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Large-size, low-frequency customized tuning fork and its application in quartz-enhanced photoacoustic spectroscopy detection] 20:09:15 1818494 AIClient - Response from AI: no 20:09:15 1818494 CrossRefSearchJob - AI response: no 20:09:15 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3112703 20:09:15 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75228-w 20:09:16 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Coaxially nested component with asymmetric fiber resonant cavity and separation membrane for gaseous and dissolved gases detection] 20:09:16 1818494 AIClient - Response from AI: no 20:09:16 1818494 CrossRefSearchJob - AI response: no 20:09:16 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75228-w 20:09:16 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103052 20:09:16 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Performance of the laser frequency comb for the red channel of SALT's high-resolution spectrograph] 20:09:17 1818494 AIClient - Response from AI: no 20:09:17 1818494 CrossRefSearchJob - AI response: no 20:09:17 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103052 20:09:17 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74890-4 20:09:17 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Programmable one-pot polymerase-mediated DNA synthesis via temperature control] 20:09:17 1818966 AIClient - Response from AI: no 20:09:17 1818966 CrossRefSearchJob - AI response: no 20:09:17 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76002 20:09:17 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104493 20:09:17 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [An observational study of systematics affecting low-resolution multiobject transmission spectroscopy using HFOSC-HCT] 20:09:18 1818966 AIClient - Response from AI: no 20:09:18 1818966 CrossRefSearchJob - AI response: no 20:09:18 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104493 20:09:18 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74766-7 20:09:18 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Congenital Dyserythropoietic Anaemia type I (CDA-I) is a rare inherited disorder of erythropoiesis, in which erythroid cells display a unique nuclear phenotype referred to as ‘spongy’ heterochromatin. The molecular basis of CDA-I remains unknown, with most cases of CDA-I caused by mutations in CDAN1 , encoding Codanin-1, or CDIN1 , encoding for Codanin-1-interacting nuclease 1 (CDIN1). To date, very little is known about the function of CDA-I disease proteins and the mechanism by which their associated mutations cause disease. Here, we demonstrate that endogenous CDIN1 interacts with Codanin-1, to form a stable complex. Structural and functional analysis of this complex reveals that the CDIN1-Codanin-1 complex is an RNA nuclease. We shed light on the key mechanistic features of the complex using biochemical and biophysical approaches, complemented by all-atom molecular dynamics (MD) structural simulations. We identify various functional consequences of founder patient mutations on the RNA nuclease activity of CDIN1, providing a framework for understanding the pathophysiology and developing therapeutic strategies for CDA-I. ] 20:09:18 1818494 AIClient - Response from AI: no 20:09:18 1818494 CrossRefSearchJob - AI response: no 20:09:18 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74890-4 20:09:18 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76384 20:09:18 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Hepatocellular carcinoma (HCC) patients with portal vein tumor thrombus (PVTT) are associated with a significantly poor prognosis and limited treatment options. Single‐cell RNA sequencing (scRNA‐seq) has revealed senescent Kupffer cells (sKCs), which are characterized by high levels of p21 expression and enriched in the tumor microenvironment (TME) of HCC‐PVTT. These sKCs exhibit a pronounced senescence‐associated secretory phenotype (SASP), promoting the proliferation and invasion of tumors and crosstalk with cancer‐associated fibroblasts. To target sKCs, a biomimetic nanodelivery system termed SKEV@AAV has been developed. This system comprises adeno‐associated virus (AAV) vectors carrying p21 ‐specific shRNA, encapsulated within sKCs‐derived exosomes (SKEV). SKEV@AAV effectively downregulated p21 , suppressed SASP signaling, and disrupted pro‐tumor interactions between sKCs and cancer‐associated fibroblasts. In an orthotopic PVTT model, SKEV@AAV showed single‐agent antitumor activity and attenuated SASP‐associated inflammatory remodeling. Furthermore, the combination efficacy with anti‐PD‐1 was evaluated in a murine splenic liver‐metastasis model, where SKEV@AAV reduced tumor burden, enhanced CD8 + T‐cell infiltration, decreased regulatory T cells, and promoted memory T‐cell differentiation. Our findings reveal a pivotal role of sKCs in mediating immune suppression in HCC‐PVTT and provide a nanotherapeutic strategy that reverses sKCs' senescence, reprograms the TME, and ultimately enhances antitumor immune activation. ] 20:09:19 1818966 AIClient - Response from AI: no 20:09:19 1818966 CrossRefSearchJob - AI response: no 20:09:19 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74766-7 20:09:19 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104893 20:09:19 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Statistical analysis and future improvement of SHARK-NIR calibration and image processing pipeline] 20:09:20 1818966 AIClient - Response from AI: no 20:09:20 1818966 CrossRefSearchJob - AI response: no 20:09:20 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104893 20:09:20 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74172-z 20:09:20 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Metabolic enzymes perform life-sustaining functions in various cellular compartments. Anecdotally, metabolic activity is observed to vary between genetically identical cells, which impacts drug resistance, differentiation, and immune cell activation. However, no large-scale resource systematically reporting metabolic cellular heterogeneity exists. Here, we leverage imaging-based single-cell spatial proteomics to reveal the extent of non-genetic variability of the human enzymatic proteome, as a proxy for metabolic states. Nearly two fifths of enzymes exhibit cell-to-cell variable expression, and half localize to multiple cellular compartments. Metabolic heterogeneity arises largely autonomously of cell cycling, and individual cells reestablish these myriad metabolic phenotypes over several cell divisions. We reveal through multiplexed imaging that metabolic states are continuous and that the correlation between metabolic pathways is metabolic state dependent. These results establish cell-to-cell enzymatic heterogeneity as an organizing principle of cell biology that may rewire our understanding of drug resistance, treatment design, and other aspects of medicine.] 20:09:21 1818494 AIClient - Response from AI: no 20:09:21 1818494 CrossRefSearchJob - AI response: no 20:09:21 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76384 20:09:21 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74842-y 20:09:21 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Water exchange process and bulk composition regulate slab dynamics and deep earthquakes] 20:09:21 1818966 AIClient - Response from AI: no 20:09:21 1818966 CrossRefSearchJob - AI response: no 20:09:21 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74172-z 20:09:21 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74977-y 20:09:21 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Although cell monolayers typically remain confluent, they can spontaneously develop persistent holes as a result of collective cellular motion. Recent studies on MDCK monolayers cultured on soft substrates have revealed that cells can align to create regions of local nematic order, and topological defects that generate localised mechanical stresses which can spontaneously trigger hole formation. To investigate this process, we develop a continuum multi-phase field model that incorporates internal dissipation and active dipolar forces that drive cell shape anisotropy. Our simulations show that reducing substrate friction enhances cell-cell velocity correlations. In the low-friction regime, topological defects generate spiral flow patterns that concentrate stress and can trigger hole formation. By contrast, in the high-friction regime, holes do not nucleate. We further demonstrate that the number and stability of the holes—whether they close or persist—depends on both substrate friction and cellular activity, through a non-dimensional friction number. These findings highlight the importance of internal dissipation in modelling collective cell motion and the critical role of collective dynamics in maintaining tissue integrity.] 20:09:22 1818966 AIClient - Response from AI: no 20:09:22 1818966 CrossRefSearchJob - AI response: no 20:09:22 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74977-y 20:09:22 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10591-4 20:09:22 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Resorantel: a dual-targeting therapeutic with potent efficacy against Staphylococcus aureus with low potential for drug resistance] 20:09:22 1818494 AIClient - Response from AI: no 20:09:22 1818494 CrossRefSearchJob - AI response: no 20:09:22 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74842-y 20:09:22 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10554-9 20:09:22 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Non-canonical role of Ku80 stabilizes Rab7A to enhance mitolysosome formation and chemotherapy in liver cancer] 20:09:23 1818966 AIClient - Response from AI: no 20:09:23 1818966 CrossRefSearchJob - AI response: no 20:09:23 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10591-4 20:09:23 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10590-5 20:09:23 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Contraction, recombination and innovation shape the dynamic pan-plastome of Astragalus sinicus] 20:09:23 1818494 AIClient - Response from AI: no 20:09:23 1818494 CrossRefSearchJob - AI response: no 20:09:23 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10554-9 20:09:23 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1003 20:09:23 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Sulfur chemistry in the interstellar medium has received renewed attention in recent years, driven by long-standing questions about sulfur depletion between diffuse and dense environments and by recent tentative reports of sulfur-bearing organics such as DMS (CH3SCH3) and/or DMDS (CH3SSCH3) in exoplanet atmospheres. These topics highlight the need to better understand how simple sulfur-bearing molecules are processed and transformed into more complex species. In this context, methanethiol (CH3SH), the direct sulfur analogue of methanol (CH3OH), is an excellent starting point for exploring the formation of more complex sulfur-bearing molecules in interstellar ices.To investigate this chemistry, we performed UV irradiation experiments on pure CH3SH ices under ultra-high-vacuum conditions. The processed ices were monitored by reflection-absorption infrared spectroscopy (RAIRS) and analyzed during warm-up using temperature programmed desorption (TPD), allowing the identification of newly formed species and to evaluate how their abundances change with experimental conditions.We find that UV photochemistry of CH3SH likely produces radicals such as CH3, CH3S, and CH2SH, which recombine to form a variety of sulfur-bearing complex organic molecules. The detected products include CH3CH2SH, CH3SCH3 (DMS), CH3SSCH3 (DMDS), HSCH2CH2SH, and CH3SCH2SH. We further show that the product yields depend on the ice temperature, thickness, and irradiation time. These results provide new experimental constraints on the solid-state network of sulfur and offer guidance for future searches for sulfur-bearing complex organic molecules in astrophysical environments.] 20:09:23 1818966 AIClient - Response from AI: no 20:09:23 1818966 CrossRefSearchJob - AI response: no 20:09:23 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10590-5 20:09:23 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76403 20:09:23 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Soft robotic grippers, with their intrinsic compliance and dexterity, provide safer manipulation of soft and fragile items compared to traditional rigid ones. However, achieving high functional integration within a single soft gripper, particularly for cross‐scale, multi‐particle, and high‐load manipulation, remains a major challenge. Here, a monolithically 3D‐printed, rapeseed‐flower‐inspired self‐reconfigurable soft gripper (SRSG) is presented, which can rapidly reconfigure its finger arrangement within ∼130 ms and achieves precise, reversible switching between diagonal and parallel configurations. The SRSG can be readily incorporated with detachable petal modules to alter the grasping workspace. Leveraging these capabilities enables a range of functions: rotating bulbs of varying diameters, picking fruits, grasping cross‐scale objects ranging from 0.07 to 270 mm (grasping range ratio of ∼3857 times), lifting payloads up to 5.6 kg (∼106 times its own weight), and adaptively enveloping numerous fine particles, multiple live aquatic organisms, and fragile underwater targets. The fully soft, electronics‐free SRSG establishes a self‐reconfigurable grasping paradigm for robust operation in unstructured environments, and opens up new directions for soft robotic end‐effectors.] 20:09:24 1818494 AIClient - Response from AI: no 20:09:24 1818494 CrossRefSearchJob - AI response: no 20:09:24 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1003 20:09:24 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-574 20:09:24 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Introduction.Titan’s atmosphere is a compelling laboratory in which to study organic photochemistry and haze formation in a reduced environment [1]. Starting with the photolysis of the primordial methane and nitrogen, the neutral and charged photochemistry produces a wide range of organic compounds, which eventually aggregate to produce Titan’s ubiquitous refractory haze [2, 3]. Although molecular abundance measurements are mostly limited to species with six or fewer carbon atoms [4], there is also compelling evidence of polycyclic aromatic hydrocarbons (PAHs) in Titan’s upper atmosphere [3, 5, 6]. However, the largest molecules currently included in models of Titan’s photochemistry are substituted benzene species [7]. In this work we give an overview the most promising neutral pathways for forming naphthalene (C10H8), the simplest PAH, and share preliminary results from including these species in an existing model of Titan photochemistry [8, 9].Background.Photochemical models. To decipher Titan’s complex atmospheric chemistry, several groups have assembled photochemical models with networks of hundreds or thousands of neutral and charged reactions, photolysis of major species, haze formation, and condensation [8, 7, 10]. While small molecules with few carbon atoms can be simulated with relatively simple chemical networks, the number of possible isomers for a given stoichiometric formula grows exponentially with the number of carbon atoms. Because of this, photochemistry models have mostly focused on simulating the lowest-energy isomers. Recently, there has been a renewed effort to improve the small-molecule photochemistry by accounting for isomers of three- and four-carbon species [9]. We build on this work to extend the chemical network to larger aromatic species.PAH chemistry. The chemistry of PAHs is of great interest in fields ranging from combustion chemistry [e.g., 11, 12] to interstellar chemistry [e.g., 13], but most of the work on PAH formation and growth has focused on high-temperature conditions [e.g., 11]. Significant effort has been dedicated to determining empirical methods of estimating chemical bahavior of large PAHs in interstellar conditions [e.g., 14], but the chemistry driving the formation of small PAHs is less generalizable and remains an active area of research [e.g., 13]. Similar methods of simulating molecular growth have been used in models of Titan’s photochemistry, but they have been focused on particle formation rather than molecular growth [2]. Recent work in theoretical and experimental chemistry has revealed several potential pathways for forming naphthalene in low-temperature conditions relevant to Titan [e.g., 11, 12], though these reactions are highly dependent on the availability of specific isomers of the reactants. Given the recent advances in Titan isomer chemistry, it is now possible to explicitly simulate the gas-phase formation of naphthalene.Preliminary findings.Naphthalene formation. We have assembled a preliminary chemical network that produces the naphthalene skeleton via neutral gas-phase reactions (see figure). Many of these pathways involve multiple reactions, sometimes producing non-naphthalene C10H8 isomers as intermediate steps. Thus, we find it is critical to explicitly account for different isomers when modeling naphthalene formation.Naphthalene sinks. We have identified no neutral chemical reactions that destroy the naphthalene skeleton, but addition reactions with small radicals like C2H and CN are expected to be rapid. Photolysis of naphthalene also appears ineffective at destroying the naphthalene structure (only ~1% at 193 nm) [15], though to our knowledge there are no experimental branching ratios available. Thus, the naphthalene skeleton can only be destroyed at high altitudes where far UV radiation is most intense.More information required. Although we have assembled a simple network for naphthalene formation, a lack of published data means that many of the inputs to the photochemical model must be estimated. Theoretical or experimental rates are needed for many reactions, and there is little information available regarding rates and products of reactions of large species with abundant small radicals such as H, CH3, C2H, and CN, all of which react rapidly with less abundant species in Titan’s atmosphere. There is a need for UV absorption cross-sections and photolysis branching ratios for most of the species included in the figure. Finally, there is a need for more study into ion-molecule pathways to PAH formation, which may dominate in Titan’s ionosphere [7].Outlook.With an understanding of the chemistry producing the smallest PAHs, it will be possible to begin to bridge the gap between small molecules, which are modeled explicitly, and large PAHs that can be modeled empirically. Models that can simulate PAH formation will be useful to interpret the infrared PAH-related emission features [5, 6], measurements of ionospheric composition and haze [e.g., 3], and the coming measurements from Dragonfly of the haze composition at the surface.Figure. A preliminary low-temperature chemical network for forming the naphthalene skeleton (purple boxes) from precursor species (green boxes) via neutral radical-molecule reactions. Some of these reactions are slow but included for completeness. Most of these reactions also produce many non-PAH products which are not included in this schematic.References.[1] Coustenis 2021. The atmosphere of Titan. Oxford Research Encyclopedias. [2] Lavvas et al., 2011, ApJ 728, 80. Lavvas et al., 2013, PNAS 110, 2729–2734. [3] Haythornthwaite, R.P., et al., 2021. Planet. Sci. J. 2, 26. [4] Nixon, 2024, Earth Space Chem. 8, 406–456. [5] López-Puertas, M., et al., 2013, ApJ 770, 132. [6] Stikkelbroek, 2025, Thesis, Univ. Amsterdam. Stikkelbroek et al. 2025, EPSC-DPS, 1444. [7] Loison, J.C., et al., 2019, Icarus 329, 55–71. [8] Vuitton, V., et al., 2019, Icarus 324, 120–197. [9] Lavvas et al., 2025, EPSC-DPS 220. [10] Willacy et al., 2022, ApJ 933, 230. [11] Mebel et al., 2017, J. Phys. Chem. A 121, 901–926. [12] Yang et al., 2025, ACS Central Sci. 11, 322–330. [13] Tielens, 2026, ACS Earth Space Chem. 10, 942–968. [14] Tielens, 2008, Ann. Rev. Astron. Astrophys. 46, 289–337. [15] Dyakov et al., 2005, J. Phys. Chem. A 109, 8774–8784.] 20:09:24 1818966 AIClient - Response from AI: no 20:09:24 1818966 CrossRefSearchJob - AI response: no 20:09:24 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76403 20:09:24 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10526-z 20:09:24 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. 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Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Electric fields trigger ceramide-dependent vesicle budding and boost the generation of small extracellular vesicles] 20:09:25 1818494 AIClient - Response from AI: no 20:09:25 1818494 CrossRefSearchJob - AI response: no 20:09:25 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-574 20:09:25 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3105695 20:09:25 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? 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Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Data reduction pipeline for the SuMAC millimeter-wave spectrometer at the LMT] 20:09:25 1818966 AIClient - Response from AI: no 20:09:25 1818966 CrossRefSearchJob - AI response: no 20:09:25 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10526-z 20:09:25 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104416 20:09:25 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? 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Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [High-Precision NIR absorption gas cell characterization for GIANO-B via broadband GHz dual-comb spectroscopy] 20:09:26 1818494 AIClient - Response from AI: no 20:09:26 1818494 CrossRefSearchJob - AI response: no 20:09:26 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3105695 20:09:26 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75234-y 20:09:26 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? 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Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Viral modulation of sulfur-oxidizing bacteria drives organic carbon sink formation during primary succession in deglaciating ecosystems] 20:09:26 1818966 AIClient - Response from AI: no 20:09:26 1818966 CrossRefSearchJob - AI response: no 20:09:26 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104416 20:09:26 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76344 20:09:26 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Device‐associated thrombosis remains a critical problem in cardiovascular medicine, often requiring lifelong anticoagulation therapy that paradoxically introduces significant bleeding risks. Here, we present a bioinspired passive flow routing approach that mitigates thrombosis by altering local hemodynamics to reduce stagnation, a primary hemodynamic driver of clot formation. Inspired by flow‐reattachment mechanisms in avian wings and aeronautical slats, we integrate circumferential routing channels into mechanical heart valve housings to redirect a small fraction of forward flow into peri‐ring regions prone to stasis. Computational optimization identifies a configuration that eliminates near‐zero‐shear pockets and reduces exposure to low shear by several orders of magnitude, while maintaining comparable high‐shear exposure relative to control under physiologic conditions. In a fibrin clot deposition assay, the routed design exhibits reduced peri‐ring clot accumulation. In an ovine bypass model without anticoagulation, the routed valve demonstrated improved sinus washout across angiographic assessments and, unlike the control, explant examination after three months showed no macroscopic thrombus at the sewing‐ring interface. Preliminary computational extensions indicate that passive flow routing can alleviate stagnation in additional cardiovascular geometries. These findings establish bioinspired passive flow routing as a hemodynamic design strategy to mitigate thrombosis in cardiovascular devices by targeting the hemodynamic root cause of stasis.] 20:09:26 1818494 AIClient - Response from AI: no 20:09:26 1818494 CrossRefSearchJob - AI response: no 20:09:26 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75234-y 20:09:26 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75118-1 20:09:26 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Solid-state semiconductor lasers underpin technologies from telecommunications and data storage to sensing, medical diagnostics, and emerging quantum communication. Polaritons, hybrid exciton-photon states, have further extended this reach by enabling room-temperature effects such as low-threshold lasing and strong optical nonlinearities. Organic semiconductors are attractive for polaritonics because of their large exciton binding energies, strong nonlinearities, and compatibility with solution processing. However, while solution-processed organic films have been widely explored, the optical cavities used for organic polariton lasing have typically relied on vacuum deposition, limiting truly scalable, low-cost, and accessible device fabrication. Here, we show that all-dielectric organic microcavities fabricated entirely by solution processing, including both the mirrors and active layer, operate in the strong coupling regime, exhibit polariton lasing, and support reversible, detuning-dependent redistribution of the condensate at high excitation densities, establishing an accessible and tunable platform for nonlinear organic polariton physics.] 20:09:27 1818966 AIClient - Response from AI: no 20:09:27 1818966 CrossRefSearchJob - AI response: no 20:09:27 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76344 20:09:27 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10588-z 20:09:27 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Neural effects of expectation violation generalise across sensory modalities] 20:09:27 1818494 AIClient - Response from AI: no 20:09:27 1818494 CrossRefSearchJob - AI response: no 20:09:27 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75118-1 20:09:27 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75246-8 20:09:27 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Continuous nonthermal slab gap formed by progressive tearing beneath Northeast Asia] 20:09:28 1818966 AIClient - Response from AI: no 20:09:28 1818966 CrossRefSearchJob - AI response: no 20:09:28 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10588-z 20:09:28 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3105150 20:09:28 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Updating the control software of the multichannel GRIS spectropolarimeter for simultaneous observations] 20:09:28 1818494 AIClient - Response from AI: no 20:09:28 1818494 CrossRefSearchJob - AI response: no 20:09:28 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75246-8 20:09:28 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10585-2 20:09:28 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Coccolithophores produce 40–60% of marine calcium carbonate, largely through biomineralization of plates which encase cells in a ‘coccosphere’. Despite the importance of coccolithophore calcification in ocean biogeochemistry, its function remains unresolved. A hypothesis suggesting it acts as a physical deterrent has been investigated in grazers and viruses, but not in bacteria. Here we show bacterial pathogenicity in heavily-calcified C. braarudii treated with Gephyrocapsa huxleyi bacterial-pathogen, Phaeobacter inhibens , is only observed with decalcified algae, leading to algal-cell death within as little as 15 hours. Decalcified algal cell mortality is P. inhibens -specific and likely requires close proximity, since treatment with bacterial supernatant or growth-inhibiting concentrations of indole-3-acetic acid shows no detrimental effect. Additionally, scanning electron microscopy shows visible bacterial attachment only on decalcified C. braarudii . These findings provide the first experimental evidence that the coccosphere can act as a barrier against specific bacteria, highlighting its defensive role in coccolithophores. ] 20:09:29 1818966 AIClient - Response from AI: no 20:09:29 1818966 CrossRefSearchJob - AI response: no 20:09:29 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3105150 20:09:29 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74287-3 20:09:29 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The Bipartisan infrastructure law’s impact on drinking water funding for disadvantaged communities] 20:09:29 1818494 AIClient - Response from AI: no 20:09:29 1818494 CrossRefSearchJob - AI response: no 20:09:29 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10585-2 20:09:29 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103800 20:09:29 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Optical design of the MORFEO low order WFS atmospheric dispersion corrector] 20:09:30 1818966 AIClient - Response from AI: no 20:09:30 1818966 CrossRefSearchJob - AI response: no 20:09:30 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74287-3 20:09:30 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75086-6 20:09:30 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Light polarization-based electro-optic memory] 20:09:30 1818494 AIClient - Response from AI: no 20:09:30 1818494 CrossRefSearchJob - AI response: no 20:09:30 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103800 20:09:30 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75210-6 20:09:30 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract The alpine biome, located at higher elevations of mountains worldwide, supports unique biodiversity and provides important ecosystem contributions to people. Despite the growing recognition of mountain biodiversity in international policy frameworks, substantial gaps remain in our understanding of how alpine biodiversity varies across mountain systems, undermining estimates of its conservation value and consequently effective conservation strategies. Here, we curate a dataset on alpine biodiversity, incorporating expert-validated data on species’ elevational ranges for vascular plants, mammals, birds, and reptiles across 32 mountain ranges worldwide. We show that alpine biodiversity hotspots are concentrated in Neotropical regions, while most temperate regions represent coldspots with lower species richness. These patterns persist whether considering species with broad elevational ranges or only those strictly confined to the alpine zone. Unlike the classical latitudinal gradient of biodiversity, alpine richness patterns show no consistent relationship with latitude, highlighting the importance of regional history, landscape structure, and biogeographical processes.] 20:09:30 1818966 AIClient - Response from AI: no 20:09:30 1818966 CrossRefSearchJob - AI response: no 20:09:30 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75086-6 20:09:30 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75061-1 20:09:31 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Modulation of intra-oceanic trench bending and along-trench thermochemical transport by mantle toroidal flow] 20:09:31 1818494 AIClient - Response from AI: no 20:09:31 1818494 CrossRefSearchJob - AI response: no 20:09:31 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75210-6 20:09:31 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-602 20:09:31 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Comets are frozen remnants from our solar system’s birth, 4.6 billion years ago. Comparing their composition with that found in planet-forming disks surrounding young solar analogues (104 — 106 years old) provides a diagnostic of the evolutionary processes that can shape planetary systems. Moreover, it allows the tracing of chemical signatures from parental molecular clouds to planets, bridging the gap between interstellar chemistry and planetary formation (Ceccarelli C., et al., 2023, Mumma M. J., & Charnley S. B.). Nevertheless, systematic comparisons between protostellar environments, disks, and comets remain scarce, often limited to a few target selections (e.g., Drozdovskaya M.et al., 2019; Bianchi E., et al., 2019).In this work, we present the first statistical analysis of [CH3CN]/[CH3OH] abundance ratios across a diverse sample, including 13 comets, 24 low-mass hot corinos, and 6 planet-forming disks. This statistical approach allows us to identify whether inconsistencies are present in existing datasets and provides a more comprehensive view of the various stages of planet formation (Lippi M., et al., 2024).While we observe significant variations of the [CH3CN]/[CH3OH] abundance ratios within the planet-forming disk sample – most likely driven by evolutionary processes – in comets and hot corinos this ratio shows a remarkable similarity (see Figure 1). This suggests that the transition from protostellar envelopes to cometary bodies is driven by a consistent chemistry that converges over time, even when material is continuously reprocessed.Figure 1: Comparison of the [CH3CN]/[CH3OH] abundance ratio in hot corinos, Class 0 to Class II disks, and comets. References: Ceccarelli, C., Codella, C., Balucani, N., et al. 2023, in Astronomical Society of the Pacific Conference Series, Vol. 534, Protostars and Planets VII; Mumma M. J., Charnley S. B., Annual Review of Astronomy and Astrophysics, 2011, 49, 471-524; Drozdovskaya, M. N., van Dishoeck, E. F., Rubin, M., Jørgensen, J. K., & Al- 470; Bianchi, E., Codella, C., Ceccarelli, C., et al. 2019, MNRAS, 483, 1850; Lippi M., Podio L., Codella C., Faggi S., De Simone M., Villanueva G. L., Mumma M. J., Ceccarelli C., The Astrophysical Journal, 2024, 970.] 20:09:31 1818966 AIClient - Response from AI: no 20:09:31 1818966 CrossRefSearchJob - AI response: no 20:09:32 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75061-1 20:09:32 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75046-0 20:09:32 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Biodiversity loss threatens the multifunctionality of ecosystems on which human well-being ultimately depends. Multitrophic species interactions may be key to explaining the ecological consequences of biodiversity loss, but research explicitly linking species interactions and ecosystem multifunctionality remains rare. To fill this gap, we synthesize data from a large-scale biodiversity experiment established in 2009 in subtropical China that manipulates tree species richness (1-24 species). We integrate 11 types of antagonistic and mutualistic species interaction networks, and 34 ecosystem functions associated with a diverse set of species and trophic levels. Our analysis highlights that characterizing the structure of species interaction networks is invaluable for assessing interaction-mediated biodiversity effects and underlying mechanisms. Positive effects of network size align with expected benefits of multitrophic diversity for ecosystem multifunctionality. Positive effects of niche overlap among interacting species and negative effects of highly connected species (i.e. high linkage density) reveal additional, interaction-mediated drivers. The effects of niche overlap suggest benefits of functionally similar species, and the effects of linkage density underscore the importance of specialized interactions in promoting ecosystem multifunctionality. These findings emphasize that ecosystem service provisioning does not only rely on biodiversity across trophic levels, but to a similar degree on how species interact.] 20:09:33 1818966 AIClient - Response from AI: no 20:09:33 1818966 CrossRefSearchJob - AI response: no 20:09:33 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75046-0 20:09:33 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.13140/rg.2.2.26814.65608 20:09:33 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Knowledge, Attitude, and Practice (KAP) survey on paracetamol use among NSU students] 20:09:33 1818494 AIClient - Response from AI: no 20:09:33 1818494 CrossRefSearchJob - AI response: no 20:09:33 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-602 20:09:33 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75150-1 20:09:33 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Improvement of the tensile strength of carbon nanotube fibers to 12.5 GPa by fluidics-induced alignment and densification] 20:09:33 1818966 AIClient - Response from AI: no 20:09:33 1818966 CrossRefSearchJob - AI response: no 20:09:33 1818966 CrossRefSearchJob - Publication not relevant: 10.13140/rg.2.2.26814.65608 20:09:33 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76442 20:09:33 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Correction to “Nanoparticles (NPs)‐Meditated LncRNA AFAP1‐AS1 Silencing to Block Wnt/β‐Catenin Signaling Pathway for Synergistic Reversal of Radioresistance and Effective Cancer Radiotherapy”] 20:09:34 1818494 AIClient - Response from AI: no 20:09:34 1818494 CrossRefSearchJob - AI response: no 20:09:34 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75150-1 20:09:34 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3390/inorganics14070178 20:09:34 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Nickel–iron layered double hydroxide (Ni1−xFex-LDH) with different Ni/Fe ratios was prepared by a simple hydrothermal method and evaluated for ozone decomposition under various humidity conditions. In particular, Ni0.8Fe0.2-LDH showed outstanding activity and stability across a wide humidity range and maintained complete ozone conversion for 10 h even at 90% relative humidity. The combined characterization and catalytic results indicate that the cooperative effect of Ni and Fe increases the specific surface area, tunes the metal valence states, and optimizes the humidity-dependent reaction pathway. More importantly, the catalyst shows clear self-healing behavior after ozone exposure, suggesting that the ozone-induced surface reconstruction is at least partly reversible rather than fully destructive. These results identify an efficient Ni1−xFex-LDH catalyst for ozone abatement and provide insight into the dynamic behavior of hydroxyl-rich layered catalysts under oxidizing atmospheres.] 20:09:35 1818966 AIClient - Response from AI: no 20:09:35 1818966 CrossRefSearchJob - AI response: no 20:09:35 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76442 20:09:35 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.66709/news-322420 20:09:35 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Dutch importers linked to suspect Amazon timber, investigation finds] 20:09:35 1818494 AIClient - Response from AI: no 20:09:35 1818494 CrossRefSearchJob - AI response: no 20:09:35 1818966 AIClient - Response from AI: no 20:09:35 1818966 CrossRefSearchJob - AI response: no 20:09:35 1818494 CrossRefSearchJob - Publication not relevant: 10.3390/inorganics14070178 20:09:35 1818966 CrossRefSearchJob - Publication not relevant: 10.66709/news-322420 20:09:35 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76387 20:09:35 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75087-5 20:09:35 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Type‐II superconductors under magnetic fields remain in a quantum‐coherent, non‐dissipative state as long as vortices are pinned. Dissipation emerges when vortices depin, a process often driven by thermal fluctuations and commonly associated with a melting transition from a vortex solid to a vortex liquid. Macroscopic experiments almost always observe this transition close to the superconducting critical temperature . However, how the vortex solid responds to thermal fluctuations at the scale of individual vortices, far below the melting transition, remains largely unexplored. Here, we use scanning tunneling microscopy (STM) to directly visualize vortices in the iron‐based superconductor (). We observe the formation of vortex liquid droplets—spatially localized regions where vortices exhibit strong thermal fluctuations—at temperatures as low as . These results demonstrate that the onset of dissipation at the local scale occurs at temperatures significantly below in type‐II superconductors, revealing a previously unrecognized regime of vortex dynamics.] 20:09:35 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract In eukaryotes, meters of DNA are packaged into micrometer scale nuclei. Nucleosomes, as the major organizational unit, have been extensively studied in vitro, yet the elaborate 3D structure of chromatin inside cells and its distinct oligo-nucleosome arrangements remain poorly resolved. Here, we combine cryo-electron tomography with template matching, subtomogram averaging and molecular simulations to visualize nucleosomes and chromatin structure inside human cells. We confidently assign individual nucleosomes and report their in-situ structure at secondary structure resolution. By predicting the paths of linker DNA, we identify oligo-nucleosome arrangements and uncover higher-order chromatin structures in situ, including a 37-nm wide, elongated but non-fibrous arrangement. In situ structural biology thus reveals the molecular chromatin organization inside cells and sets the stage for 3D genomics.] 20:09:36 1818966 AIClient - Response from AI: no 20:09:36 1818966 CrossRefSearchJob - AI response: no 20:09:36 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75087-5 20:09:36 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1158 20:09:36 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Saturn’s geologically-active, icy moon Enceladus possesses a subsurface liquid water ocean beneath its icy crust, which is in contact with an unconsolidated rocky core. The ocean water percolates through the core where hydrothermal reactions potentially produce a multitude of organic compounds. Originating deep within the core, chemical species may rise from the ocean floor to the surface and are ejected into space in a plume of gas and ice grains through vents in the icy crust. Thus, markers of chemical or even biological processes occurring in the ocean or at larger depth could be mirrored in the plume composition and detected via spacecraft performing flybys through the plume. In this way, the Cosmic Dust Analyser (CDA; [1]) and the Ion and Neutral Mass Spectrometer (INMS, [2]) onboard the Cassini spacecraft sampled Enceladean material. A variety of organic and inorganic compounds, including salts and silica, and most of the bioessential CHNOP(S) elements have been found in the erupted plume material [3,4,5,6,7,8,9]. The organic fraction of the compounds detected by CDA ranges from simple to complex, and aromatic rings represent a significant component of their molecular structures.The analysis of ice grains from Enceladus [3,4], and returned samples from the carbonaceous asteroids Bennu and Ryugu [10,11,12], have revealed the presence of diverse organic compounds, including aromatic species, amines, and heterocyclic molecules. Aromatic compounds are amongst the most abundant and stable organic compounds in the universe and are thought to be involved in subsurface reaction chemistry on Enceladus [3]. Additionally, the polycyclic aromatic hydrocarbon (PAH) world hypothesis, aromatic groups may have acted as stabilising compounds within early pre-cellular container elements before the evolution of modern lipid membranes [13]. The identification of nitrogen-bearing heterocyclic compounds (i.e. nucleobases) in chondritic material from Bennu and Ryugu [10,11,12], with a more tentative detection of N-heterocycles in Enceladus plume ice grains [3], further highlights the importance of investigating the origin and chemical evolution of aromatic and heterocyclic compounds in extraterrestrial aqueous environments.As part of the ERC-CoG Analogue Icy Moon Simulations (AIMS) project, we simulate high-temperature and -pressure processes under conditions though to be found at Enceladus’ hydrothermal seafloor, and investigate the alteration of organic compounds in such conditions [14]. This project will advance our understanding of the synthesis, degradation, alteration, and evolution of organic, inorganic and biogenic material in the ocean before ejection into the plume, which is vital for missions aiming to detect biosignatures. In this work, we present the latest updates on the organic composition of Enceladean ice grains detected by Cassini [3], as well as results from our new hydrothermal simulations using aromatic and heterocyclic compounds. This allows not only further constraint of Cassini data interpretation, but will also provide feedback for future missions visiting Enceladus, e.g. the future ESA’s L4 mission alongside the ongoing ESA’s JUICE and NASA’s Europa-Clipper missions to Europa.[1]Srama et al. (2004), Space Sci Rev 114, 465-518.[2]Waite et al. (2004), Space Sci Rev (2004) 114, 113-231.[3]Khawaja et al. (2025), Nature Astron. 9, 1662–1671[4]Khawaja et al. (2019), MNRAS 489, 5231–5243[5]Postberg & Khawaja et al. (2018), Nature 558, 564 – 567[6]Postberg et al.(2023), Nature 618, 489–493[7]Postberg et al. (2009), Nature 459, 1098–1101[8]Hsu et al. (2015), Nature 519, 207-210[9]Waite et al. (2009), Nature 460, 487-490[10]Mojarro et al., (2025), PNAS, 122, 49[11]Koga et al. (2026), Nature Astron. 10, 1038[12]Glavin et al. (2025), Nature Astron. 9, 199–210[13]Groen et al. (2012), Orig Life Evol Biosph 42, 295–306[14]Khawaja, Hortal- S.nchez & O'Sullivan et al. (2024), RSTA 382, 2273.] 20:09:36 1818494 AIClient - Response from AI: no 20:09:36 1818494 CrossRefSearchJob - AI response: no 20:09:36 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76387 20:09:36 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3102857 20:09:36 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [CHORUS on GTC: optical design of the UV band spectroscopic chain] 20:09:37 1818494 AIClient - Response from AI: no 20:09:37 1818494 CrossRefSearchJob - AI response: no 20:09:37 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3102857 20:09:37 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3762/bxiv.2026.21.v1 20:09:37 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [We report a practical and efficient method for the synthesis of trichloromethyl ketones from the corresponding methyl ketones via a two-step sequence involving trifluoroacetylation followed by selective chlorination. The key chlorination step proceeds under mild, weakly acidic conditions using sodium hypochlorite pentahydrate, thus avoiding the use of hazardous chlorine gas or strong base. A wide range of aromatic and aliphatic methyl ketones was successfully converted into the corresponding trichloromethyl ketones in high yields. Mechanistic studies suggest that the reaction involves the formation of a 2,2-dichloro-1,3-diketone intermediate and subsequent cleavage of the trifluoroacetyl group. In contrast to previously reported base-mediated halogenation methods, the present protocol exhibits a high regioselectivity and operational simplicity under acidic conditions. This method provides a convenient alternative for the synthesis of trichloromethyl ketones from readily available substrates and is expected to be broadly applicable in organic synthesis and medicinal chemistry.] 20:09:37 1818966 AIClient - Response from AI: no 20:09:37 1818966 CrossRefSearchJob - AI response: no 20:09:38 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1158 20:09:38 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10600-6 20:09:38 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Rise and subsequent fall in neuro-behavioral coupling during learning a skilled reaching task is revealed by generative AI] 20:09:38 1818494 AIClient - Response from AI: no 20:09:38 1818494 CrossRefSearchJob - AI response: no 20:09:38 1818494 CrossRefSearchJob - Publication not relevant: 10.3762/bxiv.2026.21.v1 20:09:38 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74443-9 20:09:38 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract A false-negative diagnosis of cancer can lead to a delay in effective treatment and a poorer prognosis. Here, we use the example of cutaneous melanoma to examine how many years of life are lost after a false-negative diagnosis compared to a primarily correct diagnosis. From 1996 to 2015, 9,063 patients are prospectively registered in the German Central Malignant Melanoma Registry and followed up until December 2023. A false-negative diagnosis is found in 206 (2.3%) patients. The median time to correct diagnosis is 24.0 months. The 10-year recurrence-free survival probabilities are 32.9% for false-negative diagnoses and 76.2% for correct diagnoses (p < 0.001). The 10-year melanoma-specific survival probabilities are 62.1% versus 85.0% (p < 0.001). On average, each person with an initial false-negative diagnosis loses 8.2 years of life compared to people with a correct diagnosis. This high number of years of life lost raises the question of whether similar results also apply to other types of cancer.] 20:09:38 1818966 AIClient - Response from AI: no 20:09:38 1818966 CrossRefSearchJob - AI response: no 20:09:38 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10600-6 20:09:38 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3102485 20:09:38 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Development of near-infrared scanning Fabry-Perot spectrometer for 3D spectroscopy II: improvements to the final model and practical performances for scientific observations] 20:09:39 1818494 AIClient - Response from AI: no 20:09:39 1818494 CrossRefSearchJob - AI response: no 20:09:39 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74443-9 20:09:39 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74984-z 20:09:39 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Energetic electrons in Earth’s inner radiation belt pose significant hazards to spacecraft systems, with the strongest radiation in low-Earth orbit (LEO) mostly confined to the South Atlantic Anomaly (SAA) region. Once considered stable, the inner belt is now understood to exhibit significant variability. Using data from the low-Earth-orbit Macau Science Satellite-1 mission, we report transient distortions of the SAA radiation environments, observationally characterized by enhanced fluxes of energetic electrons outside the traditional SAA radiation region, appearing either attached to or detached from its boundary. We show that these distortions can be explained by large-scale electric-field perturbations that adiabatically alter the electron mirror heights, which can be further modulated by ultra-low-frequency waves. Test-particle simulations successfully reproduce the observational features and provide crucial constraints on properties of the associated electric fields. These findings reveal a distinct manifestation of inner-belt variability, extending the electron radiation risks beyond the expected boundaries of the SAA radiation environments.] 20:09:39 1818966 AIClient - Response from AI: no 20:09:39 1818966 CrossRefSearchJob - AI response: no 20:09:39 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3102485 20:09:39 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3105213 20:09:39 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A laser frequency comb for calibration of G-CLEF: preliminary results] 20:09:40 1818494 AIClient - Response from AI: no 20:09:40 1818494 CrossRefSearchJob - AI response: no 20:09:40 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74984-z 20:09:40 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1021/jacsau.6c00697 20:09:40 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Topology-Informed Design Rules for Deconstructable Thermoset Copolymer Networks] 20:09:40 1818966 AIClient - Response from AI: no 20:09:40 1818966 CrossRefSearchJob - AI response: no 20:09:40 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3105213 20:09:40 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-694 20:09:40 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Ribose is a key biomolecule in the context of the RNA world hypothesis and prebiotic chemistry, yet the photochemistry of carbohydrates remains significantly less explored than that of amino acids or nucleobases. In this work, a theoretical investigation of the excited-state dynamics of β-D-ribopyranose following ultraviolet (UV) excitation using non-adiabatic molecular dynamics simulations is presented.Several electronic structure approaches of different accuracy and computational cost were employed and compared, including CASSCF, MRSF-TDDFT, and OM2/MRCISD. To enable simulations with the MRSF-TDDFT method, a new interface between the ABIN molecular dynamics package and the OpenQP electronic structure program was developed. The suitability of the individual methods for non-adiabatic dynamics simulations of sugar-like systems was critically evaluated.The simulations provide insight into the low-lying excited states of ribose, the topology of the relevant potential energy surfaces, and the dominant relaxation pathways following UV excitation. The excited-state dynamics reveal ultrafast relaxation to the ground state accompanied by competing photochemical processes, including pyranose ring opening, bond dissociation, and return to the initial closed-ring structure.These findings suggest that β-D-ribopyranose can efficiently dissipate absorbed UV energy under the investigated conditions, accompanied by competing reactive and non-reactive relaxation pathways. This work contributes to the understanding of saccharide photochemistry under extraterrestrial conditions and provides a comparison of electronic structure methods for non-adiabatic molecular dynamics simulations of biologically relevant carbohydrate molecules.] 20:09:41 1818494 AIClient - Response from AI: no 20:09:41 1818494 CrossRefSearchJob - AI response: no 20:09:41 1818494 CrossRefSearchJob - Publication not relevant: 10.1021/jacsau.6c00697 20:09:41 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74728-z 20:09:41 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract The ubiquitin-proteasome system (UPS) is the preeminent proteolytic system in eukaryotes. While soluble nucleocytosolic proteins are readily accessed by the UPS, organelle-localised proteins present major, membrane-related accessibility challenges. Cells overcome this problem by employing the conserved AAA+ ATPase Cdc48 to extract organellar proteins to the cytosol, thereby enabling proteasomal degradation. Major Cdc48-dependent proteolytic systems exist at the endoplasmic reticulum, mitochondria and chloroplasts, and are uniquely adapted to deliver protein homeostasis within the respective organelles. We provide a focused comparison of these systems, analysing similarities and differences between them. Better understanding of underlying principles has important implications spanning human health and agriculture.] 20:09:41 1818966 AIClient - Response from AI: no 20:09:41 1818966 CrossRefSearchJob - AI response: no 20:09:41 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-694 20:09:41 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75149-8 20:09:41 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Unlocking stable intermediate states in SrFeO3-δ through voltage control of oxygen non-stoichiometry] 20:09:41 1818494 AIClient - Response from AI: no 20:09:41 1818494 CrossRefSearchJob - AI response: no 20:09:41 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74728-z 20:09:41 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10595-0 20:09:41 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Astrocytes modulate the effects of cocaine in low frequency neuro-vascular oscillations in mice] 20:09:42 1818966 AIClient - Response from AI: no 20:09:42 1818966 CrossRefSearchJob - AI response: no 20:09:42 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75149-8 20:09:42 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75170-x 20:09:42 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Bipolar membranes reveal surface-hydroxyl-structure-dependent water dissociation mechanism] 20:09:42 1818494 AIClient - Response from AI: no 20:09:42 1818494 CrossRefSearchJob - AI response: no 20:09:42 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10595-0 20:09:42 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74895-z 20:09:42 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Glass-like anomalies and unconventional thermoelectric transport in chimney ladder crystals] 20:09:43 1818966 AIClient - Response from AI: no 20:09:43 1818966 CrossRefSearchJob - AI response: no 20:09:43 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75170-x 20:09:43 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75082-w 20:09:43 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Dissipative sensors typically use linear resonators with impedance matching to achieve maximal signal and fast operation. The impedance matching, however, sets an upper limit to the bandwidth of the readout. In this paper, we present a nonlinear resonator performing the readout of a double quantum dot charge state via a charge-sensing quantum dot. We show that by driving the resonator in the nonlinear regime, we achieve a near-unity signal for a dissipative sensor. This despite not satisfying the sensor impedance matching requirements necessary for such large signals in the linear regime. Our experiments, supported by numerical calculations, demonstrate that the signal increase stems from the sensor dissipation shifting the onset of the nonlinear resonator response. By lifting the matching requirement, we open up an avenue to ultra-fast charge detectors as the resonator input-output coupling - setting the detector bandwidth - does not have to match to the typically much slower sensor dissipation rate.] 20:09:43 1818494 AIClient - Response from AI: no 20:09:43 1818494 CrossRefSearchJob - AI response: no 20:09:43 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74895-z 20:09:43 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-495 20:09:43 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [IntroductionAn important component in the exploration of planetary bodies, such as Mars, relies heavily on in-situ mineralogical analysis to uncover the geological history and also investigate potential habitability and organic content. Raman spectroscopy has emerged as a cornerstone technique in planetary in-situ exploration as it enables the identification of minerals and organic compounds [1]. It had its debut in planetary research with two Raman instruments on NASA’s Perseverance rover [2,3] which landed in Jezero crater, Mars, in February 2021 and has been collecting in-situ Raman data from the Martian surface since then. Raman spectroscopy will also be used in upcoming planetary missions, such as JAXA’s Martian Moons eXploration (MMX) mission with the RAman spectrometer for MMX (RAX) [4, 5] and ESA’s ExoMars rover with the RLS (Raman Laser Spectrometer) [1], both operating at 532 nm. In this study we present external-cavity diode lasers (ECDLs) as a promising alternative to frequency-doubled Nd:YAG lasers for space-borne Raman Spectroscopy.BackgroundExternal-Cavity diode lasers (ECDLs) address the growing demand for compact, tunable, and energy-efficient laser sources in planetary Raman spectroscopy, where in-situ mineralogical analysis requires high spectral resolution. Due to their compact design, high electrical-to-optical conversion efficiency, direct electrical modulation capability, and low étendue [6], diode lasers are especially attractive for space-borne instruments. Recent advances in semiconductor technology now enable green-emitting diodes (520–530 nm), offering a flexible, semiconductor-based alternative to traditional frequency-doubled Nd:YAG lasers at 532 nm. By embedding these diodes in an external cavity, we narrow their broad gain spectrum to longitudinal single-mode operation with linewidths of 1cm⁻¹, meeting the requirements for high-precision Raman measurements. The tunability of ECDLs further enables shifted-excitation Raman difference spectroscopy (SERDS), which suppresses fluorescence by capturing spectra at slightly shifted wavelengths (~1 nm), thereby enhancing the signal-to-noise ratio for weak Raman signals in fluorescent backgrounds [7, 8].MethodologyIn this work, we present two external-cavity setups for green diodes, specifically designed for in-situ Raman measurements under planetary conditions:A Littrow configuration, known for its simplicity and reliability (see Figure 1).A filter-based configuration, combining a narrow bandpass filter with a cat’s-eye reflector.By embedding the diodes in an external cavity, we narrow their inherently broad emission to achieve longitudinal single-mode operation with linewidths of 1 cm⁻¹ (Littrow setup), meeting the requirements for high-resolution Raman spectroscopy.For the Littrow configuration, we systematically evaluated eight laser diodes based on emission wavelength, optical output power, and tuning range. The filter-based setup was tested with two diodes to assess their tuning range and maximum single-mode output power. The Littrow configuration was selected as the primary setup due to its established reliability and simplicity, making it ideal for initial testing and characterization of the diodes and ECDL system.Figure 1: Sketch of the Littrow configuration, where the grating is mounted on a piezo actuator for fine adjustment of the cavity length [9].Results Our results with the Littrow setup demonstrate wide tuning ranges across multiple diodes, with three diodes achieving the target wavelength of 532 nm which is demonstrated in Fig. 2. This positions them as direct, semiconductor-based alternatives to frequency-doubled Nd:YAG lasers for instruments like RAX [9]. The filter-based setup exhibits different tuning behavior compared to the Littrow configuration. Furthermore, its maximum single-mode output power is lower, indicating limited suitability for our application. Additionally, initial radiation hardness tests confirm the operational robustness of the diodes, marking a critical step toward flight qualification.Figure 2: Tuning range of eight different diodes in the Littrow setup. Three of them achieving the target wavelength of 532nm.ConclusionThis study bridges the gap between laboratory characterization and practical space applications, demonstrating that green ECDLs are a viable alternative to Nd:YAG lasers for next-generation planetary instruments. Key findings show that the Littrow setup is better suited for such applications than the filter-based configuration. The compact size, efficiency, and tunability of ECDLs make them a compelling alternative to traditional solid-state lasers, while their compatibility with 532 nm ensures seamless integration into existing mission instruments. Additionally, their ability to perform SERDS further enhances their utility, enabling high-sensitivity Raman measurements even in the presence of strong fluorescence.References:[1]: Rull et al., 2017[2]: Bhartia et al., 2021[3]: Lopez-Reyes et al., 2025[4]: Hagelschuer et al., 2022[5]: Schröder et al., this conference[6]: Angel et al., 1995[7]: Zhao et al., 2002[8]: Böttger et al., 2017[9]: Lukaszewski et al., in revision] 20:09:44 1818494 AIClient - Response from AI: no 20:09:44 1818494 CrossRefSearchJob - AI response: no 20:09:44 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-495 20:09:44 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103923 20:09:44 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [RISTRETTO: assembly and testing of the seven-spaxel, high-resolution, diffraction-limited spectrograph] 20:09:44 1818966 AIClient - Response from AI: no 20:09:44 1818966 CrossRefSearchJob - AI response: no 20:09:44 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75082-w 20:09:44 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75225-z 20:09:44 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A single-cell atlas of alternative wing development in two hemipteran species] 20:09:45 1818494 AIClient - Response from AI: no 20:09:45 1818494 CrossRefSearchJob - AI response: no 20:09:45 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103923 20:09:45 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3102367 20:09:45 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [100GbE data acquisition and online triggering for KID pulse detection at µs timescale] 20:09:46 1818966 AIClient - Response from AI: no 20:09:46 1818966 CrossRefSearchJob - AI response: no 20:09:46 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75225-z 20:09:46 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.3762/bjoc.22.77 20:09:46 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ Spacer length is a key molecular parameter governing the self-assembly of short peptides. Here, we investigate isoleucine-cysteine-alanine (ICA) tripeptides containing carbon spacers of 6, 3, or 0 methylene units linking the peptide backbone to a hydrophobic naphthalene (Nap) π-block. Using complementary spectroscopic and microscopic techniques, we show that spacer length controls the balance between conformational flexibility and directional non-covalent interactions, thereby dictating assembly pathways and material properties. The results establish a correlation between spacer length and assembly propensity, with the longest spacer (C 6 ) consistently promoting aggregation more effectively than the intermediate analogue (C 3 ), whereas peptides containing the rigid C 0 -spacer fail to develop ordered nanostructures. These findings identify spacer length as a powerful design parameter for tuning peptide self-assembly across multiple length scales. ] 20:09:46 1818494 AIClient - Response from AI: no 20:09:46 1818494 CrossRefSearchJob - AI response: no 20:09:46 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3102367 20:09:46 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1288 20:09:46 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Ices in embedded protostellar disks provide one of the earliest observable records of the volatile material available for planet formation, but their interpretation is complicated by the surrounding infalling envelope. In particular, it remains unclear whether infrared ice absorption features observed toward highly inclined Class 0/I systems primarily trace disk ices or envelope ices. We investigate this question using RADMC-3D radiative transfer models of parameterized disk+envelope structures. We introduce three cases for each model to separate the intrinsic disk-ice signal from the effects of envelope scattering and thermal emission, as well as envelope ice absorption. We find that the H$_2$O 3 $\mu$m and CO$_2$ 4.3 $\mu$m bands are strongly affected by the envelope because they lie in a scattering-dominated wavelength regime. In contrast, the CO$_2$ 15.2 $\mu$m band is dominated by more direct thermal emission and remains a more robust tracer of disk ices across most parameter variations. Other ice features in between show behavior that reflect their absorption and scattering opacities at their respective wavelengths. Disk contribution ratios in the observed ice optical depths are the highest for the extracted spectra from the disk center, and decrease as one moves farther away in each direction. Surprisingly, apertures located outside the disk show signatures from the ices in the disk, showcasing the impact of scattering. We confirm that $\sim70^\circ$ is the critical angle for the best view of ices in the disk for short wavelength features. Moreover, our results show that the inferred disk contribution depends strongly on envelope infall rate, disk mass, size and vertical extent. Higher envelope infall rate results in higher envelope contribution, bringing disk contribution to almost non-existent at ^{-5} M_\odot{\rm yr}^{-1}$ for the scattering-dominated bands, while for the 15 $\mu$m feature disk contribution still stays significant. Meanwhile, higher disk mass does not necessarily result in higher disk contribution to the ice absorption features. Grain size distribution, especially in the envelope, may also significantly alter the contribution ratios since they are an important factor in determining absorption and scattering opacities. We then proceed to reveal the ice inventory in the ‘Butterfly Star’ IRAS04302, and reveal spatial distribution of its ice features with an empirical approach before performing detailed radiative transfer modeling.] 20:09:47 1818966 AIClient - Response from AI: maybe; Host-Guest interactions in supramolecular chemistry 20:09:47 1818966 CrossRefSearchJob - AI response: maybe; Host-Guest interactions in supramolecular chemistry 20:09:47 1818966 CrossRefSearchJob - Publication relevant (maybe): 10.3762/bjoc.22.77 20:09:47 1818494 AIClient - Response from AI: no 20:09:47 1818494 CrossRefSearchJob - AI response: no 20:09:47 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1288 20:09:47 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76330 20:09:47 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Longitudinal, long‐term molecular monitoring is critical for personalized medicine, yet protein adsorption in biofluids rapidly fouls bio‐interfaced sensors and restricts analyte access to sensing regions. Despite advances in antifouling coatings and regeneration strategies, repeated restoration of surface‐enhanced Raman spectroscopy (SERS) sensitivity in static, protein‐rich media remains difficult without degrading nanogap integrity, limiting longitudinal sensing. This work introduces a regenerative molecular sensor based on multiresonant plasmonic nanoprotruding meshes (MPNMs) that co‐localizes SERS sensing and nanocavitation‐based actuation within nanogaps anchored on a biocompatible polymeric mesh. The nanogaps are engineered to support an electric‐dipole resonance for SERS enhancement and a magnetic‐dipole resonance for photothermal conversion, enabling femtosecond‐laser‐triggered nanocavitation within SERS‐active nanogaps. Upon femtosecond‐laser irradiation, collapse of vapor nanobubbles (≈200 ns lifetime) generates thermomechanical forces that detach and displace foulants with micron‐scale precision to regenerate the nanogaps while preserving nanomorphology and optical performance. In undiluted human serum, regeneration restores detection limit for the Pseudomonas aeruginosa virulence factor pyocyanin from 2.0 µ m to a clinically relevant 3.9 n m after 24 h of fouling. Repeated regeneration cycles enable spatiotemporal profiling of dynamic molecular signatures from P. aeruginosa biofilms in wound models over 24 h, establishing a self‐regenerating platform for longitudinal molecular monitoring in protein‐rich biosystems. ] 20:09:48 1818494 AIClient - Response from AI: no 20:09:48 1818494 CrossRefSearchJob - AI response: no 20:09:48 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76330 20:09:48 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75099-1 20:09:48 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Fluid-mediated nuclearity control in heterogeneous polyolefin catalysis] 20:09:49 1818966 DEBUG DownloadPDFJob - Loading from URL: 20:09:49 1818966 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:09:49 1818494 AIClient - Response from AI: no 20:09:49 1818494 CrossRefSearchJob - AI response: no 20:09:49 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75099-1 20:09:49 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.202600080 20:09:49 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Three‐dimensional (3D) graphene offers exceptional electrical and mechanical properties at the material level, yet these advantages are often compromised during system integration due to the lack of a reliable, miniaturizable interfacial method with conventional electronics. In particular, mismatched interfacial properties and the absence of robust interconnection techniques have hindered seamless implementation at the system level, stalling progress toward miniaturization and practical applications. Here, we present a localized interconnection method in which conventional silver nanoparticles (Ag‐NPs) ink is deposited into a reservoir‐structured metal electrode under a controlled thermal environment, selectively accelerating solvent evaporation to yield high electrical conductivity and mechanical robustness. This approach enables the formation of micrometer‐scale interconnections with minimal spreading, while achieving low contact resistance (7.14 Ω), stable impedance (< 10 5  Hz), and high mechanical durability under repeated bending at a 2 mm radius of curvature, along with excellent environmental stability. Finally, we applied the proposed method to high‐performance wearable multi‐modal motion sensors and electrochemical biosensors, demonstrating its utility in emerging applications, such as human‐robot‐interaction and point‐of‐care diagnostics. ] 20:09:50 1818494 AIClient - Response from AI: no 20:09:50 1818494 CrossRefSearchJob - AI response: no 20:09:50 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.202600080 20:09:50 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75068-8 20:09:50 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Structure-guided reprogramming of DELLA turnover for a sustainable Green Revolution in rice] 20:09:50 1818966 DEBUG DownloadPDFJob - Not a PDF file: /opt/downloadPDF/chemwiki_pubstore/b987adacb7b0b70287271fdf9f51e766.pdf. Deleted. 20:09:50 1818966 DEBUG DownloadPDFJob - URL: Download location: /opt/downloadPDF/chemwiki_pubstore/b987adacb7b0b70287271fdf9f51e766.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:09:50 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: An error occurred: invalid argument (Session info: chrome=147.0.7727.101) Build info: version: '4.41.0', revision: '9fc754f' System info: os.name: 'Linux', os.arch: 'amd64', os.version: '6.8.0-60-generic', java.version: '21.0.7' Driver info: org.openqa.selenium.chrome.ChromeDriver Command: [98fd262bd51b73de5f00fea3c951d1a6, get {url=}] Capabilities {acceptInsecureCerts: false, browserName: chrome, browserVersion: 147.0.7727.101, chrome: {chromedriverVersion: 147.0.7727.117 (474cc805edd..., userDataDir: /tmp/org.chromium.Chromium....}, fedcm:accounts: true, goog:chromeOptions: {debuggerAddress: localhost:45575}, goog:processID: 1819290, networkConnectionEnabled: false, pageLoadStrategy: normal, platformName: linux, proxy: Proxy(), se:cdp: ws://localhost:45575/devtoo..., se:cdpVersion: 147.0.7727.101, setWindowRect: true, strictFileInteractability: false, timeouts: {implicit: 0, pageLoad: 300000, script: 30000}, unhandledPromptBehavior: dismiss and notify, webauthn:extension:credBlob: true, webauthn:extension:largeBlob: true, webauthn:extension:minPinLength: true, webauthn:extension:prf: true, webauthn:virtualAuthenticators: true} Session ID: 98fd262bd51b73de5f00fea3c951d1a6 org.openqa.selenium.InvalidArgumentException: invalid argument (Session info: chrome=147.0.7727.101) Build info: version: '4.41.0', revision: '9fc754f' System info: os.name: 'Linux', os.arch: 'amd64', os.version: '6.8.0-60-generic', java.version: '21.0.7' Driver info: org.openqa.selenium.chrome.ChromeDriver Command: [98fd262bd51b73de5f00fea3c951d1a6, get {url=}] Capabilities {acceptInsecureCerts: false, browserName: chrome, browserVersion: 147.0.7727.101, chrome: {chromedriverVersion: 147.0.7727.117 (474cc805edd..., userDataDir: /tmp/org.chromium.Chromium....}, fedcm:accounts: true, goog:chromeOptions: {debuggerAddress: localhost:45575}, goog:processID: 1819290, networkConnectionEnabled: false, pageLoadStrategy: normal, platformName: linux, proxy: Proxy(), se:cdp: ws://localhost:45575/devtoo..., se:cdpVersion: 147.0.7727.101, setWindowRect: true, strictFileInteractability: false, timeouts: {implicit: 0, pageLoad: 300000, script: 30000}, unhandledPromptBehavior: dismiss and notify, webauthn:extension:credBlob: true, webauthn:extension:largeBlob: true, webauthn:extension:minPinLength: true, webauthn:extension:prf: true, webauthn:virtualAuthenticators: true} Session ID: 98fd262bd51b73de5f00fea3c951d1a6 at org.openqa.selenium.remote.ErrorCodec.decode(ErrorCodec.java:169) at org.openqa.selenium.remote.codec.w3c.W3CHttpResponseCodec.decode(W3CHttpResponseCodec.java:142) at org.openqa.selenium.remote.codec.w3c.W3CHttpResponseCodec.decode(W3CHttpResponseCodec.java:49) at org.openqa.selenium.remote.HttpCommandExecutor.execute(HttpCommandExecutor.java:223) at org.openqa.selenium.remote.service.DriverCommandExecutor.invokeExecute(DriverCommandExecutor.java:216) at org.openqa.selenium.remote.service.DriverCommandExecutor.execute(DriverCommandExecutor.java:174) at org.openqa.selenium.remote.RemoteWebDriver.execute(RemoteWebDriver.java:604) at org.openqa.selenium.remote.RemoteWebDriver.get(RemoteWebDriver.java:372) at com.diqa.downloader.Main.main(Main.java:112) 20:09:50 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10610-4 20:09:50 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Tartrazine, along with many other absorbing molecules, has recently emerged as a promising tissue-clearing agent for achieving transient and reversible optical transparency in live animals. In this mini-review, we describe the fundamental physical origins of tissue opacity, extract engineering principles guiding the design of next-generation dye-based clearing agents, and summarize recent advances in dye-enabled in vivo tissue clearing. We also discuss current challenges and offer forward-looking perspectives to inform future research.] 20:09:51 1818966 AIClient - Response from AI: no 20:09:51 1818966 CrossRefSearchJob - AI response: no 20:09:51 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10610-4 20:09:51 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.13140/rg.2.2.23564.07045 20:09:51 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Pincol Rearrangement] 20:09:51 1818494 AIClient - Response from AI: no 20:09:51 1818494 CrossRefSearchJob - AI response: no 20:09:51 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75068-8 20:09:51 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104793 20:09:51 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [An updated and complete design of the jockey club spectroscopy survey system] 20:09:52 1818494 AIClient - Response from AI: no 20:09:52 1818494 CrossRefSearchJob - AI response: no 20:09:52 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104793 20:09:52 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75142-1 20:09:52 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Seconds-scale exfoliation of high-quality 2D crystals enabled by polycyclic aromatic hydrocarbon radical anion-mediated organoalkali intercalation] 20:09:52 1818966 AIClient - Response from AI: no 20:09:52 1818966 CrossRefSearchJob - AI response: no 20:09:52 1818966 CrossRefSearchJob - Publication not relevant: 10.13140/rg.2.2.23564.07045 20:09:52 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.202600039 20:09:52 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Thrombotic vascular diseases contribute to significant global mortality, yet current therapeutic strategies face persistent challenges, including bleeding risks, suboptimal efficiency, and procedural complexity. Here, we report a micro‐explosive thermochemical thrombolysis (METCT) therapy via proximal injection of liquid alkali metal (LAM) encapsulated in dimethyl silicone (LAM@oil), which enables prompt, efficient, and safe vascular recanalization within an ultrafast timeframe (< 90 s). This LAM@oil system effectively disrupts thrombus tissue through a synergistic triple‐action mechanism: mechanical micro‐explosions forces, alkaline ablation due to highly localized exothermic chemical reactions, and thermal thrombolysis mediated by elevated temperature. Upon thrombolysis completion, the non‐toxic reaction byproducts (sodium and potassium ions) exhibit physiologically biocompatible and metabolizable effects. Critically, the LAM@oil demonstrates significantly higher thrombolytic efficacy compared to clinically available thrombolytic drugs (residual thrombus area percent 10.87% ± 7.16% for LAM@oil vs. 80.86% ± 13.32% for urokinase), with no associated bleeding risks. This strategy opens a byproduct‐green, cost‐effective, and high‐efficiency alternative to conventional thrombolytics, holding big potential for clinical translation in acute thrombosis management.] 20:09:53 1818494 AIClient - Response from AI: no 20:09:53 1818494 CrossRefSearchJob - AI response: no 20:09:53 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75142-1 20:09:53 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75126-1 20:09:53 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Plasmodium falciparum oocysts undergo an explosive biomass increase during development in Anopheles mosquitoes, a dramatic growth process likely promoted by as-yet unknown nutrients scavenged from the mosquito. We previously observed in blood-stage parasites, that the amino acid transporter PfApiAT2, although dispensable, regulates proline homeostasis and mediates resistance to halofuginone, a potent proline-tRNA synthetase inhibitor. Here, we demonstrate that PfApiAT2 is a proline-specific transporter essential for early oocyst development in Anopheles gambiae . Halofuginone-resistant pfapiat2 -mutant parasites form stunted oocysts severely defective in sporozoite production. This phenotype is recapitulated in PfApiAT2-knockout parasites that undergo a complete block in sporogony, forming oocysts that stall and degenerate. Remarkably, this growth defect can be rescued by nutrient supplementation to the mosquito vector. By identifying an amino acid transporter essential for oocyst growth, our data unveil a vulnerability in P. falciparum transmission, revealing a critical nutritional dependency of the parasite on its mosquito vector. ] 20:09:53 1818966 AIClient - Response from AI: no 20:09:53 1818966 CrossRefSearchJob - AI response: no 20:09:53 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.202600039 20:09:53 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75085-7 20:09:53 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Observation of non-adiabatic non-Abelian braiding of matter waves] 20:09:53 1818494 AIClient - Response from AI: no 20:09:53 1818494 CrossRefSearchJob - AI response: no 20:09:53 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75126-1 20:09:53 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74917-w 20:09:54 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Oral microbiome modulation mitigates hyperglycemia exacerbation in gestational diabetes mellitus] 20:09:55 1818494 AIClient - Response from AI: no 20:09:55 1818494 CrossRefSearchJob - AI response: no 20:09:55 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74917-w 20:09:55 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.66709/news-322242 20:09:55 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Illegally sourced timber from Cambodia and Laos continues to enter Vietnam’s supply chains despite recent efforts to tighten legality controls, according to a new report from U.K.-based watchdog the Environmental Investigation Agency (EIA). Falsified paperwork, manipulated harvesting quotes, and intermixing of timber from multiple sources are just some of the ways well-established criminal networks perpetuate […]] 20:09:55 1818966 AIClient - Response from AI: no 20:09:55 1818966 CrossRefSearchJob - AI response: no 20:09:55 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75085-7 20:09:55 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75213-3 20:09:55 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Brain-computer interfaces (BCIs) promise to extend human movement capabilities by enabling direct neural control of supernumerary effectors, yet integrating augmented commands with multiple degrees of freedom without disrupting natural movement remains a key challenge. Here, we propose a tactile-encoded BCI that leverages sensory afferents through a tactile-evoked P300 paradigm, allowing reliable decoding of supernumerary motor intentions even when superimposed with voluntary actions. The interface was evaluated in a multi-day experiment comprising a single motor recognition task to validate baseline BCI performance and a dual-task paradigm to assess the potential influence between the BCI and natural human movement. The interface achieved real-time and reliable decoding of four supernumerary degrees of freedom, with significant performance improvements after three days of training. After training, performance did not differ significantly between the single-task and dual-task conditions, and natural movement remained unimpaired during concurrent supernumerary control. Lastly, the interface was deployed in a movement augmentation task, demonstrating its ability to command two supernumerary robotic arms for functional assistance during bimanual tasks. These results establish a neural interface paradigm for movement augmentation through stimulation of sensory afferents, expanding motor degrees of freedom without impairing natural movement.] 20:09:55 1818494 AIClient - Response from AI: no 20:09:55 1818494 CrossRefSearchJob - AI response: no 20:09:55 1818494 CrossRefSearchJob - Publication not relevant: 10.66709/news-322242 20:09:55 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75219-x 20:09:55 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Pangenomes of several species have been assembled recently, facilitating the detection and genotyping of structural variants. As part of the FarmGTEx Project, we previously constructed a Holstein pangenome (H20D) based on 40 phased haploid assemblies. Here, we use this breed specific pangenome to genotype 93,059 structural variants from whole-genome sequences of 1,571 cattle. We then develop a Holstein pangenome variation imputation reference panel we name HolPIP. Leveraging HolPIP, we impute 86.65% (68,354/78,886) of structural variants for 50,299 bulls with Beagle R² ≥ 0.8. Using these imputed structural variants and phenotypes for 43 complex traits, we conduct GWAS, identifying 1,225 structural variant-trait associations. We next use fine-mapping to prioritize 32 high-confidence candidate structural variants, including a 75-bp deletion in ANKRD11 linked to dairy form, rump width, and stature, as well as an insertion in DHX32 associated with RNA metabolism. Compared to SNPs across various functional annotations, structural variants show a stronger genome-wide enrichment across most complex traits in cattle, suggesting that structural variants may have an important contribution to the genetic basis of dairy traits. ] 20:09:55 1818966 AIClient - Response from AI: no 20:09:55 1818966 CrossRefSearchJob - AI response: no 20:09:55 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75213-3 20:09:55 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75180-9 20:09:55 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Catalytic Promiscuity and Cascade Reaction Mechanism of Ketosteroid Isomerases for Addition Reactions of Cyclic Enones] 20:09:56 1818494 AIClient - Response from AI: no 20:09:56 1818494 CrossRefSearchJob - AI response: no 20:09:56 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75219-x 20:09:56 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-993 20:09:56 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The Kronian moon Enceladus harbours a liquid ocean beneath its icy crust, making it of particular scientific interest. Data collected by the Cassini orbiter suggest the presence of the chemicals necessary to develop life as we know it, making it a key driver behind ESA’s Voyage 2050 programme. Libration-enhanced tidal heating keeps the moon’s interior sufficiently warm to sustain its liquid ocean (Hemingway et al., 2018). The icy crust thins at its southern pole, where fissures, dubbed the ‘Tiger Stripes’, jet water from the liquid ocean to the planet's surface, akin to geysers (C. C. Porco et al., 2006; Hemingway and Mittal, 2017). The jetted liquid water expands into droplets and freezes as it experiences the vacuum of space. The water-ice grains are distributed; the heavier grains fall back to the moon’s surface, while the lighter ones escape Enceladus and feed Saturn’s E-ring (Postberg et al., 2018). Hence, Enceladus’ surface undergoes a continuous renewal from water-ice grain depositions either from direct plume deposition or E-ring bombardment (Southworth et al., 2018). Near the plume’s source, the deposition could amount to 1mm/year with particle sizes ranging from 0.6 to 15 micrometre (Spitale et al., 2015).These water-ice grains are unconsolidated and undergo a consolidation process over long periods of time (Blackford, 2007; Molaro et al., 2019), called sintering, which largely follows the processes described by Swinkels and Ashby (1981). Initially, two grains are brought into contact, followed by a neck-growth stage driven by multiple mechanisms until the grains become difficult to distinguish over time. The pores become isolated and closed off as they shrink over a longer period, resulting in the densification of the bulk, see figure 1.Figure 1: The blue circles represent water-ice grains sintering together over time. The initial stage highlights an initially small neck formation, which grows in stage 1, through two highlighted transport processes until the pores coalesce in the final stage.The grain size and local temperature significantly affect the sintering time. The average surface temperature of 72K prevents significant sintering over the geological timescale of the moon (Molaro et al., 2019). However, the elevated temperatures near the plumes would allow micron-sized crystalline water-ice grains to sinter over relatively short geological timescales (~15 years) and withstand pressures on the order of ten megapascals, indicating that Enceladus’ surface may exhibit locally different mechanical properties (Southworth et al., 2015; Choukroun et al., 2020). Furthermore, the porosity of the bulk material affects the bulk thermal properties through conduction and radiation, affecting the sintering rates between the grains (Ferrari and Lucas, 2016).To understand the sintering processes and determine the mechanical properties of Enceladus’ surface, laboratory experiments have been used to study water-ice produced in low-temperature environments. Results indicate that icy granular surfaces are mechanically weaker at low temperature than at warmer temperatures (Gundlach et al., 2018; Molaro et al., 2019; Choukroun et al., 2020; van Veen, 2025; Fabbretti, 2026). Vapour transport is the dominant consolidation mechanism in early sintering stages, while surface diffusion may become dominant at much lower temperatures. In vacuum conditions, Fabbretti (2026) found an increased sintering rate between water-ice grains compared to the atmospheric findings of van Veen (2025). This indicates that the sintering behaviour of water-ice grains operates differently in the absence of an atmosphere.This study aims to understand the mechanical properties of Enceladus’ surface analogues as well as low-temperature and low-pressure sintering of water-ice grains. We performed experiments in our PISCES (Plumes and Ices Simulation Chamber for Enceladus and other moonS) to investigate the sintering behaviour of water-ice grains under vacuum conditions. This novel experimental chamber is used to reach sub-mbar pressures and low temperatures (Bourgeois and Cazaux, 2025). Fine grains are produced through direct spray into the chamber or outside using liquid nitrogen, and are exposed to a near vacuum where they are mechanically evaluated. A penetrometer setup is used to measure the cone penetration resistance of the bulk material in a vacuum with respect to the grain size, porosity and sintering time. The L4 mission is in the works with respect to ESA’s Voyage 2050 programme. It is set to explore the Kronian moons with an orbiter and a lander (Helbert et al., 2025). Understanding the surface’s mechanical properties will help find an adequate landing site for the mission.] 20:09:56 1818966 AIClient - Response from AI: no 20:09:56 1818966 CrossRefSearchJob - AI response: no 20:09:56 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75180-9 20:09:56 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75143-0 20:09:56 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract The naked mole-rat (Heterocephalus glaber) is a long-lived mammal with resistance to cancer and hypoxia, suggesting the evolution of robust proteostasis networks. The ribosome, central for protein synthesis, is key to cellular stress responses and has an unusual feature: the 28S rRNA split; however, the details of its organization remain unknown. Here, we present high-resolution cryo-EM structures of the naked mole-rat 80S ribosome in four states of the elongation cycle. The structures reveal a conserved overall architecture and rRNA modification landscape compared to other mammals, and provide an atomic-level view of the distinct break in the 28S rRNA. This cleavage event, located in the D6 expansion segment, is structurally stabilized by a network of interactions with surrounding ribosomal proteins, maintaining the integrity of the large subunit. Our comparative analysis revealed that this compensatory network preserves a canonical architecture that is nearly indistinguishable from intact mouse and human ribosomes. These findings resolve the structural basis of this distinct cleavage, showing that it is a stable, integrated feature whose function is likely linked to more subtle regulatory mechanisms, rather than inducing major structural rearrangements. ] 20:09:57 1818494 AIClient - Response from AI: no 20:09:57 1818494 CrossRefSearchJob - AI response: no 20:09:57 1818966 AIClient - Response from AI: no 20:09:57 1818966 CrossRefSearchJob - AI response: no 20:09:57 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-993 20:09:57 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-90 20:09:57 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75143-0 20:09:57 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.21357/chqe-vz33 20:09:57 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The role of water in the chemistry of interstellar icesH. Carrascosa1, G. M. Muñoz Caro1, C. Del Burgo Olivares1, Y. –J. Chen2Centro de Astrobiología (CAB, CSIC-INTA), Ctra de Ajalvir, km 4, Torrejón de Ardoz, 28850, Madrid, Spain.Department of physics, National Central University, Zhongli District, Taoyuan City, Taiwan.Experiments performed under simulated interstellar conditions have shown the formation of a full variety of complex organic molecules (such as sugars, heterocycles, amides, etc.) from irradiation of ice samples. As water is, by far, the most abundant molecules in ice mantles in the interstellar medium, most of the species present in ice mantles will be surrounded by water molecules. Understanding the role of water is therefore essential to predict the conditions and environmental situations where certain species will be favoured.It is well known that the presence of water determines the chemistry in specific directions, which can be drastically different from the chemistry without water. For example, methanol ice forms formaldehyde readily under UV radiation. Formaldehyde is a very reactive species, which polymerises, forming a polymer called polyoxymethylene (POM). However, in the presence of water, formaldehyde molecules are solvated by water molecules, and the formation of POM is highly inhibited [1].We have experimentally studied the role of water in two different ice mixtures: 1) H2O:NH3:CH3OH and 2) H2O:H2S. Experiments were carried out using a high vacuum chamber, cooled down with liquid nitrogen and submitted to UV radiation with a deuterium lamp. After simultaneous deposition and irradiation, ice samples were warmed up to room temperature. A methanol extract of the organic residue at room temperature, was analysed by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (HPLC-MS) equipments, to identify and quantify the molecules remaining in the organic residues. The composition and abundances of the detected molecules were compared in experiments with different water ratios [2].Several works have already studied the formation of organic molecules in H2O:NH3:CH3OH ice mixtures ([3] and references therein). There is a full variety of organic species detected from UV irradiation of this ice samples. The experimental procedure prior to chromatographic analyses is designed in each work depending on the family of species of interest. Sugars, amino acids, or heterocycles are among the species which have been detected. We have not carried out any pretreatment of the samples, to avoid any induced chemistry after the extraction of the sample from the simulation chamber. GC-MS analyses have revealed that N-heterocycles are favoured over O-heterocycles, and we have investigated the role of water toward this chemistry [4].Figure 1: chromatogram of a H2O:CH3OH:NH3 ice mixture. Gaussian profiles for each of the identified species are shown. Note that there are no O-heterocycles, as a consequence of the chemistry induced by the presence of ammonia, and the chemical properties of the O-H groups provided by photodissociation of water and methanol molecules.The fate of sulphur in the interstellar medium is still unclear. Several authors have pointed out to the formation of long sulphur chains as sulphur reservoirs in the interstellar medium [5, 6, 7]. However, H2S has not been detected in ice mantles, suggesting that, if present, its abundance will be low compared to water. Consequently, H2S molecules will not be in close contact in ice mantles. Experiments were made with H2O:H2S ice samples in different ratios. If sulphur ends up forming chains, there must be an efficient mechanism which brings together sulphur atoms, making it possible to react and producing covalent S-S bonds. This mechanism has been elucidated [2] and will be presented here. In our experiments, water enhances the formation of octaedric sulphur by a factor of ~100. Water molecules play a key role, forming covalent bonds with sulphur intermediates that favours subsequent S-addition reactions. Some of these intermediates have been detected in the organic residue, which served to complete the chemical pathway to the formation of sulphur chains in a water environment.In brief, we show strong evidence for the need of a water-rich ice environment in the photosynthesis of sulphur allotropes up to S8, and provide a reaction scheme that also requires the presence of water for the N-heterocycles formation.Figure 2: mechanism of sulphur formation in two steps. First, water molecules favour the formation of S-SO3 species, which is required to elongate sulphur chains. 2) when sulphur chains are long enough, they will make an intramolecular reaction producing sulphur cycles. Alternatively, A’ shows a chemical pathway by which molecules could not elongate more, producing different species that were also detected in the chromatographic analyses.[1] Schutte, W., Allamandola, L. J., and Sandford, S. A., 1993, Icarus, 104, 118-137.[2] Del Burgo Olivares, C., Carrascosa, H., Muñoz Caro, et al., 2026, submitted to A&A.[3] Muñoz Caro, G. M., Carrascosa, H., Martín-Doménech, R., 2025, Nat. Rev. Chem, 9, 537-552.[4] Del Burgo Olivares, C., Carrascosa, H., Muñoz Caro, G. M., et al., 2026, submitted.[5] Cazauz, S., Carrascosa, H., Muñoz Caro, G. M., et al. 2022 A&A 657, 1-12.[6] Carrascosa, H., Muñoz Caro, G. M., Martín-Doménech, R. et al. 2024, MNRAS, 533, 1, 967-978[7] Herath, A., McAnally, M., Turner, A. M., et al. 2025, Nat. Comm. 16, 5571.] 20:09:57 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Oppsummering av resultater for SenseInside NIR instrument for måling av 1) vann i klippfisk, saltfisk og tørrfisk, 2) kjøttfylde i kongekrabbe, 3) fett i laks, makrell og sild, og 4) protein i fiskefarse.] 20:09:58 1818966 AIClient - Response from AI: no 20:09:58 1818966 CrossRefSearchJob - AI response: no 20:09:58 1818966 CrossRefSearchJob - Publication not relevant: 10.21357/chqe-vz33 20:09:58 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-857 20:09:58 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The early geological history of Mars is comparable to that of Earth, with a probable past presence of liquid water, CHNOPS elements, and energy sources, all of which are essential for a potential emergence of life. The absence of plate tectonics and limited erosion, which expose ancient terrains, make Mars a prime target for the search for traces of life and the study of the habitability of Earth like planets [1].The Rosalind Franklin rover (ExoMars 2028 mission) will be sent to Mars in 2028. As it is equipped with a drill capable of digging up to 2 meters deep, it will be able to collect and analyze samples relatively protected from the harsh conditions of the surface (particularly radiations and perchlorates). The main objective of this mission is to search for biosignatures such as specific organic compounds (amino acids, carboxylic acids…) using an appropriated instrumental payload [2]. In particular, the Mars Organic Molecule Analyzer (MOMA) was designed to separate, detect and identify organic molecules. MOMA has two operational modes based on laser desorption or gas chromatography (GC), both coupled with mass spectrometry (MS) [3].The organic molecules in the samples collected by the rover must be volatilized before being separated by GC and identified by MS. To do so, the samples can be either pyrolyzed or chemically derivatized. Derivatization agents (MTBSTFA, DMF-DMA, TMAH) are aboard the rover and can be used to increase the volatility of polar molecules while avoiding pyrolysis and potential degradation due to rising temperature. Using a laboratory GC-MS setup, coupled with a pyrolizer, we perform the derivatization-GC-MS analysis of various solid analog samples. This setup reproduces the MOMA hardware constraints as closely as possible, particularly in terms of available time and temperature but also by performing online derivatization with a sample-to-agent ratio similar to that of the MOMA instrument. We studied both natural (from the Arctic, Mauritania…) and artificial samples from a set of samples selected by the ExoMars scientific team in order to test the capacity and complementarity of the rover's payload in detection of organic matter.After optimizing the analytical sequence, we can detect molecules with strong exobiological potential (such as carboxylic acids, amino acids or nucleobases) in most of the samples.Although our MOMA-like derivatization-GC-MS setup does not detect as many interesting molecules as other more sensitive laboratory instruments, we aim to explain this difference, determine its performance (limits of detection and quantification) and optimize its analytical parameters. [1] Cockell, Trajectories of Martian Habitability, Astrobiology, 2014, vol 14, num 2[2] Goesmann et al., The Mars Organic Molecule Analyzer (MOMA) Instrument: Characterization of Organic Material in Martian Sediments, Astrobiology, 2017, vol 17, num 6 & 7[3] Vago et al., Habitability on Early Mars and the Search for Biosignatures with the ExoMars Rover, Astrobiology, 2017, vol 17, num 6 & 7] 20:09:58 1818494 AIClient - Response from AI: no 20:09:58 1818494 CrossRefSearchJob - AI response: no 20:09:58 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-90 20:09:58 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3102176 20:09:58 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [High-temperature transmission spectroscopy system for molecular pressure broadening measurements in exoplanetary atmospheric conditions] 20:09:59 1818966 AIClient - Response from AI: no 20:09:59 1818966 CrossRefSearchJob - AI response: no 20:09:59 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-857 20:09:59 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76304 20:09:59 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Identifying the drivers of cellular senescence that contribute to the decline in vascular function with age and disease is critical for developing restorative interventions. Here, we investigated how increased mechanical stress from extracellular matrix (ECM) stiffening shapes endothelial cell (EC) senescence. We developed a 3D human in vitro model that decouples mechanical stress from inflammatory or biochemical signals, enabling the study of senescence responses to tissue stiffening alone. We found that matrix stiffening induces an EC senescence phenotype with elevated p16/p21 and an immunomodulatory senescence‐associated secretory phenotype (SASP), in the absence of inflammatory signals. This mechano‐induced senescence activates Notch signaling, and treatment with an FDA‐approved γ‐secretase inhibitor attenuates stiffness‐induced senescence. Analysis of fibrotic capsule tissue from patients with synthetic breast implants, a model of localized, mechanically driven fibrosis, validated an increase in p16 + Notch1 + endothelial populations. Complementary single‐cell RNA sequencing data further confirmed enrichment of Notch‐ and SASP‐related gene programs. Our work provides a human‐relevant platform for studying targetable stages of endothelial mechanoaging and identifies potential therapeutic targets associated with stiffness‐induced endothelial senescence for mechanically remodeled tissues. ] 20:09:59 1818494 AIClient - Response from AI: no 20:09:59 1818494 CrossRefSearchJob - AI response: no 20:09:59 1818494 CrossRefSearchJob - Publication not relevant: 10.1117/12.3102176 20:09:59 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-645 20:09:59 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The icy ocean moons Enceladus and Europa offer potentially habitable environments below their icy crusts. Ice grains ejected from cryovolcanic plumes [1,2] and micrometeorite bombardment can be sampled by impact ionization mass spectrometers, as performed in the past by the Cosmic Dust Analyzer (CDA; [3]) onboard Cassini in the Saturnian system. Successor instruments to the CDA include the SUrface Dust Analyzer (SUDA; [4]) onboard NASA’s Europa Clipper mission and the HiFi instrument for a future Enceladus mission [5]. The strongly enhanced capabilities of SUDA and contemporary instruments, relative to CDA, allow the identification of molecular biosignatures. Among possible molecular biosignatures, amino acids are essential building blocks of proteins and play a crucial role in the formation of water-based life as we know it, thus their identification on extraterrestrial water worlds is key to the search for life beyond Earth.Laboratory analogue experiments using laser-induced liquid beam ion desorption (LILBID [6]) have demonstrated that impact ionization mass spectrometers can detect amino acids [7] down to the ppm or ppb level, if they are entrapped in emitted ice grains, and can distinguish between abundance patterns of abiotic and biotic formation processes [8]. However, at any given molecular mass of an amino acid, several isomers (identical molecular formula but distinct arrangements of atoms in space) exist, which are indistinguishable by their molecular peaks in recorded mass spectra. Until now, it was unclear whether isomeric amino acids can be discriminated from each other, e.g., by fragmentation patterns in impact ionization mass spectra.Here, using LILBID mass spectrometry, we conducted a cation mode analysis of eight isomeric amino acids with an identical molecular mass of 131.173 u and formula C6H13NO2 [9]. The recorded mass spectra were investigated for spectral features that enable differentiation of the different isomeric amino acids, with the aid of quantum chemistry calculations.We show that the amino acid isomers (including diastereoisomers) can be uniquely identified due to their distinct mass spectral features and fragmentation patterns. Several observed fragments and their intensities can be explained through intramolecular hydrogen bonding and other structural effects originating from the parent molecules. Importantly, α-amino acids can be clearly differentiated from non-α-amino acids, because they have lower proton affinities than non-α-amino acids, which result in lower ionization efficiencies for α-amino acids. Additionally, we further complement the LILBID database [10], which already contains a large variety of analogue mass spectra of both organic and inorganic compounds, for upcoming missions to icy ocean moons.The ability to discriminate amino acid isomers in a robust and reliable manner highlights a novel ability of impact ionization mass spectrometers that has significant implications for the search of biosignatures in the solar system, in particular for SUDA on Europa Clipper and other future instruments onboard missions exploring ocean worlds.[1] F. Spahn et al., Science, 311, 1416-1418 (2006)[2] L. Roth et al., Science, 343, 171-174 (2014)[3] R. Srama et al., Space Sci. Rev., 114, 465-518 (2004)[4] S. Kempf et al., Space Sci. Rev. 221, 10 (2025)[5] O. Mousis et al., The Planetary Science Journal, 3(12), 268 (2022)[6] F. Klenner et al., Rapid Commun. Mass Spectrom., 33, 1751-1760 (2019)[7] F. Klenner et al., Astrobiology, 20, 179-189 (2020)[8] F. Klenner et al., Astrobiology, 20, 1168-1184 (2020)[9] J. Bönigk, et al. Astrobiology 15311074261443835 (2025)[10] F. Klenner et al., Earth Space Sci., 9, e2022EA002313 (2022)] 20:10:00 1818966 AIClient - Response from AI: no 20:10:00 1818966 CrossRefSearchJob - AI response: no 20:10:00 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76304 20:10:00 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-794 20:10:00 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The state of the art in coupling dust coagulation to hydrodynamical simulations of protoplanetary disks are 2D simulations with ∼100 particle size bins. Many problems in planet formation, such as the streaming instability, are 3D in nature and require extremely high resolution in size space. Coupling 3D hydrodynamics with coagulation requires going beyond the current state of the art, by harnessing the power of machine learning (specifically neural differential equations) to obtain an efficient and accurate subgrid model for dust collisions. This will for the first time allow for a full treatment of the dust component, including coagulation, in simulations of the polydisperse streaming instability and pebble accretion.] 20:10:00 1818494 AIClient - Response from AI: no 20:10:00 1818494 CrossRefSearchJob - AI response: no 20:10:00 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-645 20:10:00 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74919-8 20:10:00 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Chemical intuition on bond-dissociation energies as an emergent ability of universal machine-learning interatomic potentials] 20:10:01 1818494 AIClient - Response from AI: no 20:10:01 1818494 CrossRefSearchJob - AI response: no 20:10:01 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74919-8 20:10:01 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.32942/x2xd4n 20:10:01 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Wood (secondary xylem) is a source of information about events that occurred during their lifespan. The aim of our research was to provide the pattern of modification of Lebanon cedar wood under the influence of mechanical stress, as a result of binding its trunk with string or wire. The wood samples were taken from a young Cedrus libani (14 years old - evaluated based on the number of growth rings) growing in the Agdaci campus of Faculty of Forestry, Bartin University. They were taken from three different levels of the trunk including the strangulation point, and above and below this point. Using standard protocols, cross-sections of the taken wood were prepared. Then, the morpho-anatomical features of wood were examined: (i) tracheid radial diameter (TRD), (ii) cell wall thickness of tracheid (CWT), (iii) tracheid radial diameter divided by cell wall thickness (TRD/CWT), (iv) tracheid number per mm2 (TN), (v) tracheid length (TL), (vi) ray number per mm (RN), (vii) ray density per mm2 (RD), (viii) ray height (RH), (ix) parenchyma cell number in rays per mm2 (PCN), (x) percent of uniseriate rays (PUR), and (xi) percent of biseriate rays (PBR). Among the analyzed biometric features, those concerning the rays and parenchyma cells differed significantly between the wood samples taken from different trunk levels at p &lt; 0.01. Both axial and radial traumatic resin ducts were observed. There was no significant difference in TRD, CWT and TRD/CWT between levels. We postulate that increased the amount of parenchyma in wound secondary xylem by producing both uni- and biseriate rays as well as traumatic resin ducts facilitates compartmentalization and wound closure and reflect the phenotypic plasticity and structural adaptations of the cedar wood to respond to injury and physiological needs.] 20:10:01 1818966 AIClient - Response from AI: no 20:10:01 1818966 CrossRefSearchJob - AI response: no 20:10:01 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-794 20:10:01 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3105533 20:10:01 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Recent thermal infrared observations enabled by the NALES reduction pipeline] 20:10:02 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76435 20:10:02 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT This study proposes a smart fluid hydraulic system based on magnetorheological fluid (MRF) valve control for flexible gripping. An MRF micro‐servo valve (MRF‐MSV) that integrates an excitation coil and micro‐textured damping channels has been designed. Through experiments and simulations based on the Bingham model, the hydraulic resistance characteristics of the valve under different currents are analyzed, which confirms the enhancing effect of the micro‐textured channels on hydraulic resistance. Furthermore, experiments demonstrate that at an excitation current of 3 A, the valve body's resistance pressure reaches 1191.4 kPa with a micro‐textured height of 0.2 mm, representing an 81.9% increase compared to the valve without micro‐textured channels (655 kPa). Integrating the MRF‐MSV with a soft actuator enables dynamic control of bending and grasping motions, with a maximum bending angle of 180°. Then, an MRF variable‐stiffness soft actuator (MRF‐VSSA) is developed. When a current of 1.2 A is applied to the variable‐stiffness module, the fingertip force increases from 2.69 to 5.05 N, showing an 87.7% increase. Finally, an MRF‐based smart fluid‐hydraulic system is constructed, and a magnetically driven manipulator is developed. Experiments indicate that this manipulator can execute complex hand movements and stably grasp objects of various shapes without causing damage.] 20:10:02 1818494 AIClient - Response from AI: no 20:10:02 1818494 CrossRefSearchJob - AI response: no 20:10:02 1818494 CrossRefSearchJob - Publication not relevant: 10.32942/x2xd4n 20:10:02 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75294-0 20:10:02 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Zeolitic isolated protonic acid sites-mediated NH3 storage for robust NOx removal] 20:10:02 1818966 AIClient - Response from AI: no 20:10:02 1818966 CrossRefSearchJob - AI response: no 20:10:02 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3105533 20:10:02 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1101 20:10:02 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Introduction Cryovolcanic eruptions occurring on icy satellites, as observed on Enceladus [1-6] and suspected for Europa [7,8], offer a unique opportunity to study the interior of such objects and the origin of ejected volatiles. On Enceladus, plumes outgas from surface fractures [1], and originate from the salty subsurface ocean [9]. On Europa, a similar activity was observed. Here, we present the Smoothed Particle Hydrodynamics (SPH) [10] to characterize the behavior of volatile emissions, used for Enceladus [11] and applicable to Europa plumes.Smoothed Particle Hydrodynamics model for volatile emissionsEnceladus plumes. Our SPH model describes the volatile release from a surface fracture on Enceladus [11]. It integrates hydrodynamic equations and provides the evolution of density, velocity, and energy. We consider phase transitions between vapor and icy-grains and their viscous interaction. The thermal interaction with the surface, the solar radiation and radiative equilibrium, the gravitational attraction, and tidal limitations are also considered. We predict the mass loss and the surface ice accumulation which result consistent with literature [3,5].Europa plumes: setup and modeling challenges. The model is applicable to the suspected cryovolcanism on Europa [7,8]. Here, the emission mechanisms are not constrained by observations [12]. The Jovian plasma environment is important for detection, but a second-order effect for the plume structure as only a small fraction of material is involved in the plasma-plume interaction [12]. The icy shell thickness determines the depth of a potential subsurface liquid interface, where ocean evaporation occurs. In addition, from the perspective of source mechanisms such as liquid pockets or diapirism [12], the extent of the reservoir is highly uncertain. Furthermore, the unknown temporal modulation of plume activity suggests episodic events, with wall deposition as a possible mechanism for fracture sealing [13]. By applying our model, we can characterize the episodic emission by investigating the relationship between the ejected mass and the release timescale. This depends on source and subsurface physical properties, which we can explore to provide predictions useful for interpreting the future observations of Europa Clipper and JUICE missions (Figure 1).Figure 1. Schematic representation of workflow to investigate ejected mass and release timescale according to source and subsurface conditions.Preliminary simulation of Europa plumes show a similar behavior of the two-component (vapor-ice) flow as obtained for Enceladus activity, where we considered different icy-grain sizes, a quantity that affects the viscous drag coupling. This process shapes the dynamics within the fracture, yielding a slower flow for larger grains (100 micron) and increasing the release time. Larger grains produce a more collimated icy plume, also affecting a small fraction of the vapor plume. Small grains (1 micron) are initially driven by vapor, where density is higher. This occurs on top of the venting area, where we get a plumper plume (Figure 2).Figure 2. Velocity distribution (grains: blue-green shades; vapor: red-yellow-shades) at t~10 s after emission for 1-micron (left) and 100-micron (right) sized icy grains for Europa plumes simulation. Larger grains show a higher collimation, while small grains present a broader low-velocity distribution above the venting area. Vapor expands in all directions, although for the large grain simulation, it also shows some degree of collimation where ice is present.To enhance the quality of our model and yield more robust predictions, we are improving the phase transition treatment to better describe the thermal effects of the latent heat of sublimation and to simulate the evaporation process. A definitive numerical solution for latent heat transfer in SPH simulations is still missing. Here we present a numerically stable procedure to the latent heat problem in vapor–ice phase change. We show benchmark tests validating the implementation based on analytical considerations and energy conservation. We also discuss the challenges introduced by simulating the evaporation process, generating new SPH particles. Conclusions and perspectivesPreliminary results show that our SPH model is applicable to Europa plumes. It offers an advanced tool to investigate the episodic release of volatiles, in particular to characterize the ejected material and the release time relationship, according to source and subsurface properties. To this aim, we are performing preliminary simulations and refining the considered processes to improve the description of the two-phase flow. In the future, we plan to account for the thermal interaction with fracture walls and the sealing of fractures via ice deposition, taking advantage of the SPH formalism and Eulerian models for thermophysical characterization [14]. Finally, our model can be applied to volatile emissions occurring on various objects of the Solar System. These include cometary activity [15], drilling-induced release of volatile-dust mixtures on Mars [16-17] and the evolution of vaporized ejecta resulting from impacts of hydrated objects, with the possible accumulation within Permanently Shadowed Regions on the Moon and Mercury [18].References[1] Hansen et al. 2006, Science 311, 1422.[2] Schmidt et al. 2008, Nature, 451, 685.[3] Kempf et al. 2010, Icarus, 206, 446-457. [4] Dong et al. 2011, J. Geophys. Res., 116.[5] Teolis et al 2017, Astrobiology, 17, 9.[6] Postberg et al. 2018, Nature, 558, 564.[7] Roth et al. 2014, Science, 343, 171.[8] Sparks et al. 2016, ApJ, 829, 121. [9] Spencer & Nimmo 2013, Annu. Rev. Earth Planet. Sci. 41, 693.[10] Monaghan 2005, Rep. Prog. Phys. 68, 1703.[11] Teodori et al. 2026, Icarus, 443, 116765.[12] Vorburger & Wurz 2021, JGR Space Physics, 126, e2021JA029690.[13] Boccelli et al. 2025, PSS, 263, 106136.[14] Formisano et al. 2024, PSS, 251, 105969.[15] Rinaldi et al. 2025, EPSC-DPS2025-1556.[16] Maggioni et al. 2025, MNRAS, 543, 3310.[17] Maggioni et al. 2026, PSS, 272, 106244. [18] Teodori et al. 2025, EPSC-DPS2025-323.AcknowledgmentsThis work has been developed under the “ASI-INAF agreement n. 2023-6-HH.0”, the "ASI-INAF agreement n. 2023-3-HH.0", by ISSI within the project “Thermophysical Characterization of Ice-Rich Areas on the Surface of Specific Planetary Bodies: Conditions for the Formation of a Transient Exosphere” and INAF MiniGrant “PLUMES-Planetary fractures Lagrangian simUlations for Multi-component EmissionS”.] 20:10:03 1819442 AIClient - Response from AI: no 20:10:03 1819442 CrossRefSearchJob - AI response: no 20:10:03 1819442 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76435 20:10:03 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103740 20:10:03 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A white-pupil echelle spectrograph design for high-resolution integral field spectroscopy: achieving near-peak blaze efficiency for key emission lines] 20:10:03 1818966 AIClient - Response from AI: no 20:10:03 1818966 CrossRefSearchJob - AI response: no 20:10:03 1818966 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1101 20:10:03 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76391 20:10:03 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Superoxide dismutase 1 (SOD1), a copper‐dependent antioxidant, is essential for redox homeostasis, and its decline drives renal senescence and fibrosis. However, the mechanisms linking profibrotic signaling to SOD1 inhibition remain unclear. Here, we identified a pathological copper‐COMMD1‐SOD1 axis in which intracellular copper overload paradoxically suppressed SOD1 activity. In kidney tissues from chronic kidney disease (CKD) patients and complementary in vivo and in vitro fibrotic models, we consistently observed a reduction in SOD1 activity accompanied by elevated intracellular copper levels. Lowering intracellular copper levels restored SOD1 activity, suppressed reactive oxygen species (ROS) accumulation, and alleviated cell senescence and fibrosis. Mechanistically, pathological copper overload impaired SOD1 homodimerization, the essential final step in its activation. We identified copper metabolism MURR1 domain containing 1 (COMMD1) as a key copper‐sensitive mediator of this process. Copper overload acted upstream, simultaneously upregulating COMMD1 expression and enhancing its binding affinity to SOD1. This enhanced COMMD1‐SOD1 interaction directly disrupted SOD1 homodimer assembly and enzymatic function. Collectively, these findings redefined the regulatory role of copper in SOD1 activity and uncovered a previously unrecognized mechanism by which pathological copper overload paradoxically suppressed SOD1 activity via COMMD1‐dependent disruption of SOD1 homodimerization, providing new insight into the pathophysiology of copper dyshomeostasis‐associated diseases.] 20:10:03 1818494 AIClient - Response from AI: no 20:10:03 1818494 CrossRefSearchJob - AI response: no 20:10:03 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75294-0 20:10:03 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75007-7 20:10:03 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Conserved macromolecular architecture of poplar secondary cell walls revealed by ssNMR and atomistic modeling] 20:10:04 1819442 AIClient - Response from AI: no 20:10:04 1819442 CrossRefSearchJob - AI response: no 20:10:04 1819442 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103740 20:10:04 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75060-2 20:10:04 1818494 AIClient - Response from AI: no 20:10:04 1818494 CrossRefSearchJob - AI response: no 20:10:04 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Metal–organic framework glass enables durable sodium-ion storage for hard carbon negative electrodes] 20:10:04 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75007-7 20:10:04 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75165-8 20:10:04 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [A low-temperature, water-free fabrication route to Mg-based micro thermoelectric coolers for thermal management] 20:10:04 1818966 AIClient - Response from AI: no 20:10:04 1818966 CrossRefSearchJob - AI response: no 20:10:04 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76391 20:10:04 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74995-w 20:10:04 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [L-type pyocins inhibit the BAM complex to kill without cell entry] 20:10:05 1819442 AIClient - Response from AI: no 20:10:05 1819442 CrossRefSearchJob - AI response: no 20:10:05 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75060-2 20:10:05 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74988-9 20:10:05 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Lichens are symbiotic associations between a fungal mycobiont and a photosynthetic photobiont. They thrive in nutrient-poor environments; yet the mechanisms underlying their adaptation to iron limitation remained largely unknown. Here, we characterize the iron acquisition system of Xanthoria parietina , a globally distributed lichen-forming fungus associated with the microalgal photobiont Trebouxia decolorans . We demonstrate that the mycobiont produces the siderophore ferrichrome and possesses the full genetic repertoire not only for siderophore biosynthesis, but also reductive iron assimilation, iron detoxification, and regulation. The ferrichrome-synthesizing non-ribosomal peptides synthetase exhibits a lichen-specific compact architecture but retains functionality when heterologously expressed in a non-lichenized ascomycete. Transcriptomic analysis and ferrichrome quantification reveal substrate-dependent regulation of the siderophore system. Importantly, ferrichrome promotes photobiont growth independent of extracellular iron reduction, indicating direct utilization. These findings provide the functional evidence of siderophore-mediated iron acquisition in a lichen symbiosis and highlight ferrichrome as a key mediator of mutualistic nutrient exchange. ] 20:10:05 1818966 AIClient - Response from AI: no 20:10:05 1818966 CrossRefSearchJob - AI response: no 20:10:05 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74995-w 20:10:05 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-474 20:10:05 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [IntroductionThe icy Galilean moons — Europa, Ganymede, and Callisto — are major targets in the search for habitable environments because they likely harbor subsurface oceans beneath their icy crusts. Assessing their habitability requires understanding the origin and evolution of complex organic molecules (COMs), which are key precursors of prebiotic chemistry.Although COMs have not yet been directly detected on the Galilean moons, upcoming missions such as ESA’s JUICE and NASA’s Europa Clipper will provide new constraints on the abundance and distribution of organics, salts, and volatile ices through infrared, submillimeter, and mass spectrometry observations.While the formation and transport of COMs have been extensively studied in protoplanetary disks, their evolution within circumplanetary disks (CPDs), where giant-planet satellites form, remains poorly understood. COMs inherited from the protosolar nebula may have been altered or destroyed during transport into Jupiter’s CPD, while the CPD itself may also have enabled in situ organic synthesis through thermal and photochemical processing of icy particles.This study investigates the formation and transport of COMs in Jupiter’s evolving CPD using a time-dependent disk model coupled to particle transport calculations. Two formation pathways are explored: thermal processing of NH3:CO2 ices [1] and UV photochemistry of CH3OH-rich particles [2]. The goal is to determine under which conditions COMs can form, survive, and become incorporated into the Galilean moons.MethodologyThe study employs a two-dimensional gas-starved model of Jupiter’s CPD, which evolves from a hot, massive disk to a colder and less dense configuration as Jupiter’s accretion rate decreases with time. The nominal model assumes an initial accretion rate of 6.6 × 10−6MJ yr−1, a depletion timescale of 20 kyr, a turbulent viscosity parameter α = 10−3, and a centrifugal radius of 50 RJ. The thermodynamic structure of the CPD is controlled by viscous heating, radiative cooling, and irradiation from a young Jupiter with a surface temperature near 2000 K. The model naturally produces shadowed regions that can cool the disk locally by up to 100 K.Particle transport is modeled using a Lagrangian framework accounting for gas drag, turbulence, diffusion, and settling. Simulations track particles ranging from 1 μm to 1 cm released at different epochs and locations within the CPD. Two COM formation pathways are explored: thermal processing of NH3:CO2 ices between 80 and 260 K, and UV photochemistry of CH3OH-rich ices. UV fluence is computed self-consistently along particle trajectories while accounting for attenuation by gas and dust opacity.The simulations therefore couple disk evolution, particle transport, irradiation exposure, and ice chemistry to determine where and when COMs can form and survive within Jupiter’s CPD.ResultsThe simulations show that thermal processing dominates COM formation within Jupiter’s CPD. Particles drifting inward through the disk systematically cross regions with temperatures between 80 and 260 K, where NH3:CO2 ices are efficiently converted into COM-bearing material within a few hundred years.At early epochs (t0 = 50 kyr), particles smaller than 1 mm remain strongly coupled to the gas, while larger particles rapidly migrate inward due to gas drag. Figure 1 shows that many trajectories intersect the thermal COM formation zone located between ~20 RJ and the centrifugal radius. In contrast, UV-driven chemistry is much less efficient. CH3OH-rich particles generally sublimate before accumulating sufficient UV fluence to trigger substantial photochemical COM formation. Only a limited fraction of small particles released late in the disk evolution reach irradiation thresholds derived from laboratory experiments. As the CPD evolves and gas densities decrease, particle-gas coupling weakens and even micron-sized grains drift inward. The thermal processing region simultaneously migrates closer to Jupiter, but particles continue to experience efficient thermal processing before significant UV irradiation occurs.The simulations also show that increasing particle density, turbulent viscosity, or lowering the disk accretion rate further suppresses irradiation-driven chemistry by shortening particle residence times within the disk. Overall, the results indicate that thermal processing of NH3:CO2 ices is the dominant COM formation pathway in Jupiter’s CPD, whereas UV photochemistry plays only a secondary role under nominal conditions.Fig. 1. Median radial trajectories of 1 µm, 100 µm, 1 mm, and 1 cm particles as a function of time in our nominal CPD model. The particles are released one scale height above the CPD midplane at t0 = 50 kyr. Particle trajectories are computed in both the radial and vertical directions, but only their projection onto the CPD midplane is shown here for clarity. Median trajectories are shown at 10 Rjup intervals in the midplane, spanning from 5 to 135 Rjup in the CPD. Dotted lines highlight portions of these trajectories that intersect the COM formation zone via thermal processing in the CPD. The horizontal dotted-dashed line indicates the location of Rc.ConclusionsThis study shows that COMs can form efficiently within Jupiter’s CPD through thermal processing of icy particles drifting through warm disk regions. In contrast, UV-driven photochemistry is generally inefficient because particles sublimate before accumulating sufficient irradiation doses.The results suggest that the Galilean moons may have inherited part of their organic inventory directly from the CPD, although COM survival strongly depended on local thermal conditions and accretion histories. The hotter inner disk likely destroyed most organics incorporated into Io and possibly Europa, whereas the colder formation environments of Ganymede and especially Callisto favored preservation of COM-rich material.The study also highlights the need for improved laboratory photochemical data and more comprehensive chemical models, including mixed-ice chemistry and grain-surface processes.Overall, the results indicate that thermal processing within Jupiter’s CPD could have generated and preserved organics later incorporated into the Galilean moons. Future observations from JUICE and Europa Clipper will provide key constraints on the origin and survival of organics within the Jovian system. All results and interpretations are presented in [3]. References[1] Bossa, J. B., et al. 2008, A&A, 492, 719, doi: 10.1051/0004-6361:200810536[2] Tenelanda-Osorio, L. I., et al. 2022, MNRAS, 515, 5009, doi:10.1093/mnras/stac1932[3] Mousis, O., et al. 2026, PSJ, 7(2), id.41, doi:10.3847/PSJ/ae3559] 20:10:05 1818494 AIClient - Response from AI: no 20:10:05 1818494 CrossRefSearchJob - AI response: no 20:10:05 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75165-8 20:10:05 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-951 20:10:05 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Astrophysical ices accrete on substrates whose chemical composition vary significantly according to their environment.In the interstellar medium, ices mantles grow onto dust grains composed of amorphous silicates and carbonaceous materials[1], while more diverse mineralogical substrates are present in circumstellar regions [2]. On the surfaces of icy moons inthe Solar System, several saline species have been identified [3]; these species are thought to originate from subsurfaceoceans, making their characterization essential for inferring the chemistry of these internal water bodies. In this study,we investigated the interactions between astrochemically relevant molecules and saline substrates through laboratoryexperiments. Specifically, we evaluated the adsorption of carbon monoxide and ammonia onto iron salts; the oxidationstates of Fe could indicate the redox conditions of the oceans under the surface. Infrared spectra show the emergence ofspectral profiles reflecting the interactions between ices and salt substrates. Under ultra-high vacuum conditions, whilepure CO typically desorbs at 25–30 K, the new spectral features of CO persisted on the salt substrate up to approximately180 K, a clear effect of strong chemical interactions. Furthermore, signatures of NH3 remained visible at temperaturesas high as 300 K. These results suggest that saline surfaces significantly enhance the thermal stability of volatile species,with profound implications for the chemical evolution of icy planetary surfaces and their observations.[1]Jones, A. P. ”Dust evolution, a global view: III. Core/mantle grains, organic nano-globules, comets and surface chemistry.” RoyalSociety Open Science 3.12 (2016).[2] Keller, L. P., et al. ”Identification of iron sulphide grains in protoplanetary disks.” Nature 417.6885 (2002): 148-150..[3] Carlson, R. W., et al. ”Europa’s surface composition.” Europa 283 (2009).[4] Napoleoni, Maryse, et al. ”Probing the oxidation state of ocean worlds with SUDA: Fe (II) and Fe (III) in ice grains.” ThePlanetary Science Journal 5.4 (2024): 95.] 20:10:06 1819442 AIClient - Response from AI: no 20:10:06 1819442 CrossRefSearchJob - AI response: no 20:10:06 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74988-9 20:10:06 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1158/0008-5472.32872525 20:10:06 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [<p>The role of candidate tRF-E and tRF-K in HCC cells.</p>] 20:10:06 1818494 AIClient - Response from AI: no 20:10:06 1818494 CrossRefSearchJob - AI response: no 20:10:06 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-951 20:10:06 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-508 20:10:06 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The Cassini-Huygens mission revealed great complexity in Titan’s atmosphere. Indeed, mass spectrometers onboard Cassini detected the presence of ions of unexpectedly high masses [1]. These macromolecular ions are understood as the precursors of the aerosols abundant at lower altitude with formation mechanisms likely driven by ion chemistry [2]. These precursor molecules probably are polycyclic aromatic (nitrogen bearing) hydrocarbons (PAHs & N-PAHs) identified by their C-H infrared emission signatures [3], compatible with the detected ion mass-to-charge ratios [4]. Chemistry in ionospheres is triggered by UV photons and energetic particles pervading the Solar System. But specific to Titan is its place within Saturn’s magnetosphere where oxygenated ions, sourced from the plumes of Enceladus, were detected. 10 to 100 keV oxygen ions can reach fluxes of ~106 ions.cm-2.s-1 in Titan’s upper atmosphere [5]. Ions typically deposit on Titan between 1200 and 800 km in altitude and mainly loose energy until thermalization by interactions with N2 [6]. Yet a fraction of these ions must interact directly with the organics and contribute to Titan’s complex chemistry. As ion irradiation is known to trigger sputtering, chemical growth and possibly implantation, what is the impact of these processes on Titan’s chemical budget?Titan’s atmospheric chemistry has been historically investigated by subjecting N2:CH4 mixtures to representative energy sources triggering photolysis and radiolysis [7]. The resulting aerosol analogs, called “tholins”, are made of irregular polymeric structures with unsaturation levels indicative of N-PAHs, with infrared features of amines, (iso)cyanides, aliphatic and heteroaromatic groups. Tholins exposed to VUV [8] and plasma [9] irradiation showed erosion on the grains and non-uniform modification of chemical functions. Here, we used N-PAHs as simpler aerosol analogues to investigate and quantify distinct and competing processes triggered by ion irradiation. High resolution mass spectrometry analysis of O+-irradiated adenine (C5H5N5) showed the formation of different families of (HCN)-like polymeric structures of condensed aromatics [10]. During irradiation, sputtering also occurs and expels small molecules to the gas phase, typically HCN, comparable to plasma-driven erosion [11]. But adenine is not fully representative of Titan aerosols as tholins show a range of N/C ratios from 1.5 to 0 [12]. To get a broader picture of oxygen irradiation on a range of representative molecules, we have conducted new experiments on adenine, adenine:chrysene mixtures, bathophenanthroline (C24H16N2) and chrysene (C18H12) with N/C ratios of 1, ~0.2, 0.08 and 0 respectively.Irradiation experiments were performed at the ARIBE beam line coupled to the IGLIAS chamber at GANIL (Caen, France) [13] and at the HUN-REN Institute for Nuclear research (Atomki) in Debrecen (Hungary) with the AQUILA chamber [14] and the Electron Cyclotron Resonance ion source [15]. We used oxygen ions at 10 and 20 keV (for 18O) and at 70 and 108 keV (for 16O) to irradiate samples at 150 or 300 K with maximum fluences of 2x1016 ions/cm2. The experimental rationale varied depending on the process we aimed to quantify: single layers of hundreds of nanometers for sputtering and multiple layers for implantation. In-situ infrared spectroscopy and quadrupole mass spectrometry measurements are performed to track chemical changes and sputtering.Infrared analysis shows the progressive destruction of the initial molecular film, associated to its intact sputtering and to radiolysis followed by sublimation of volatile species [16]. The appearance of new bands allows to identify and quantify abundant radiolytic products, associated with dehydrogenation processes. Samples irradiated with 18O ions were analyzed ex-situ with an 18T-FT-ICR mass spectrometer at the CARMeN Institute (Rouen, France) with a resolution allowing unambiguous detection of implanted 18O. The molecular content of the irradiated samples was analyzed by Laser Desorption Ionization, revealing high molecular complexity with m/z reaching 700.We will present experimental results that provide insights into the heterogeneous processes in Titan’s upper atmosphere. By extracting sputtering yields and destruction cross sections, we provide input for photochemical-microphysical models of Titan’s complex atmosphere. By probing molecular growth through oxygen incorporation into C,H,N material, we investigate an added prebiotic interest for the aerosols sedimenting to the surface. This work can also have implications for outer solar system bodies like Triton, Pluto, Eris and Makemake where oxygen ions of the solar wind and galactic cosmic rays process ices and transient atmospheres of high hydrocarbon content.AcknowledgmentsThis work is supported by the French National Research Agency in the framework of the "Investissements d’avenir” program (ANR-15-IDEX-02) and the generic call for proposals (ANR-22-CE49-0017). The experiments were performed at the Grand Accélérateur National d’Ions Lourds (GANIL) by means of the CIRIL Interdisciplinary Platform, part of CIMAP laboratory, Caen, France. We acknowledge the fundings from ANR IGLIAS grant (ANR-13-BS05-0004) and ANR MIRRPLA grant (ANR-22-EXOR-0012) of the French Agence Nationale de la Recherche and Normandie Region (RIN 50/50). This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 871149. We acknowledge the funding from Europlanet’s Transnational Access Pilot programme 2025 (project code 25-EPN-P-5) and from Europlanet’s Transnational Access programme 2026 (project code 26-EPN-38). Access to the CNRS research infrastructure Infranalytics (FR2054) is gratefully acknowledged.References[1] F. J. Crary et al., PSS, 57, 1847-1856 (2009)[2] P. Lavvas et al., Proc. Natl. Acad. Sci. U.S.A., 110, 2729-2734 (2013)[3] M. López-Puertas et al., ApJ, 770, 132 (2013)[4] R. P. Haythornthwaite et al., PSJ, 2, 26 (2021)[5] T. E. Cravens et al., Geophysical Research Letters, 35, 3 (2008)[6] S. Hörst et al., JGR, 113, E10 (2008)[7] M. L. Cable et al., Chem Rev, 112, 1882 (2012)[8] N. Carrasco et al., Nature Astronomy, 2, 489 (2018)[9] A. Chatain et al., Icarus, 345, 113741 (2020)[10] F. Matuszewski et al., Icarus, 445, 116865 (2026)[11] A. Chatain et al., Icarus, 396, 115502 (2023)[12] H. Imanaka et al., PNAS, 107, 12423-12428 (2010)[13] B. Augé et al., Rev. Sci. Instrum., 89, 075105 (2018)[14] R. Rácz et al., Rev. Sci. Instrum., 95, 095105 (2024)[15] S. Biri et al., Eur. Phys. J. Plus, 136, 247 (2021)[16] E. Dartois et al., A&A, 671, A156 (2023)] 20:10:06 1819442 AIClient - Response from AI: no 20:10:06 1819442 CrossRefSearchJob - AI response: no 20:10:06 1819442 CrossRefSearchJob - Publication not relevant: 10.1158/0008-5472.32872525 20:10:06 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76401 20:10:06 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Rheumatoid arthritis (RA) involves persistent synovial inflammation and progressive destruction of cartilage and bone, where aberrantly activated fibroblast‐like synoviocytes (FLSs) play a central role. Although 5‐methylcytosine (m 5 C) modification is implicated in many diseases, its role in RA remains unclear. Here, we observed upregulated expression of the m 5 C methyltransferase NOP2/Sun domain family member 2 (NSUN2) in both synovial tissues (STs) and FLSs from RA patients. Functionally, NSUN2 knockdown suppressed migration and invasion of RA FLSs, whereas NSUN2 overexpression exerted opposing effects. Mechanistically, NSUN2 mediated m 5 C modification of isoprenylcysteine carboxyl methyltransferase (ICMT) mRNA and enhanced its stability. Furthermore, we identified salvianolic acid A (SAA) as an NSUN2 inhibitor, which phenocopied the effects of NSUN2 knockdown on RA FLSs. Given the well‐recognized ROS‐scavenging capacity of cerium oxide nanoparticles, we constructed Ce/SAA nanoparticles (Ce/SAA NPs) via coordination self‐assembly to enable synergistic therapy for RA. Notably, Ce/SAA NPs ameliorated arthritis in collagen‐induced arthritis (CIA) mice, and intra‐articular NSUN2‐siRNA attenuated disease progression in CIA rats. These results highlight NSUN2‑mediated m 5 C modification in RA pathogenesis and suggest NSUN2 as a therapeutic target. ] 20:10:07 1818966 AIClient - Response from AI: maybe; CO2 conversion 20:10:07 1818966 CrossRefSearchJob - AI response: maybe; CO2 conversion 20:10:07 1818966 CrossRefSearchJob - Publication relevant (maybe): 10.5194/epsc2026-474 20:10:07 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-73278-8 20:10:07 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Macrophage INSIG1 deficiency drives psoriasiform dermatitis via the SREBP2-STAT1 axis] 20:10:07 1818494 AIClient - Response from AI: no 20:10:07 1818494 CrossRefSearchJob - AI response: no 20:10:07 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-508 20:10:07 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1026 20:10:07 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Dust grains play a fundamental role in the physical processes regulating the formation of stars and planets. Recent observations of 12 young protostars found dust emissivity indices with values β < 1 (Maury+, 2019, Galametz+, 2019), which would imply that dust coagulated into grains over 100µm in size (Ysard+, 2019), much larger than what predicts actual paradigms of planet formation at this stage of stellar evolution. To address this issue, the PEBBLES project seeks to develop a methodology for characterizing dust properties in protostars. We aim to build new 3D MHD models with dust evolution and realistic optical properties, by accounting properly for composition and structure of grains. We aim to interpret the dust aggregate signatures in protostellar environments.The first step is to accurately account for the evolution of the dust size distribution through growth and fragmentation in 3D MHD models. These two processes are described by the Smoluchowski coagulation and the fragmentation equations. Solving accurately these equations while preserving tractable computational costs is a tremendous numerical challenge. I will present a new code COALA, based on the discontinuous Galerkin method (Lombart+, 2021, 2022, 2024) that addresses all these issues. I will show the first 3D MHD simulation of protostellar collapse with dust growth (Lombart+, 2026).The second step is to associate realistic dust optical properties of grains to the dust size distributions. Using laboratory-measured material properties from the THEMIS 2 dust model (Ysard+, 2024), we derive various grain shapes in the scope of picturing the evolution from small compact grains to potentially large fluffy aggregates. We used the Discrete Dipole approximation (DDA) code ADDA (Yurkin+, 2011) to compute our grains’ optical properties. First results show a heavy dependence of these optical properties on the shape, but also on the composition of dust grains.] 20:10:07 1819442 AIClient - Response from AI: no 20:10:07 1819442 CrossRefSearchJob - AI response: no 20:10:07 1819442 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76401 20:10:07 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-1036 20:10:07 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Nitrogen, oxygen, phosphorus, and sulfur are key elements in carbon-based biochemistry, and in-situ comet missions are a unique opportunity to study these elements' prevalence in pristine organics. A milestone was ESA's Rosetta mission, which investigated comet 67P/Churyumov-Gerasimenko (hereafter 67P). The on-board high-resolution Double Focusing Mass Spectrometer (DFMS), part of the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA; Balsiger et al. 2007) analyzed the chemical composition of 67P in great detail (Altwegg et al. 2019). Subsequent studies revealed a plethora of complex organic molecules reaching from pure hydrocarbons (Hänni et al. 2022), O-bearing molecules (Hänni et al. 2023), N-bearing compounds (Hänni et al. 2025) as well as dimethyl sulfide (Hänni et al. 2024). In these previous studies, the chemical species formed during the experiments were primarily identified based on signals corresponding to their molecular masses and (major) fragments produced by electron-impact in the mass spectra. However, such an approach can lead to ambiguities, as best-fitting molecules are hand-picked, introducing human bias and error propagation. In addition, isomers with similar fragmentation patterns further increase such degeneracies.In this work, the previously acquired mass spectra will therefore be reanalyzed using a Monte Carlo-based deconvolution approach (Gautier et al. 2020) to obtain a more standardized, reproducible, and intercomparable interpretation of the chemical composition. By statistically exploring large numbers of possible combinations of candidate molecules and their associated fragmentation patterns, this method aims to disentangle overlapping contributions in the spectra and improve the identification of true molecular compounds while minimizing misassignments caused by fragmentation artifacts.Introducing this statistical approach standardizes the analysis procedure and reduces the influence of human bias on the spectral interpretation, while also testing whether the results align with previous studies. Furthermore, the results will be compared to those reported by the Cometary Sampling and Composition Experiment (COSAC; Goesmann et al. 2007) aboard the Philae lander, where the same software was used for the deconvolution of the mass spectra (Leseigneur et al. 2022). References:Altwegg, K., Balsiger, H., & Fuselier, S. A. (2019). Cometary chemistry and the origin of icy solar system bodies: the view after Rosetta. Annual Review of Astronomy and Astrophysics, 57(1), 113-155.Balsiger, H., Altwegg, K., Bochsler, P., Eberhardt, P., Fischer, J., Graf, S., ... & Wollnik, H. (2007). Rosina–Rosetta orbiter spectrometer for ion and neutral analysis. Space Science Reviews, 128(1), 745-801.Gautier, T., Serigano, J., Bourgalais, J., Hörst, S. M., & Trainer, M. G. (2020). Decomposition of electron ionization mass spectra for space application using a Monte‐Carlo approach. Rapid Communications in Mass Spectrometry, 34(8), e8684.Goesmann, F., Rosenbauer, H., Roll, R., Szopa, C., Raulin, F., Sternberg, R., ... & Munoz-Caro, G. (2007). COSAC, the cometary sampling and composition experiment on Philae. Space Science Reviews, 128(1), 257-280.Hänni, N., Altwegg, K., Combi, M., Fuselier, S. A., De Keyser, J., Rubin, M., & Wampfler, S. F. (2022). Identification and characterization of a new ensemble of cometary organic molecules. Nature Communications, 13(1), 3639.Hänni, N., Altwegg, K., Baklouti, D., Combi, M., Fuselier, S. A., De Keyser, J., ... & Wampfler, S. F. (2023). Oxygen-bearing organic molecules in comet 67P’s dusty coma: First evidence for abundant heterocycles. Astronomy & Astrophysics, 678, A22.Hänni, N., Altwegg, K., Combi, M., Fuselier, S. A., De Keyser, J., Ligterink, N. F., ... & Wampfler, S. F. (2024). Evidence for abiotic dimethyl sulfide in cometary matter. The Astrophysical Journal, 976(1), 74.Hänni, N., Altwegg, K., Baklouti, D., Combi, M., Fuselier, S. A., De Keyser, J., ... & Wampfler, S. F. (2025). Nitrogen-and nitrogen-oxygen-bearing organic molecules in comet 67P/Churyumov-Gerasimenko: An untargeted investigation. Astronomy & Astrophysics, 699, A135.Leseigneur, G., Bredehöft, J. H., Gautier, T., Giri, C., Krüger, H., MacDermott, A. J., ... & Goesmann, F. (2022). ESA's Cometary Mission Rosetta—Re‐Characterization of the COSAC Mass Spectrometry Results. Angewandte Chemie International Edition, 61(29), e202201925.] 20:10:08 1818966 AIClient - Response from AI: no 20:10:08 1818966 CrossRefSearchJob - AI response: no 20:10:08 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-73278-8 20:10:08 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10606-0 20:10:08 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Depression involves dysregulation across distributed cortico-limbic circuits, and ketamine is notable for its rapid antidepressant effects. Although depression and ketamine treatment have been linked to altered brain network topology, how within-frequency and cross-frequency coupling are jointly reorganized at the brain-wide level remains unclear. Here, we developed a frequency-varying multilayer brain functional network (FMBFN) framework to analyze local field potential recordings from eight brain regions in male C57BL/6 mice. This framework integrates within- and cross-frequency coupling and extracts multi-scale network features to characterize brain network structure. Applying this approach in the chronic social defeat stress (CSDS) model, we found that CSDS was associated with frequency-specific hyperconnectivity and selective alterations in network integration during social interaction. Ketamine reversed social avoidance and induced the distinct reorganization of multilayer network topology, including region-specific nodal changes. Notably, the lateral habenula showed the response pattern opposite to that of the other recorded regions. As an exploratory cross-modal extension, we further examined gut microbial features and found that specific ketamine-associated microbial changes were linked to global network topology, suggesting candidate gut-brain association patterns. Together, these findings establish the FMBFN framework as a systems-level tool for characterizing brain-wide neural dynamics in psychiatric disorders and for linking network-level alterations to biological contexts.] 20:10:08 1818494 AIClient - Response from AI: no 20:10:08 1818494 CrossRefSearchJob - AI response: no 20:10:08 1819442 AIClient - Response from AI: no 20:10:08 1819442 CrossRefSearchJob - AI response: no 20:10:08 1819442 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1036 20:10:08 1818494 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-1026 20:10:08 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s42003-026-10598-x 20:10:08 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/celc.70268 20:10:08 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Choline-dependent methionine metabolism supports leukemia progression] 20:10:08 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ Microbial electrochemical technologies (MET), among others, facilitate sustainable CO 2 conversion into chemicals at ambient temperature and neutral pH. Reactors used in MET, called bioelectrochemical systems (BES), come in different types; bed electrodes are prominent; however, they lack reproducible, geometrically defined granular electrodes. Typical carbon granules are irregular, have wide size distributions, and poorly defined electrochemical properties, which limit their engineering applications. This study introduces sphere‐like granular biochar (GB) cathodes, produced by pyrolyzing beechwood spheres at 850°C (GB850). GB850 electrodes were modified and characterized on a single‐granule basis. The hydrogen evolution reaction (HER) at neutral pH models abiotic cathodic reactions, reflecting its important role as an intermediate in CO 2 ‐reducing BES. To improve electrocatalytic activity, GB850 was modified with nickel‐molybdenum (GB850‐NiMo), and the uniform electrodeposition was verified through structural and compositional analysis. GB850‐NiMo exhibited an HER overpotential of only 106 ± 9 mV at −1 mA/cm 2 , 85% lower than that of GB850. Its electrochemical double‐layer capacitance ( C dl ) increased fourfold after NiMo deposition, indicating a larger electrochemically active surface area. The apparent stability of GB850‐NiMo highlights its potential to optimize bed electrodes in CO 2 ‐reducing BES through controlled modifications. The highly defined geometry of sphere‐like GB offers a valuable tool for future engineering. ] 20:10:09 1818966 AIClient - Response from AI: no 20:10:09 1818966 CrossRefSearchJob - AI response: no 20:10:09 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10606-0 20:10:09 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75123-4 20:10:09 1818494 AIClient - Response from AI: yes; Electrochemical CO2 conversion 20:10:09 1818494 CrossRefSearchJob - AI response: yes; Electrochemical CO2 conversion 20:10:09 1818494 CrossRefSearchJob - Publication relevant (yes): 10.1002/celc.70268 20:10:09 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Abstract Resistance to Bruton’s tyrosine kinase inhibitors (BTKi) remains a major therapeutic challenge in B-cell malignancies. Here, we identify chromatin remodeler BRG1-mediated suppression of ferroptosis as a central mechanism of BTKi resistance in mantle cell lymphoma (MCL), in which aberrant BRG1-dependent transcription program protects cells from BTKi-induced ferroptosis by restricting reactive oxygen species (ROS) and labile iron. Mechanistically, BRG1 promotes resistance through regulation of both BTK-dependent survival signaling and a BTK-independent transcriptional program. The latter is mediated by BRG1-driven induction of MEF2B, which upregulates atypical mitochondrial complex I subunit NDUFA4L2. Increased NDUFA4L2 restricts cellular respiration, preemptively limiting mitochondrial ROS generation and activating AMPK signaling, together reducing susceptibility to lipid peroxidation and ferroptosis. Pharmacologic inhibition of BRG1 disrupts these programs, restoring ferroptotic sensitivity and synergizing with BTKi across resistant MCL models. Together, our study establishes BRG1 as a central regulator of BTKi resistance and provides a rationale for co-targeting BRG1 and BTK as a therapeutic strategy for B-cell malignancies.] 20:10:10 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76448 20:10:10 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Correction to “Bioinspired Polyacrylic Acid‐Based Dressing: Wet Adhesive, Self‐Healing, and Multi‐Biofunctional Coacervate Hydrogel Accelerates Wound Healing”] 20:10:10 1819442 AIClient - Response from AI: no 20:10:10 1819442 CrossRefSearchJob - AI response: no 20:10:10 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s42003-026-10598-x 20:10:10 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3104852 20:10:10 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Aerogels to reduce optical reflections] 20:10:10 1818966 AIClient - Response from AI: no 20:10:10 1818966 CrossRefSearchJob - AI response: no 20:10:10 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75123-4 20:10:10 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3103027 20:10:10 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Streamlining spectroscopic observations: a real-time data reduction display for Keck and beyond] 20:10:11 1818966 AIClient - Response from AI: no 20:10:11 1818966 CrossRefSearchJob - AI response: no 20:10:11 1818966 CrossRefSearchJob - Publication not relevant: 10.1117/12.3103027 20:10:11 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1002/advs.76063 20:10:11 1818494 AIClient - Response from AI: no 20:10:11 1818494 CrossRefSearchJob - AI response: no 20:10:11 1818494 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76448 20:10:11 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ABSTRACT Hybrid solid electrolytes (HSEs) represent a promising material system for lithium metal batteries by combining high ionic conductive and mechanically strong inorganic with soft organic solid electrolytes. However, for HSEs consisting of ceramic fillers, lithium hopping between the polymer and ceramic phases remains unproven, emphasizing the tortuosity inside the polymer phase as a pivotal factor. Herein, we report an in‐plane aligned Li 6.6 La 3 Zr 1.6 Ta 0.4 O 12 (Ta‐LLZO) ceramic fiber network structure for HSEs and compare its morphological nature to typical LLZO‐based fillers. Simulations reveal a high tortuosity inside the polymer phase with a parallel to the electrodes aligned network structure, enabling dendritic structure blocking behavior, but still reaching decent ionic transport (0.44 mS cm −1 , 60°C). Post‐mortem microscopy analyses confirmed the dendrite blocking mechanism of the network, ultimately leading to long cycling lifetime of > 1100 h in symmetric lithium metal cells operated with 0.1 mA cm −2 at 60°C. Overall, the ceramic network HSE represents a superior morphology by combining decent ionic conductivity, low resistance and long cycling life in symmetric and full cells with LiFePO 4 cathodes. The comparison of different filler characteristics with a special focus on tortuosity eventually facilitates the evaluation of these properties for the purpose of optimizing HSEs. ] 20:10:11 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.3389/fchem.2026.1804888 20:10:11 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ Introduction The Na–K–2Cl cotransporter isoform 1 (NKCC1) regulates cell volume and ionic distribution, thereby also controlling the efficacy of neuronal GABAergic inhibition. enhanced activity of the NKCC1 chloride importer and high Cl. levels has been reported in a long list of disorders, including epilepsies, brain trauma, peripheral and central cancers, spinal cord injury or chronic pain, and cerebrovascular infarcts, indicating that NKCC1 inhibitors might constitute promising therapeutic avenues. Synthetized four decades ago, bumetanide constitutes the only agent that is widely used in animal models and human trials, limiting the possibility to assign some NKCC1 inhibitors specifically to treat some disorders. Methods Here, we have synthetized many novel NKCC1 inhibitors to augment the range of molecules that can be tested in animal models and pre-IND tests. We used modifications of the bumetanide parent molecule by modifying two sites with alterations that have not been envisaged before. Specifically, we incorporated carboxylic acid bioisosteres and sulfonimidamides or sulfoximines moieties. Their efficacy was evaluated against NKCC1, NKCC2, and KCC2 using human cell lines. Results and discussion The synthesis of the new inhibitors and the structure–activity relationship (SAR) are described. Some molecules are superior to bumetanide as NKCC1 inhibitors, which widens the family of NKCC1 inhibitors and paves the way for more efficient agents. Our aims here are solely chemical, namely, describing the possible targets of the bumetanide molecule that can be changed using novel approaches. In the future, we and others will test these molecules in animal models and clinical trials to validate the use of some of them in treating a variety of disorders. ] 20:10:11 1819442 AIClient - Response from AI: no 20:10:11 1819442 CrossRefSearchJob - AI response: no 20:10:11 1819442 CrossRefSearchJob - Publication not relevant: 10.1117/12.3104852 20:10:11 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74954-5 20:10:11 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Single cell spatial transcriptomics track the evolutionary hierarchy and microenvironment remodeling during breast carcinoma invasion] 20:10:11 1818494 AIClient - Response from AI: no 20:10:11 1818494 CrossRefSearchJob - AI response: no 20:10:11 1818494 CrossRefSearchJob - Publication not relevant: 10.3389/fchem.2026.1804888 20:10:11 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75235-x 20:10:11 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Thermoresponsive and xenon-triggered gate-opening in flexible three-dimensional covalent organic framework for selective xenon capture] 20:10:11 1818966 AIClient - Response from AI: no 20:10:11 1818966 CrossRefSearchJob - AI response: no 20:10:11 1818966 CrossRefSearchJob - Publication not relevant: 10.1002/advs.76063 20:10:11 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74880-6 20:10:11 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Prokaryotic Schlafen proteins cleave tRNAs during type III CRISPR immunity] 20:10:11 1819442 AIClient - Response from AI: no 20:10:11 1819442 CrossRefSearchJob - AI response: no 20:10:11 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74954-5 20:10:12 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74603-x 20:10:12 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Spatial transcriptomic atlas of aggressive osteosarcomas reveals shared immune landscape and targetable surface markers] 20:10:12 1818966 AIClient - Response from AI: no 20:10:12 1818966 CrossRefSearchJob - AI response: no 20:10:12 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74880-6 20:10:12 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75198-z 20:10:12 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Architecture of the Wza-Wzc complex that mediates colanic acid translocation across the cell envelope in Gram-negative bacteria] 20:10:13 1819442 AIClient - Response from AI: no 20:10:13 1819442 CrossRefSearchJob - AI response: no 20:10:13 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74603-x 20:10:13 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.13140/rg.2.2.22043.63529 20:10:13 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [graphical abstract] 20:10:13 1818494 AIClient - Response from AI: yes; Host-Guest interactions in supramolecular chemistry 20:10:13 1818494 CrossRefSearchJob - AI response: yes; Host-Guest interactions in supramolecular chemistry 20:10:13 1818494 CrossRefSearchJob - Publication relevant (yes): 10.1038/s41467-026-75235-x 20:10:14 1819442 AIClient - Response from AI: no 20:10:14 1819442 CrossRefSearchJob - AI response: no 20:10:14 1819442 CrossRefSearchJob - Publication not relevant: 10.13140/rg.2.2.22043.63529 20:10:14 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/egusphere-2026-3794-supplement 20:10:14 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Supplementary material to "Towards harmonized measurements of condensable vapors: insights from the intercomparison of six chemical ionization mass spectrometers at a boreal forest site"] 20:10:14 1818966 AIClient - Response from AI: no 20:10:14 1818966 CrossRefSearchJob - AI response: no 20:10:14 1818966 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75198-z 20:10:14 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.3390/inorganics14070179 20:10:14 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [We demonstrate the molecular beam epitaxy growth of two-dimensional van der Waals ferromagnet Fe3GaTe2 films with precisely controlled thicknesses down to a single unit cell. Magneto-optical Kerr effect microscopy measurements reveal robust room-temperature ferromagnetism with perpendicular magnetic anisotropy persisting across all thicknesses, including finite coercivity in monolayer films. The magnetic domain structures show strong thickness dependence: ultrathin films exhibit near-single-domain states without resolved domain nucleation or domain wall propagation, while thicker films develop complex multi-domain configurations featuring bubble-like domains. These findings underscore the pivotal role of dimensional confinement in modulating the magnetic properties of Fe3GaTe2 and provide critical insights into thickness-dependent phenomena in two-dimensional magnets, advancing their prospects for room-temperature spintronic applications.] 20:10:14 1818494 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74529-4 20:10:14 1818494 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Robust SWCNT-OH/GO membranes for scalable recovery of moxifloxacin from high-salinity organic wastewater] 20:10:14 1819442 AIClient - Response from AI: no 20:10:14 1819442 CrossRefSearchJob - AI response: no 20:10:14 1819442 CrossRefSearchJob - Publication not relevant: 10.5194/egusphere-2026-3794-supplement 20:10:14 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-484 20:10:14 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [The interstellar medium and many Solar System bodies such as comets, meteorites, interplanetary dust particles (IDPs) and Ultracarbonaceous Antarctic Micrometeorites (UCAMMs) contain vast reservoirs of organic molecules. Laboratory analyses on these bodies have revealed that a major portion of carbon is incorporated in Insoluble Organic Matter (IOM) – a carbonaceous cross-linked macromolecular network that is resistant to demineralizing acids and organic solvents. Further analyses on IOMs from different sources also shows it exhibits extreme D/H isotopic enrichment in IOM, hinting their origin in the cold interstellar medium, where ion-molecule reaction is able to facilitate deuterium incorporation. While many laboratory works have studied the formation of organic molecules, only a handful have been characterized as analogues or precursor of IOM. In addition, the formation of IOM itself is still a fundamental question, which further necessitates laboratory works to elucidate the conditions necessary for its formation.We thus simulate the formation of IOM precursor by co-depositing astrophysically relevant gas mixtures at 10K and heavily irradiate the interstellar ice analogues with energetic electrons, a stand-in for cosmic rays. The resulting residue is characterized with Raman spectroscopy, focusing on the D (disordered) and G (graphitic) bands that are tell-tale signatures of IOM. We find that the transformation from ice to IOM precursor requires an intermediate step by first forming medium-complexity Soluble Organic Molecules and removing precursor ice. This then involves the reirradiation of the residue left after the volatile components including water are desorbed. We hypothesize that precursor ice, in particular H2O, inhibits the growth of organic molecules to macromolecular sizes. These findings suggest that IOM formed in a heavily irradiated environment where precursors underwent an “ice-dry” cycle to remove volatile ice components.] 20:10:15 1818966 AIClient - Response from AI: no 20:10:15 1818966 CrossRefSearchJob - AI response: no 20:10:15 1818966 CrossRefSearchJob - Publication not relevant: 10.3390/inorganics14070179 20:10:15 1818966 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75190-7 20:10:15 1818966 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Author Correction: Economical biogas direct methanation to pipeline grade natural gas via structured Ni based inverse catalyst] 20:10:15 1818494 AIClient - Response from AI: no 20:10:15 1818494 CrossRefSearchJob - AI response: no 20:10:15 1818494 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74529-4 20:10:15 1818494 DEBUG DownloadPDFJob - Loading from URL: https://www.nature.com/articles/s41467-026-75235-x_reference.pdf 20:10:15 1818494 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:10:15 1819442 AIClient - Response from AI: no 20:10:15 1819442 CrossRefSearchJob - AI response: no 20:10:15 1819442 CrossRefSearchJob - Publication not relevant: 10.5194/epsc2026-484 20:10:15 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-74734-1 20:10:15 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Projected health benefits and cost offsets from the United States National Hepatitis C Elimination Initiative] 20:10:16 1819442 AIClient - Response from AI: no 20:10:16 1819442 CrossRefSearchJob - AI response: no 20:10:16 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-74734-1 20:10:16 1819442 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75130-5 20:10:16 1819442 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Critical slowing down of semiarid vegetation resilience is amplified by intensifying heatwaves] 20:10:17 1819442 AIClient - Response from AI: no 20:10:17 1819442 CrossRefSearchJob - AI response: no 20:10:17 1819442 CrossRefSearchJob - Publication not relevant: 10.1038/s41467-026-75130-5 20:10:17 1819442 DEBUG DownloadPDFJob - Loading from URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75235-x/MediaObjects/41467_2026_75235_MOESM1_ESM.pdf 20:10:17 1819442 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:10:17 1818966 AIClient - Response from AI: yes; CO2 conversion 20:10:17 1818966 CrossRefSearchJob - AI response: yes; CO2 conversion 20:10:17 1818966 CrossRefSearchJob - Publication relevant (yes): 10.1038/s41467-026-75190-7 20:10:18 1818966 DEBUG DownloadPDFJob - Loading from URL: 20:10:18 1818966 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:10:20 1818966 DEBUG DownloadPDFJob - Not a PDF file: /opt/downloadPDF/chemwiki_pubstore/5fbb5521abc279ae4f660f8a2027b2c5.pdf. Deleted. 20:10:20 1818966 DEBUG DownloadPDFJob - URL: Download location: /opt/downloadPDF/chemwiki_pubstore/5fbb5521abc279ae4f660f8a2027b2c5.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:10:19 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: An error occurred: invalid argument (Session info: chrome=147.0.7727.101) Build info: version: '4.41.0', revision: '9fc754f' System info: os.name: 'Linux', os.arch: 'amd64', os.version: '6.8.0-60-generic', java.version: '21.0.7' Driver info: org.openqa.selenium.chrome.ChromeDriver Command: [f34a1d96c9ecc83232f7f6c9b84b2fff, get {url=}] Capabilities {acceptInsecureCerts: false, browserName: chrome, browserVersion: 147.0.7727.101, chrome: {chromedriverVersion: 147.0.7727.117 (474cc805edd..., userDataDir: /tmp/org.chromium.Chromium....}, fedcm:accounts: true, goog:chromeOptions: {debuggerAddress: localhost:46565}, goog:processID: 1819853, networkConnectionEnabled: false, pageLoadStrategy: normal, platformName: linux, proxy: Proxy(), se:cdp: ws://localhost:46565/devtoo..., se:cdpVersion: 147.0.7727.101, setWindowRect: true, strictFileInteractability: false, timeouts: {implicit: 0, pageLoad: 300000, script: 30000}, unhandledPromptBehavior: dismiss and notify, webauthn:extension:credBlob: true, webauthn:extension:largeBlob: true, webauthn:extension:minPinLength: true, webauthn:extension:prf: true, webauthn:virtualAuthenticators: true} Session ID: f34a1d96c9ecc83232f7f6c9b84b2fff org.openqa.selenium.InvalidArgumentException: invalid argument (Session info: chrome=147.0.7727.101) Build info: version: '4.41.0', revision: '9fc754f' System info: os.name: 'Linux', os.arch: 'amd64', os.version: '6.8.0-60-generic', java.version: '21.0.7' Driver info: org.openqa.selenium.chrome.ChromeDriver Command: [f34a1d96c9ecc83232f7f6c9b84b2fff, get {url=}] Capabilities {acceptInsecureCerts: false, browserName: chrome, browserVersion: 147.0.7727.101, chrome: {chromedriverVersion: 147.0.7727.117 (474cc805edd..., userDataDir: /tmp/org.chromium.Chromium....}, fedcm:accounts: true, goog:chromeOptions: {debuggerAddress: localhost:46565}, goog:processID: 1819853, networkConnectionEnabled: false, pageLoadStrategy: normal, platformName: linux, proxy: Proxy(), se:cdp: ws://localhost:46565/devtoo..., se:cdpVersion: 147.0.7727.101, setWindowRect: true, strictFileInteractability: false, timeouts: {implicit: 0, pageLoad: 300000, script: 30000}, unhandledPromptBehavior: dismiss and notify, webauthn:extension:credBlob: true, webauthn:extension:largeBlob: true, webauthn:extension:minPinLength: true, webauthn:extension:prf: true, webauthn:virtualAuthenticators: true} Session ID: f34a1d96c9ecc83232f7f6c9b84b2fff at org.openqa.selenium.remote.ErrorCodec.decode(ErrorCodec.java:169) at org.openqa.selenium.remote.codec.w3c.W3CHttpResponseCodec.decode(W3CHttpResponseCodec.java:142) at org.openqa.selenium.remote.codec.w3c.W3CHttpResponseCodec.decode(W3CHttpResponseCodec.java:49) at org.openqa.selenium.remote.HttpCommandExecutor.execute(HttpCommandExecutor.java:223) at org.openqa.selenium.remote.service.DriverCommandExecutor.invokeExecute(DriverCommandExecutor.java:216) at org.openqa.selenium.remote.service.DriverCommandExecutor.execute(DriverCommandExecutor.java:174) at org.openqa.selenium.remote.RemoteWebDriver.execute(RemoteWebDriver.java:604) at org.openqa.selenium.remote.RemoteWebDriver.get(RemoteWebDriver.java:372) at com.diqa.downloader.Main.main(Main.java:112) 20:10:20 1818966 DEBUG DownloadPDFJob - Loading from URL: https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/celc.70268 20:10:20 1818966 DownloadPDFJob - $wgChemChromeDriverLog is not set 20:10:23 1818494 DEBUG DownloadPDFJob - URL: https://www.nature.com/articles/s41467-026-75235-x_reference.pdf Download location: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:10:16 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://www.nature.com/articles/s41467-026-75235-x_reference.pdf DONE. Final URL after redirect: https://www.nature.com/articles/s41467-026-75235-x_reference.pdf An error occurred: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf (Is a directory) java.io.FileNotFoundException: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf (Is a directory) at java.base/java.io.FileOutputStream.open0(Native Method) at java.base/java.io.FileOutputStream.open(FileOutputStream.java:289) at java.base/java.io.FileOutputStream.(FileOutputStream.java:230) at java.base/java.io.FileOutputStream.(FileOutputStream.java:118) at com.diqa.downloader.Main.downloadPdf(Main.java:195) at com.diqa.downloader.Main.main(Main.java:127) 20:10:24 1819442 DEBUG DownloadPDFJob - URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75235-x/MediaObjects/41467_2026_75235_MOESM1_ESM.pdf Download location: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:10:18 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75235-x/MediaObjects/41467_2026_75235_MOESM1_ESM.pdf DONE. Final URL after redirect: https://static-content.springer.com/esm/art%3A10.1038%2Fs41467-026-75235-x/MediaObjects/41467_2026_75235_MOESM1_ESM.pdf An error occurred: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf (Is a directory) java.io.FileNotFoundException: /opt/downloadPDF/chemwiki_pubstore/f6935c33627085a9abeb1c8efd1f5532.pdf (Is a directory) at java.base/java.io.FileOutputStream.open0(Native Method) at java.base/java.io.FileOutputStream.open(FileOutputStream.java:289) at java.base/java.io.FileOutputStream.(FileOutputStream.java:230) at java.base/java.io.FileOutputStream.(FileOutputStream.java:118) at com.diqa.downloader.Main.downloadPdf(Main.java:195) at com.diqa.downloader.Main.main(Main.java:127) 20:10:30 1818966 DEBUG DownloadPDFJob - Not a PDF file: /opt/downloadPDF/chemwiki_pubstore/30977f30c79c1ec042f40bd8f323ee93.pdf. Deleted. 20:10:30 1818966 DEBUG DownloadPDFJob - URL: https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/celc.70268 Download location: /opt/downloadPDF/chemwiki_pubstore/30977f30c79c1ec042f40bd8f323ee93.pdf Using chrome webdriver logfile: /tmp/chromedriver.log Using chrome webdriver: /opt/downloadPDF/chromedriver Using chrome binary: /usr/bin/google-chrome Initializing chrome driver... Jul 03, 2026 8:10:21 PM org.openqa.selenium.devtools.CdpVersionFinder findNearestMatch WARNING: Unable to find an exact match for CDP version 147, returning the closest version; found: 143; Please update to a Selenium version that supports CDP version 147 DONE. Getting initial URL: https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/celc.70268 DONE. Final URL after redirect: https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/celc.70268 An error occurred: Failed to download PDF. HTTP status: 403 java.lang.RuntimeException: Failed to download PDF. HTTP status: 403 at com.diqa.downloader.Main.downloadPdf(Main.java:186) at com.diqa.downloader.Main.main(Main.java:127) 21:10:02 1822559 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-929 21:10:02 1822559 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Stars and planets form in dense cores within molecular clouds. These cosmic nurseries are where we see the first formation of interstellar ices. Composed mainly of H2O, CO2 and CO, these ice species and their reaction products are the likely precursors to the complex organic molecules (COMs) that enable the development of life on planets such as our own. Yet their origin and evolution, and the survival of the volatile material trapped within them through the violent star formation process, remain poorly understood. This fundamentally limits our ability to determine how molecules of great astrobiological significance are delivered to planetary bodies. Figure 1: The likely dominant fractionation mechanisms that determine the carbon isotope ratio imprinted in the ice observed in pre- and protostellar environments.The 12C/13C ratio is a sensitive probe of the physical and chemical conditions under which carbon-bearing ices form and evolve. The initial ratio is set by the distinct origins of the two isotopes: 12C is produced rapidly in massive stars, while a fraction of 12C is converted to it’s weaker counterpart 13C via the CNO cycle in later stellar generations. After injection into the interstellar medium (ISM), fractionation processes enrich or deplete one isotope relative to the other. In star-forming regions the isotope fractionation is driven by a combination of gas-phase and grain-surface processes that dominate during different physical and chemical epochs. For the abundant carbon-bearing ices, CO and CO2, the isotope ratio is therefore thought to preserve a chemical memory of the environment in which they formed, making it a valuable diagnostic of chemical evolution across the star-forming process. Understanding carbon isotope fractionation can shine a light on the inheritance or in-situ formation of molecules during different stages of star and planet formation. If the fractionation patterns established in molecular clouds are preserved through the protostellar phase, they may be inherited by protoplanetary disks and ultimately by planetary bodies. Conversely, if isotope ratios are significantly reprocessed during star formation, they instead reflect local conditions rather than primordial inheritance. Distinguishing between these scenarios has important implications for tracing the chemical origin of complex molecules across evolutionary stages, from cold molecular clouds to protostellar environments and planetary systems. Figure 2: JWST WFSS observations allow us to obtain spectra along lines of sight towards tens to hundreds of background sources in a single observation.The unrivalled sensitivity and multiplexing capabilities of The James Webb Space Telescope (JWST), now allows us to probe the chemical environment across star-forming regions with a resolution like never before. I will present 12C/13C ratios derived from JWST NIRCam Wide Field Slitless Spectroscopy (WFSS) observations towards the Chamaeleon I molecular cloud, obtained as part of the Ice Age Early Release Science programme (PID 1309; P.I. M. McClure). Spectra were extracted for 33 background sources along pencil-beam lines of sight through the cloud, in the vicinity of the deeply embedded class 0 protostar Cha MMS1, providing the largest sample of co-spatial ice isotope measurements within a single star-forming region to date. I will examine whether the carbon isotope ratio varies between ice species, whether it shows spatial dependence across the cloud, what this tells us about the chemical evolution across the region, and how the values derived in this study relate to those observed across the broader star and planet formation sequence.] 21:10:03 1822559 ERROR CrossRefSearchJob - You exceeded your current quota, please check your plan and billing details. For more information on this error, read the docs: https://platform.openai.com/docs/guides/error-codes/api-errors. 21:11:02 1822601 CrossRefSearchJob - CrossRefSearchJob with doi 10.3762/bjoc.22.77 21:11:02 1822601 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [ Spacer length is a key molecular parameter governing the self-assembly of short peptides. Here, we investigate isoleucine-cysteine-alanine (ICA) tripeptides containing carbon spacers of 6, 3, or 0 methylene units linking the peptide backbone to a hydrophobic naphthalene (Nap) π-block. Using complementary spectroscopic and microscopic techniques, we show that spacer length controls the balance between conformational flexibility and directional non-covalent interactions, thereby dictating assembly pathways and material properties. The results establish a correlation between spacer length and assembly propensity, with the longest spacer (C 6 ) consistently promoting aggregation more effectively than the intermediate analogue (C 3 ), whereas peptides containing the rigid C 0 -spacer fail to develop ordered nanostructures. These findings identify spacer length as a powerful design parameter for tuning peptide self-assembly across multiple length scales. ] 21:11:02 1822601 ERROR CrossRefSearchJob - You exceeded your current quota, please check your plan and billing details. For more information on this error, read the docs: https://platform.openai.com/docs/guides/error-codes/api-errors. 21:11:02 1822601 CrossRefSearchJob - CrossRefSearchJob with doi 10.1117/12.3112726 21:11:02 1822601 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Screening and prediction of CO2/CH4 adsorption separation by metal organic frameworks] 21:11:03 1822601 ERROR CrossRefSearchJob - You exceeded your current quota, please check your plan and billing details. For more information on this error, read the docs: https://platform.openai.com/docs/guides/error-codes/api-errors. 21:12:02 1822633 CrossRefSearchJob - CrossRefSearchJob with doi 10.5194/epsc2026-474 21:12:02 1822633 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [IntroductionThe icy Galilean moons — Europa, Ganymede, and Callisto — are major targets in the search for habitable environments because they likely harbor subsurface oceans beneath their icy crusts. Assessing their habitability requires understanding the origin and evolution of complex organic molecules (COMs), which are key precursors of prebiotic chemistry.Although COMs have not yet been directly detected on the Galilean moons, upcoming missions such as ESA’s JUICE and NASA’s Europa Clipper will provide new constraints on the abundance and distribution of organics, salts, and volatile ices through infrared, submillimeter, and mass spectrometry observations.While the formation and transport of COMs have been extensively studied in protoplanetary disks, their evolution within circumplanetary disks (CPDs), where giant-planet satellites form, remains poorly understood. COMs inherited from the protosolar nebula may have been altered or destroyed during transport into Jupiter’s CPD, while the CPD itself may also have enabled in situ organic synthesis through thermal and photochemical processing of icy particles.This study investigates the formation and transport of COMs in Jupiter’s evolving CPD using a time-dependent disk model coupled to particle transport calculations. Two formation pathways are explored: thermal processing of NH3:CO2 ices [1] and UV photochemistry of CH3OH-rich particles [2]. The goal is to determine under which conditions COMs can form, survive, and become incorporated into the Galilean moons.MethodologyThe study employs a two-dimensional gas-starved model of Jupiter’s CPD, which evolves from a hot, massive disk to a colder and less dense configuration as Jupiter’s accretion rate decreases with time. The nominal model assumes an initial accretion rate of 6.6 × 10−6MJ yr−1, a depletion timescale of 20 kyr, a turbulent viscosity parameter α = 10−3, and a centrifugal radius of 50 RJ. The thermodynamic structure of the CPD is controlled by viscous heating, radiative cooling, and irradiation from a young Jupiter with a surface temperature near 2000 K. The model naturally produces shadowed regions that can cool the disk locally by up to 100 K.Particle transport is modeled using a Lagrangian framework accounting for gas drag, turbulence, diffusion, and settling. Simulations track particles ranging from 1 μm to 1 cm released at different epochs and locations within the CPD. Two COM formation pathways are explored: thermal processing of NH3:CO2 ices between 80 and 260 K, and UV photochemistry of CH3OH-rich ices. UV fluence is computed self-consistently along particle trajectories while accounting for attenuation by gas and dust opacity.The simulations therefore couple disk evolution, particle transport, irradiation exposure, and ice chemistry to determine where and when COMs can form and survive within Jupiter’s CPD.ResultsThe simulations show that thermal processing dominates COM formation within Jupiter’s CPD. Particles drifting inward through the disk systematically cross regions with temperatures between 80 and 260 K, where NH3:CO2 ices are efficiently converted into COM-bearing material within a few hundred years.At early epochs (t0 = 50 kyr), particles smaller than 1 mm remain strongly coupled to the gas, while larger particles rapidly migrate inward due to gas drag. Figure 1 shows that many trajectories intersect the thermal COM formation zone located between ~20 RJ and the centrifugal radius. In contrast, UV-driven chemistry is much less efficient. CH3OH-rich particles generally sublimate before accumulating sufficient UV fluence to trigger substantial photochemical COM formation. Only a limited fraction of small particles released late in the disk evolution reach irradiation thresholds derived from laboratory experiments. As the CPD evolves and gas densities decrease, particle-gas coupling weakens and even micron-sized grains drift inward. The thermal processing region simultaneously migrates closer to Jupiter, but particles continue to experience efficient thermal processing before significant UV irradiation occurs.The simulations also show that increasing particle density, turbulent viscosity, or lowering the disk accretion rate further suppresses irradiation-driven chemistry by shortening particle residence times within the disk. Overall, the results indicate that thermal processing of NH3:CO2 ices is the dominant COM formation pathway in Jupiter’s CPD, whereas UV photochemistry plays only a secondary role under nominal conditions.Fig. 1. Median radial trajectories of 1 µm, 100 µm, 1 mm, and 1 cm particles as a function of time in our nominal CPD model. The particles are released one scale height above the CPD midplane at t0 = 50 kyr. Particle trajectories are computed in both the radial and vertical directions, but only their projection onto the CPD midplane is shown here for clarity. Median trajectories are shown at 10 Rjup intervals in the midplane, spanning from 5 to 135 Rjup in the CPD. Dotted lines highlight portions of these trajectories that intersect the COM formation zone via thermal processing in the CPD. The horizontal dotted-dashed line indicates the location of Rc.ConclusionsThis study shows that COMs can form efficiently within Jupiter’s CPD through thermal processing of icy particles drifting through warm disk regions. In contrast, UV-driven photochemistry is generally inefficient because particles sublimate before accumulating sufficient irradiation doses.The results suggest that the Galilean moons may have inherited part of their organic inventory directly from the CPD, although COM survival strongly depended on local thermal conditions and accretion histories. The hotter inner disk likely destroyed most organics incorporated into Io and possibly Europa, whereas the colder formation environments of Ganymede and especially Callisto favored preservation of COM-rich material.The study also highlights the need for improved laboratory photochemical data and more comprehensive chemical models, including mixed-ice chemistry and grain-surface processes.Overall, the results indicate that thermal processing within Jupiter’s CPD could have generated and preserved organics later incorporated into the Galilean moons. Future observations from JUICE and Europa Clipper will provide key constraints on the origin and survival of organics within the Jovian system. All results and interpretations are presented in [3]. References[1] Bossa, J. B., et al. 2008, A&A, 492, 719, doi: 10.1051/0004-6361:200810536[2] Tenelanda-Osorio, L. I., et al. 2022, MNRAS, 515, 5009, doi:10.1093/mnras/stac1932[3] Mousis, O., et al. 2026, PSJ, 7(2), id.41, doi:10.3847/PSJ/ae3559] 21:12:03 1822633 ERROR CrossRefSearchJob - You exceeded your current quota, please check your plan and billing details. For more information on this error, read the docs: https://platform.openai.com/docs/guides/error-codes/api-errors. 21:12:03 1822633 CrossRefSearchJob - CrossRefSearchJob with doi 10.1038/s41467-026-75190-7 21:12:03 1822633 AIClient - Request to AI with prompt: 'Given the following abstract of the publication, is it relevant to any of the following subcategories? Answer with either: yes, no or maybe. If yes or maybe, please provide also the subcategory after a semicolon. Subcategories: CO2 conversion CO conversion Chemicals used as sacrificial electron donor Host-Guest interactions in supramolecular chemistry Link Free Kredit Malaysia Terbaru 2026 Exposed No Deposit Free Credit Casino Access Photocatalytic CO2 conversion Electrochemical CO2 conversion Homogeneous photocatalytic CO2 conversion Heterogeneous photocatalytic CO2 conversion Photocatalytic CO2 conversion to CO Photocatalytic CO2 conversion to HCOOH Photocatalytic CO2 conversion to CH4 Homogeneous electrochemical CO2 conversion Heterogeneous electrochemical CO2 conversion' and documents [Author Correction: Economical biogas direct methanation to pipeline grade natural gas via structured Ni based inverse catalyst] 21:12:03 1822633 ERROR CrossRefSearchJob - You exceeded your current quota, please check your plan and billing details. For more information on this error, read the docs: https://platform.openai.com/docs/guides/error-codes/api-errors.