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Chirdon-et-al-2016-tuning-iridium-photocatalysts-and-light-irradiation-for-enhanced-co2-reduction.pdf

2025-08-29T08:58:05Z

ChemUser:

'''Imported from: /opt/uploadtmp/chirdon-et-al-2016-tuning-iridium-photocatalysts-and-light-irradiation-for-enhanced-co2-reduction_68b166caaa601.pdf'''

'''This article has not been reviewed yet'''

{{BaseTemplate}}
{{DOI|doi=10.1021/acscatal.6b03227}}

== Abstract Summary ==
The study examines a family of “all-in-one’’ Ir(III) complexes that act simultaneously as photosensitiser and catalyst for the visible-light reduction of CO₂ to CO in acetonitrile/triethanolamine (TEOA). By appending progressively bulkier aromatic groups to the 4′-position of the terpyridine (tpy) ligand and by lowering the blue-light intensity, the authors stretch the catalyst lifetime from a few hours to more than ten days and lift the turnover number (TON) from ≈90 to 265 with a quantum yield of 0.10.

== Advances and Special Progress ==
* Ligand engineering: introduction of a 9-anthryl group on tpy (complex 3) provides steric shielding and an additional triplet energy-dissipation pathway that curbs deactivation.
* Photoregulation: operating with low-power 450 nm LEDs diminishes the steady-state concentration of reactive reduced intermediates, thereby suppressing formation of an off-cycle, “green’’ degradation product.
* Record performance for this Ir(III) catalyst class: TON(CO) = 265 and continuous activity for >250 h without external photosensitisers or precious-metal co-catalysts.

== Additional Remarks ==
* Relevance: Selective CO evolution from CO₂ is a key step toward carbon-neutral synthetic fuels.
* Sustainability: The system functions in wet acetonitrile and tolerates O₂ traces, simplifying practical deployment.
* Challenge: The high cost and rarity of iridium remain obstacles; lessons on photoprotection gleaned here are transferable to earth-abundant platforms.

== Content of the Published Article in Detail ==
The complexes have the general formula
[Ir(ppy)(tpy-R)Cl]⁺
where ppy = 2-phenylpyridine and R = H (1), 4′-phenyl (2), 4′-9-anthryl (3), 4′-p-fluorophenyl (4).

1. **Photophysical & electrochemical characterisation**
* First reversible reduction at −0.84 V vs NHE is tpy-centred for all derivatives.
* Visible MLCT absorption tails to 520 nm; emission lifetimes ≈4 µs except for 3 (3.4 µs, lower Φ due to anthryl triplet quenching).
* Stern–Volmer analysis shows similar reductive-quenching rates with TEOA (k_q ~6–7 × 10⁸ M⁻¹ s⁻¹).

2. **Proposed mechanism (words)**
a. 450 nm excitation → *Ir(III)*¹* (³MLCT).
b. Reductive quenching by TEOA gives Ir(II) one-electron-reduced species (OERS).
c. Chloride or solvent dissociation opens a vacant site; CO₂ binds and is reduced to CO, regenerating Ir(III).
d. Competing dark reaction of OERS affords a long-lived “green’’ species that cannot enter the catalytic cycle; accumulation of this species deactivates the system.
e. Bulky R groups and low photon flux slow steps (c) and/or (d) that lead to deactivation.

3. **Operando UV–vis / spectroelectrochemistry**
* Growth of a 700 nm band parallels loss of activity; spectra match those formed during prolonged electrolysis of OERS, confirming an off-cycle product.
* Complex 3 accumulates this band more slowly, correlating with its longer operational life.

== Catalyst ==
* Class: Cyclometalated Ir(III) complexes bearing a bidentate ppy and tridentate tpy-R ligand.
* Function: Acts as photosensitiser, electron relay, and CO₂-reduction site in a single molecule.
* Unique properties:
- Visible absorption to 520 nm, enabling blue-LED excitation.
- Water tolerance.
- Tunable steric/electronic environment via tpy 4′-substitution; the anthryl derivative (3) displays built-in photoprotective energy-dissipation.

== Photosensitizer ==
No external photosensitiser is employed; the Ir complex itself harvests light. The MLCT excited state (³[Ir(ppy)(tpy-R)Cl]⁺*) is reductively quenched by TEOA to start the catalytic electron chain.

== Investigation ==
{| class="wikitable"
|-
! cat !! cat conc [µM] !! PS !! PS conc [mM] !! e-D !! e-D conc [M] !! solvent A !! λ_exc [nm] !! TON_CO
|-
| 1 || 500 || — (intrinsic) || 0.5 || TEOA || ≈2.7 || CH₃CN (83 %) || 450 || 91
|-
| 2 || 500 || — || 0.5 || TEOA || ≈2.7 || CH₃CN (83 %) || 450 || 144
|-
| 3 || 500 || — || 0.5 || TEOA || ≈2.7 || CH₃CN (83 %) || 450 || 172
|-
| 3 (low-light) || 500 || — || 0.5 || TEOA || ≈2.7 || CH₃CN (83 %) || 450 (0.43 mW cm⁻²) || 265
|-
|}

*All experiments used a 1 : 5 v/v TEOA/CH₃CN mixture (4 mL, CO₂-saturated, ambient T) and continuous irradiation.

[[Category:Homogeneous photocatalytic CO2 conversion]]
[[Category:Photocatalytic CO2 conversion]]
[[Category:CO2 conversion]]

Help:Create new publication

2025-02-09T14:19:02Z

ChemUser:

This page will guide you in adding a new publication, set of experiments or dataset to the wiki.

== Guidelines to style pages in this wiki ==

'''Auto generated pages according to templates (no edits possible):'''

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=== Publication pages ===
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'''Publication pages (and topic pages) are the only ones that can be freely edited! Any changes to molecules or investigations must be made on the publication page. Only exception is adding an abbreviation to a molecule, this happens on the molecule page.'''

'''How to select suitable publications/papers that are added to the Wiki?''' 
The most important point for a selection of a publication to be represented in the Wiki as a novel article is that the publication deals with the scientific content of one of the (sub)topics. Further, the publication needs to contain data to be used for filling the investigation tables. This data can be given in the manuscript or the SI but it needs to be given with the original publication. If a publication does not contain data (or insufficient data) for the required information in the investigation, the publication would be out of scope for the Wiki.

Publication pages show legally available data and information from published papers, e.g.

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II) Molecules used in the publication
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Currently, the pages are structured by the headlines:

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Each headline is formatted as sub-heading 2
The investigations are named: currently Table 1, Table 2

The appropriate molecules for 1), 2), 4), 5) are drawn under their respective title. Solvents or gas atmosphere don’t need to be drawn, as do small (inorganic) additives.

=== Molecule Drawings ===
To draw molecules in Ketcher 2: 
Bonds between ligands and metal are '''hydrogen bonds''' by default, unless this adds surplus hydrogens to the structure and those hydrogens cannot be removed by an appropriate charge. In this case, use an '''any bond'''.

Remember to add charges on the molecule, especially on metal centers in complexes with counter ions. 
Position ligands with aromatic rings correctly around the center metal atom. Try to avoid using the clean-up function, as this distorts the aromatic rings.

Molecule collections with R-groups: Add R-groups when multiple rests are mentioned in literature. Use different (R1, R2, R3…) groups for different positions on the molecule, unless two positions are always substituted with the same rest. Specify the R-groups in the Ketcher “Define R-groups” menu. 
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Small organic molecule ligands: draw individually instead of abbreviation 
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'''Drawing molecules correctly is important to generate the right identifiers (InChIKey) and find molecule information in PubChem!'''

=== Investigations ===

Columns with free text but guidelines:

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Irradiation wavelength: number, “dark” (or empty), description of source 
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Help:Create new publication

2025-02-09T14:17:16Z

ChemUser:

This page will guide you in adding a new publication, set of experiments or dataset to the wiki.

== Guidelines to style pages in this wiki ==

'''Auto generated pages according to templates (no edits possible):'''

- literature page (generated from DOI), 
- investigation (generated from investigation template input on publication page), 
- molecule page (only add abbreviation)

=== Publication pages ===
How to generate a new publication page: Authoring → Create a new Publication: enter title (default publication title, check formatting in the wiki), DOI, topic(s) it belongs to → Create publiction 
This leads to the new publication page with auto-generated infobox (About) from the DOI-generated literature page

Page titles cannot contain brackets [] or slashes /, or hashtags #. For a full list, see:
https://www.mediawiki.org/wiki/Manual:Page_title

'''Publication pages (and topic pages) are the only ones that can be freely edited! Any changes to molecules or investigations must be made on the publication page. Only exception is adding an abbreviation to a molecule, this happens on the molecule page.'''

'''How to select suitable publications/papers that are added to the Wiki?'''
The most important point for a selection of a publication to be represented in the Wiki as a novel article is that the publication deals with the scientific content of one of the (sub)topics. Further, the publication needs to contain data to be used for filling the investigation tables. This data can be given in the manuscript or the SI but it needs to be given with the original publication. If a publication does not contain data (or insufficient data) for the required information in the investigation, the publication would be out of scope for the Wiki.

Publication pages show legally available data and information from published papers, e.g.

I) The investigations: Tables with data 
II) Molecules used in the publication
III) Key findings of the original publication in brief

Currently, the pages are structured by the headlines:

1) Catalyst 
2) Photosensitizer 
3) Investigation 
4) Sacrificial electron donor 
5) Additives (optional) 

Each headline is formatted as sub-heading 2
The investigations are named: currently Table 1, Table 2

The appropriate molecules for 1), 2), 4), 5) are drawn under their respective title. Solvents or gas atmosphere don’t need to be drawn, as do small (inorganic) additives.

=== Molecule Drawings ===
To draw molecules in Ketcher 2: 
Bonds between ligands and metal are '''hydrogen bonds''' by default, unless this adds surplus hydrogens to the structure and those hydrogens cannot be removed by an appropriate charge. In this case, use an '''any bond'''.

Remember to add charges on the molecule, especially on metal centers in complexes with counter ions. 
Position ligands with aromatic rings correctly around the center metal atom. Try to avoid using the clean-up function, as this distorts the aromatic rings.

Molecule collections with R-groups: Add R-groups when multiple rests are mentioned in literature. Use different (R1, R2, R3…) groups for different positions on the molecule, unless two positions are always substituted with the same rest. Specify the R-groups in the Ketcher “Define R-groups” menu. 
R-groups can also be used for counter ions: add an unconnected R-group on the top right of the molecule drawing and specify one or multiple counter ions in the “Define R-groups” menu. 
Small organic molecule ligands: draw individually instead of abbreviation 
CO: triple bond, negative charge on C, positive charge on O
(example: https://pubchem.ncbi.nlm.nih.gov/compound/139130150)

'''Drawing molecules correctly is important to generate the right identifiers (InChIKey) and find molecule information in PubChem!'''

=== Investigations ===

Columns with free text but guidelines:

Additives: free text; gases according to list (…) 
Solvent ratio: e. g. 4:1 
Irradiation wavelength: number, “dark” (or empty), description of source 
Columns with numbers: Leave empty when number is not given or zero

=== Comment banner ===

Several comment banners can be found under “Templates”
[[Test MissingTemplates|MissingTemplates]]
[[Test MissingItems|MissingItems]]

Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Cyclic voltammetry in various conditions

2025-01-05T19:57:42Z

ChemUser:

{{Cyclic Voltammetry experiments
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|redox potential=-2.0 , -1.4 ;
|solv=Molecule:100530
|electrolyte=Molecule:100966
|el conc=0.1
|scan rate=100
|gas=Argon
|WE=glassy carbon
|WE area=7.07
|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
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}}{{Cyclic Voltammetry
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}}{{Cyclic Voltammetry
|anl=Molecule:100784
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|solv=Molecule:100530
|electrolyte=Molecule:100966
|el conc=0.1
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|gas=CO
|cond=TEA (0.05 mM), irr. >420 nm, 1 min
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}}{{Cyclic Voltammetry
|anl=Molecule:100784
|anl conc=0.5
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}}
The results show an increase in current when the solution is irradiated and triethylamine (TEA) is added (see condition column).

Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Cyclic voltammetry in various conditions

2025-01-05T19:56:36Z

ChemUser:

{{Cyclic Voltammetry experiments
|experiments={{Cyclic Voltammetry
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|anl conc=0.5
|redox potential=-2.0 , -1.4 ;
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|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100784
|anl conc=0.5
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|electrolyte=Molecule:100966
|el conc=0.1
|scan rate=100
|gas=CO
|cond=dark
|WE=glassy carbon
|WE area=7.07
|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100784
|anl conc=0.5
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|solv=Molecule:100530
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}}{{Cyclic Voltammetry
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|el conc=0.1
|scan rate=100
|gas=CO
|cond=TEA (0.05 mM), irr. >420 nm, 1 min
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|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100784
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|cond=TEA (0.05 mM), irr. >420 nm, 60 min
|WE=glassy carbon
|WE area=7.07
|CE=platinum
|RE=SCE
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}}
The results show an increase in current when the solution is irradiated and triethylamine (TEA) is added (see condition column).

Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Cyclic voltammetry in various conditions

2025-01-05T19:49:35Z

ChemUser:

{{Cyclic Voltammetry experiments
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|anl conc=0.5
|redox potential=-2.0 , -1.4 ; -1.3
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|WE area=7.07
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}}{{Cyclic Voltammetry
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|gas=CO
|cond=dark
|WE=glassy carbon
|WE area=7.07
|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100784
|anl conc=0.5
|redox potential=-2.0, -1.4 ;
|solv=Molecule:100530
|electrolyte=Molecule:100966
|el conc=0.1
|scan rate=100
|gas=CO
|cond=irr. >420, 60 min
|WE=glassy carbon
|WE area=7.07
|CE=platinum
|RE=SCE
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100784
|anl conc=0.5
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|solv=Molecule:100530
|electrolyte=Molecule:100966
|el conc=0.1
|scan rate=100
|gas=CO
|cond=TEA (0.05 mM), irr. >420 nm, 1 min
|WE=glassy carbon
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}}
The results show an increase in current when the solution is irradiated and triethylamine (TEA) is added (see condition column).

Category:Chemicals used as sacrificial electron donor

2025-01-04T18:44:26Z

ChemUser: /* General considerations */

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== General considerations ===
Sacrificial electron donors (SDs) are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used, those and their properties will be described in brief in the following sections. The information summarized on this page is gained from different articles published in the literature, e.g. the review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}.

The most often occurring artificial photosystems are the so-called three-component-systems (TCS). SDs play a major role in particular in reductive TCS which consist of (1) a photosensitizer, (2) the SD, and (3) the catalyst. A TCS usually works as follows:

=== Summarized properties of known sacrificial electron donors ===

=== Structures of known sacrificial electron donors ===
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=150|height=100}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:57:22Z

ChemUser: /* Structures of known sacrificial electron donors */

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== General considerations ===
Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used

=== Summarized properties of known sacrificial electron donors ===

=== Structures of known sacrificial electron donors ===
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=150|height=100}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:55:05Z

ChemUser: /* Structures of known sacrificial electron donors */

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== General considerations ===
Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used

=== Summarized properties of known sacrificial electron donors ===

=== Structures of known sacrificial electron donors ===
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=225|height=150}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:49:33Z

ChemUser: /* Structures of known sacrificial electron donors */

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== General considerations ===
Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used

=== Summarized properties of known sacrificial electron donors ===

=== Structures of known sacrificial electron donors ===
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=150|height=100}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=225|height=150}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="150px" width="225px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:43:05Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== General considerations ===
Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used

=== Properties of known sacrificial electron donors ===

=== Structures of known sacrificial electron donors ===
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:38:44Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:38:10Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

The information summarized on this page is gained from a review on Sacrificial Electron Donor Reagents for solar fuel production {{#literature:|doi=https://dx.doi.org/10.1016/j.crci.2015.11.026}}
For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
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Category:Chemicals used as sacrificial electron donor

2024-12-30T15:35:11Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" float="none" width="200" height="200">
-INDIGO-12302416322D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>

For further literature referring to BNAH see {{#literature:|doi=https://doi.org/10.1021/ja00236a003}}
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:32:13Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C(C)(C)1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="ORTPBQVWJKLWCB-UHFFFAOYSA-N" inchi="1S/C15H18N2O/c1-15(2)8-9-17(11-13(15)14(16)18)10-12-6-4-3-5-7-12/h3-9,11H,10H2,1-2H3,(H2,16,18)" float="none" width="200" height="200">
-INDIGO-12302416222D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 18 19 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 17 C -1.73205 2.0 0.0 0
M V30 18 C -2.69798 0.741181 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 18 1 1 17
M V30 19 1 1 18
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1C" inchi="1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3" inchikey="GYVGXEWAOAAJEU-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416242D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 10 10 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 10 C 6.65225 -3.84997 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 10 1 3 10
M V30 END BOND
M V30 END CTAB
M END
</chemform>
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:23:15Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C(C)(C)1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchikey="ORTPBQVWJKLWCB-UHFFFAOYSA-N" inchi="1S/C15H18N2O/c1-15(2)8-9-17(11-13(15)14(16)18)10-12-6-4-3-5-7-12/h3-9,11H,10H2,1-2H3,(H2,16,18)" float="none" width="200" height="200">
-INDIGO-12302416222D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 18 19 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 17 C -1.73205 2.0 0.0 0
M V30 18 C -2.69798 0.741181 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 18 1 1 17
M V30 19 1 1 18
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C=C(N(C)C)C=CC=1" inchi="1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3" inchikey="JLTDJTHDQAWBAV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302416232D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.78485 -5.35007 0.0 0
M V30 2 C 7.51515 -5.34959 0.0 0
M V30 3 C 6.65164 -4.84997 0.0 0
M V30 4 C 7.51515 -6.35053 0.0 0
M V30 5 C 5.78485 -6.35502 0.0 0
M V30 6 C 6.65382 -6.85003 0.0 0
M V30 7 N 6.65768 -7.85003 0.0 0
M V30 8 C 5.79359 -8.35336 0.0 0
M V30 9 C 7.52563 -8.34668 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 1 6 7
M V30 8 1 7 8
M V30 9 1 7 9
M V30 END BOND
M V30 END CTAB
M END
</chemform>
[[Category:Publication]]
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[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:19:23Z

ChemUser:

Category:Chemicals used as sacrificial electron donor

2024-12-30T15:16:55Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacrificial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used:

{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true|width=300|height=200}} {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true|width=300|height=200}} <chemform smiles="N1C=CC(N(C)C)=CC=1" inchi="1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3" inchikey="VHYFNPMBLIVWCW-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410412D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 9 9 0 0 0
M V30 BEGIN ATOM
M V30 1 N -2.0 0.0 0.0 0
M V30 2 C -1.5 0.866025 0.0 0
M V30 3 C -0.5 0.866025 0.0 0
M V30 4 C 0.0 0.0 0.0 0
M V30 5 N 1.0 0.0 0.0 0
M V30 6 C 1.5 -0.866026 0.0 0
M V30 7 C 1.5 0.866025 0.0 0
M V30 8 C -0.5 -0.866025 0.0 0
M V30 9 C -1.5 -0.866025 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 5 7
M V30 7 1 4 8
M V30 8 2 8 9
M V30 9 1 9 1
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="OC(CN(CC(=O)O)CCN(CC(=O)O)CC(=O)O)=O" inchi="1S/C10H16N2O8/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)20/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20)" inchikey="KCXVZYZYPLLWCC-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410432D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 20 19 0 0 0
M V30 BEGIN ATOM
M V30 1 O 0.0 -2 0.0 0
M V30 2 C 0.866025 -1.5 0.0 0
M V30 3 O 1.73205 -2.0 0.0 0
M V30 4 C 0.866025 -0.5 0.0 0
M V30 5 N 0.0 0.0 0.0 0
M V30 6 C -0.866025 -0.5 0.0 0
M V30 7 C -1.73205 0.0 0.0 0
M V30 8 N -2.59808 -0.5 0.0 0
M V30 9 C -2.59808 -1.5 0.0 0
M V30 10 C -3.4641 -2.0 0.0 0
M V30 11 O -4.33013 -1.5 0.0 0
M V30 12 O -3.4641 -3.0 0.0 0
M V30 13 C -3.4641 0.0 0.0 0
M V30 14 C -3.4641 1.0 0.0 0
M V30 15 O -2.59808 1.5 0.0 0
M V30 16 O -4.33013 1.5 0.0 0
M V30 17 C 0.0 1.0 0.0 0
M V30 18 C 0.866026 1.5 0.0 0
M V30 19 O 1.73205 1 0.0 0
M V30 20 O 0.866026 2.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 2 4
M V30 4 1 4 5
M V30 5 1 5 6
M V30 6 1 6 7
M V30 7 1 7 8
M V30 8 1 8 9
M V30 9 1 9 10
M V30 10 1 10 11
M V30 11 2 10 12
M V30 12 1 8 13
M V30 13 1 13 14
M V30 14 1 14 15
M V30 15 2 14 16
M V30 16 1 5 17
M V30 17 1 17 18
M V30 18 1 18 19
M V30 19 2 18 20
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C1C(C(N)=O)=CN(CC2C=CC=CC=2)C=C1" inchi="1S/C13H14N2O/c14-13(16)12-7-4-8-15(10-12)9-11-5-2-1-3-6-11/h1-6,8,10H,7,9H2,(H2,14,16)" inchikey="CMNUYDSETOTBDE-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12302410452D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 16 17 0 0 0
M V30 BEGIN ATOM
M V30 1 C -1.73205 1.0 0.0 0
M V30 2 C -0.866026 1.5 0.0 0
M V30 3 C 0.0 1.0 0.0 0
M V30 4 N 0.0 0.0 0.0 0
M V30 5 C -0.866025 -0.5 0.0 0
M V30 6 C -1.73205 0.0 0.0 0
M V30 7 C -2.59808 -0.5 0.0 0
M V30 8 O -2.59808 -1.5 0.0 0
M V30 9 N -3.4641 0.0 0.0 0
M V30 10 C 0.866026 -0.5 0.0 0
M V30 11 C 1.73205 0.0 0.0 0
M V30 12 C 1.73205 1.0 0.0 0
M V30 13 C 2.59808 1.5 0.0 0
M V30 14 C 3.4641 1.0 0.0 0
M V30 15 C 3.4641 0.0 0.0 0
M V30 16 C 2.59808 -0.5 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 1 1 2
M V30 2 2 2 3
M V30 3 1 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 2 7 8
M V30 9 1 7 9
M V30 10 1 4 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 13
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 11
M V30 END BOND
M V30 END CTAB
M END
</chemform>
[[Category:Publication]]
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Category:Chemicals used as sacrificial electron donor

2024-12-30T09:41:51Z

ChemUser:

Category:Chemicals used as sacrificial electron donor

2024-12-30T09:38:15Z

ChemUser:

Category:Chemicals used as sacrificial electron donor

2024-12-30T09:30:17Z

ChemUser:

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}Sacri
[[Category:Publication]]
ficial electron donors are an important component of artificial systems that mimic photochemical conversions of CO2 and others. In most of the currently known systems a few sacrificial electron donors are used.
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]
[[Category:Publication]]

Category:Chemicals used as sacrificial electron donor

2024-12-30T09:26:23Z

ChemUser: auto-generated

{{DOI|doi=}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

2024-12-16T16:51:41Z

ChemUser: /* Investigation */

{{BaseTemplate}}
{{DOI|doi=10.1021/jacs.9b00937 }}

===Abstract===
====Summary ====
A photochemical reduction of CO2 and CO to methane was shown using the nickel carbene complexes {{#moleculelink: |link=QDSMZTKUFVYRKR-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink:|link=NWZXUODUJQGAHV-UHFFFAOYSA-N|image=false|width=300|height=200}}, and {{#moleculelink:|link=BQELNTZVSDPWHI-UHFFFAOYSA-N|image=false|width=300|height=200}} as catalysts in combination with the iridium-based photosensitizer {{#moleculelink: |link=NSABRUJKERBGOU-UHFFFAOYSA-N|image=false|width=300|height=200}}. Turnover numbers (TONs) up to 310000 for CO and 19000 for CH4 and selectivities of 90% for CO2 reduction products were reached for complex {{#moleculelink:|link=BQELNTZVSDPWHI-UHFFFAOYSA-N|image=false|width=300|height=200}} in acetonitrile. The experiments were conducted under visible-light irradiation using BIH as sacrificial electron donor (see section SEDs below).
====Advances and special progress====
An exceptionally high TON of 570000 for the conversion of CO to CH4 as well as a TON of 19000 for the conversion of CO2 to CH4 could be observed using an earth-abundant metal complex as a catalyst.

====Additional remarks====
The macrocyclic nickel carbene complex {{#moleculelink:|link=NWZXUODUJQGAHV-UHFFFAOYSA-N|image=false|width=300|height=200}} gave a higher carbon-selective reduction percentage than the related complexes {{#moleculelink:|link=BQELNTZVSDPWHI-UHFFFAOYSA-N|image=false|width=300|height=200}} and {{#moleculelink: |link=QDSMZTKUFVYRKR-UHFFFAOYSA-N|image=false|width=300|height=200}}. The conversion of CO2 to CO and methane as well as the conversion of a CO/H2 atmosphere to methane were investigated with complex {{#moleculelink:|link=NWZXUODUJQGAHV-UHFFFAOYSA-N|image=false|width=300|height=200}}.

===Content of the published article in detail===
The article contains results for the reduction of CO2 to CO and CH4 and CO to CH4 under visible-light catalysis using a nickel complex as a catalyst. The catalytic system performs best (referring to the TON of CH4 production) in acetonitrile with a 1:1 CO/H2 atmosphere.

=== Catalysts tested in this study ===
<chemform smiles="C1C=CC2CN3C=CN4CN5C6[Ni+2](C34)3N=2C=1C1N3=C(CN6C=C5)C=CC=1.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F" inchikey="QDSMZTKUFVYRKR-UHFFFAOYSA-N" inchi="1S/C19H20N6.2F6P.Ni/c1-3-16-11-22-7-9-24(13-22)15-25-10-8-23(14-25)12-17-4-2-6-19(21-17)18(5-1)20-16;2*1-7(2,3,4,5)6;/h1-10H,11-15H2;;;/q;2*-1;+2" float="none" width="200" height="200">
-INDIGO-02142409402D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 40 45 0 0 0
M V30 BEGIN ATOM
M V30 1 C 4.20985 -7.22507 0.0 0
M V30 2 N 5.94015 -7.22459 0.0 0
M V30 3 C 5.07664 -6.72497 0.0 0
M V30 4 C 5.94015 -8.22553 0.0 0
M V30 5 C 4.20985 -8.23002 0.0 0
M V30 6 C 5.07882 -8.72503 0.0 0
M V30 7 C 4.15985 -4.10007 0.0 0
M V30 8 C 5.89015 -4.09959 0.0 0
M V30 9 C 5.02664 -3.59997 0.0 0
M V30 10 N 5.89015 -5.10053 0.0 0
M V30 11 C 4.15985 -5.10502 0.0 0
M V30 12 C 5.02882 -5.60003 0.0 0
M V30 13 C 6.80666 -8.7247 0.0 0
M V30 14 N 7.6722 -8.22387 0.0 0
M V30 15 C 6.75641 -3.59999 0.0 0
M V30 16 N 7.6222 -4.1004 0.0 0
M V30 17 C 7.77675 -7.22936 0.0 0
M V30 18 N 8.75491 -7.02142 0.0 0
M V30 19 C 9.25491 -7.88743 0.0 0
M V30 20 C 8.58574 -8.63058 0.0 0
M V30 21 C 8.53574 -3.69369 0.0 0
M V30 22 C 9.20491 -4.43683 0.0 0
M V30 23 N 8.70491 -5.30284 0.0 0
M V30 24 C 7.72675 -5.0949 0.0 0
M V30 25 C 9.20491 -6.16887 0.0 0
M V30 26 Ni 6.975 -6.1 0.0 0 CHG=2
M V30 27 F 10.392 -5.325 0.0 0
M V30 28 P 11.258 -4.825 0.0 0 CHG=-1
M V30 29 F 12.124 -5.325 0.0 0
M V30 30 F 11.258 -3.825 0.0 0
M V30 31 F 10.392 -4.325 0.0 0
M V30 32 F 12.124 -4.325 0.0 0
M V30 33 F 11.258 -5.825 0.0 0
M V30 34 F 10.409 -8.275 0.0 0
M V30 35 P 11.275 -7.775 0.0 0 CHG=-1
M V30 36 F 12.141 -8.275 0.0 0
M V30 37 F 11.275 -6.775 0.0 0
M V30 38 F 10.409 -7.275 0.0 0
M V30 39 F 12.141 -7.275 0.0 0
M V30 40 F 11.275 -8.775 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 2 9 7
M V30 8 2 10 8
M V30 9 1 7 11
M V30 10 1 8 9
M V30 11 2 11 12
M V30 12 1 12 10
M V30 13 1 12 3
M V30 14 1 4 13
M V30 15 1 13 14
M V30 16 1 8 15
M V30 17 1 15 16
M V30 18 1 14 17
M V30 19 1 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 14
M V30 23 1 16 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 1 23 24
M V30 27 1 24 16
M V30 28 1 23 25
M V30 29 1 25 18
M V30 30 10 10 26
M V30 31 10 2 26
M V30 32 10 17 26
M V30 33 10 24 26
M V30 34 1 27 28
M V30 35 1 28 29
M V30 36 1 28 30
M V30 37 1 28 31
M V30 38 1 28 32
M V30 39 1 28 33
M V30 40 1 34 35
M V30 41 1 35 36
M V30 42 1 35 37
M V30 43 1 35 38
M V30 44 1 35 39
M V30 45 1 35 40
M V30 END BOND
M V30 END CTAB
M END
</chemform> <chemform smiles="C12CN3C=CN(C)C3[Ni+2]34N5C(C(C=CC=1)=N23)=CC=CC=5CN1C4N(C)C=C1.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F" inchi="1S/C20H24N6.2F6P.Ni/c1-23-9-11-25(15-23)13-17-5-3-7-19(21-17)20-8-4-6-18(22-20)14-26-12-10-24(2)16-26;2*1-7(2,3,4,5)6;/h3-12H,13-16H2,1-2H3;;;/q;2*-1;+2" inchikey="NWZXUODUJQGAHV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-11282315202D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 41 45 0 0 0
M V30 BEGIN ATOM
M V30 1 C 5.64015 -6.64993 0.0 0
M V30 2 C 3.90985 -6.65041 0.0 0
M V30 3 C 4.77336 -7.15003 0.0 0
M V30 4 C 3.90985 -5.64947 0.0 0
M V30 5 N 5.64015 -5.64498 0.0 0
M V30 6 C 4.77118 -5.14997 0.0 0
M V30 7 C 3.88485 -2.67507 0.0 0
M V30 8 C 5.61515 -2.67459 0.0 0
M V30 9 C 4.75164 -2.17497 0.0 0
M V30 10 N 5.61515 -3.67553 0.0 0
M V30 11 C 3.88485 -3.68002 0.0 0
M V30 12 C 4.75382 -4.17503 0.0 0
M V30 13 C 6.48118 -2.17459 0.0 0
M V30 14 N 7.3472 -2.67459 0.0 0
M V30 15 C 6.50618 -7.14993 0.0 0
M V30 16 N 7.3722 -6.64993 0.0 0
M V30 17 C 7.47675 -5.65542 0.0 0
M V30 18 N 8.45492 -5.44748 0.0 0
M V30 19 C 8.95491 -6.31349 0.0 0
M V30 20 C 8.28574 -7.05663 0.0 0
M V30 21 C 8.26074 -2.26788 0.0 0
M V30 22 C 8.92991 -3.01102 0.0 0
M V30 23 N 8.42991 -3.87704 0.0 0
M V30 24 C 7.45175 -3.66909 0.0 0
M V30 25 C 9.06164 -4.21559 0.0 0
M V30 26 C 9.03664 -5.08393 0.0 0
M V30 27 Ni 6.525 -4.65 0.0 0 CHG=2
M V30 28 F 10.6948 -3.25 0.0 0
M V30 29 P 11.5608 -2.75 0.0 0 CHG=-1
M V30 30 F 12.4268 -3.25 0.0 0
M V30 31 F 11.5608 -1.75 0.0 0
M V30 32 F 10.6948 -2.25 0.0 0
M V30 33 F 12.4268 -2.25 0.0 0
M V30 34 F 11.5608 -3.75 0.0 0
M V30 35 F 10.6895 -6.83333 0.0 0
M V30 36 P 11.5556 -6.33333 0.0 0 CHG=-1
M V30 37 F 12.4216 -6.83333 0.0 0
M V30 38 F 11.5556 -5.33333 0.0 0
M V30 39 F 10.6895 -5.83333 0.0 0
M V30 40 F 12.4216 -5.83333 0.0 0
M V30 41 F 11.5556 -7.33333 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 2 9 7
M V30 8 2 10 8
M V30 9 1 7 11
M V30 10 1 8 9
M V30 11 2 11 12
M V30 12 1 12 10
M V30 13 1 12 6
M V30 14 1 8 13
M V30 15 1 13 14
M V30 16 1 1 15
M V30 17 1 15 16
M V30 18 1 16 17
M V30 19 1 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 16
M V30 23 1 14 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 1 23 24
M V30 27 1 24 14
M V30 28 1 23 25
M V30 29 1 18 26
M V30 30 10 5 27
M V30 31 10 17 27
M V30 32 10 24 27
M V30 33 10 10 27
M V30 34 1 28 29
M V30 35 1 29 30
M V30 36 1 29 31
M V30 37 1 29 32
M V30 38 1 29 33
M V30 39 1 29 34
M V30 40 1 35 36
M V30 41 1 36 37
M V30 42 1 36 38
M V30 43 1 36 39
M V30 44 1 36 40
M V30 45 1 36 41
M V30 END BOND
M V30 END CTAB
M END
</chemform><chemform smiles="C1C=C2C3N4[Ni+2]56C7N(C=CN7CCN7C=CN(C75)CC=4C=CC=3)CC(C=1)=N26.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F" inchi="1S/C20H22N6.2F6P.Ni/c1-3-17-13-25-11-9-23(15-25)7-8-24-10-12-26(16-24)14-18-4-2-6-20(22-18)19(5-1)21-17;2*1-7(2,3,4,5)6;/h1-6,9-12H,7-8,13-16H2;;;/q;2*-1;+2" inchikey="BQELNTZVSDPWHI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-11282315202D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 41 46 0 0 0
M V30 BEGIN ATOM
M V30 1 C 3.85985 -2.82507 0.0 0
M V30 2 C 5.59015 -2.82459 0.0 0
M V30 3 C 4.72664 -2.32497 0.0 0
M V30 4 N 5.59015 -3.82553 0.0 0
M V30 5 C 3.85985 -3.83002 0.0 0
M V30 6 C 4.72882 -4.32503 0.0 0
M V30 7 C 3.90985 -5.97507 0.0 0
M V30 8 N 5.64015 -5.97459 0.0 0
M V30 9 C 4.77664 -5.47497 0.0 0
M V30 10 C 5.64015 -6.97553 0.0 0
M V30 11 C 3.90985 -6.98002 0.0 0
M V30 12 C 4.77882 -7.47503 0.0 0
M V30 13 C 6.45641 -2.32499 0.0 0
M V30 14 N 7.3222 -2.8254 0.0 0
M V30 15 C 6.50666 -7.4747 0.0 0
M V30 16 N 7.3722 -6.97387 0.0 0
M V30 17 C 7.47675 -5.97936 0.0 0
M V30 18 N 8.45491 -5.77142 0.0 0
M V30 19 C 8.95491 -6.63743 0.0 0
M V30 20 C 8.28574 -7.38058 0.0 0
M V30 21 C 8.23574 -2.41869 0.0 0
M V30 22 C 8.90491 -3.16183 0.0 0
M V30 23 N 8.40491 -4.02784 0.0 0
M V30 24 C 7.42675 -3.8199 0.0 0
M V30 25 C 8.98702 -4.48495 0.0 0
M V30 26 C 9.01202 -5.21431 0.0 0
M V30 27 Ni 6.55 -4.875 0.0 0 CHG=2
M V30 28 F 10.542 -3.975 0.0 0
M V30 29 P 11.408 -3.475 0.0 0 CHG=-1
M V30 30 F 12.274 -3.975 0.0 0
M V30 31 F 11.408 -2.475 0.0 0
M V30 32 F 10.542 -2.975 0.0 0
M V30 33 F 12.274 -2.975 0.0 0
M V30 34 F 11.408 -4.475 0.0 0
M V30 35 F 10.534 -6.975 0.0 0
M V30 36 P 11.4 -6.475 0.0 0 CHG=-1
M V30 37 F 12.266 -6.975 0.0 0
M V30 38 F 11.4 -5.475 0.0 0
M V30 39 F 10.534 -5.975 0.0 0
M V30 40 F 12.266 -5.975 0.0 0
M V30 41 F 11.4 -7.475 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 3 1
M V30 2 2 4 2
M V30 3 1 1 5
M V30 4 1 2 3
M V30 5 2 5 6
M V30 6 1 6 4
M V30 7 2 9 7
M V30 8 2 10 8
M V30 9 1 7 11
M V30 10 1 8 9
M V30 11 2 11 12
M V30 12 1 12 10
M V30 13 1 6 9
M V30 14 1 2 13
M V30 15 1 13 14
M V30 16 1 10 15
M V30 17 1 15 16
M V30 18 1 16 17
M V30 19 1 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 16
M V30 23 1 14 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 1 23 24
M V30 27 1 24 14
M V30 28 1 23 25
M V30 29 1 18 26
M V30 30 1 26 25
M V30 31 10 4 27
M V30 32 10 8 27
M V30 33 10 17 27
M V30 34 10 24 27
M V30 35 1 28 29
M V30 36 1 29 30
M V30 37 1 29 31
M V30 38 1 29 32
M V30 39 1 29 33
M V30 40 1 29 34
M V30 41 1 35 36
M V30 42 1 36 37
M V30 43 1 36 38
M V30 44 1 36 39
M V30 45 1 36 40
M V30 46 1 36 41
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===
{{#moleculelink: |link=NSABRUJKERBGOU-UHFFFAOYSA-N|image=true}}

=== Investigation===
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Results for different electron donors and proton donors|importFile=Durable_Solar-Powered_Systems_with_Ni-Catalysts_for_Conversion_of_CO2_or_CO_to_CH4_20241216_174210.xlsx|description=}}

===Further Information===
The Supporting Information gives quantum yields for described experiments in Table 1.
====Sacrificial electron donor ====
In this study, the experiments were done with the sacrificial electron donor BIH ([[Molecule:100508|100508]]).
==== Additives ====
In this study, triethylamine ({{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}) and water ({{#moleculelink:|link=XLYOFNOQVPJJNP-UHFFFAOYSA-N|image=false|width=300|height=200}}) were used as additives.
[[Category:Photocatalytic CO2 conversion to CH4]][[Category:Publication]]

Efficient Visible-Light-Driven Carbon Dioxide Reduction using a Bioinspired Nickel Molecular Catalyst

2024-12-16T16:50:49Z

ChemUser:

{{DOI|doi=10.1002/cssc.202301892}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== Abstract ===
The study introduces a bioinspired nickel-based molecular catalyst, [Ni(N2S2)]Cl2 (NiN2S2), for photochemical catalytic reduction of CO2 under visible light. Combining the catalyst with [Ru(bpy)3]Cl2 as a photosensitizer and BIH as a sacrificial electron donor, the system achieved an 89% selectivity towards CO, with a turnover number (TON) of 7991 during 8 hours of irradiation. The process demonstrated high catalytic efficiency with a turnover frequency (TOF) of 1079 h⁻¹ and an apparent quantum yield (AQY) of 1.08%.

==== Summary ====
Inspired by natural enzymes, this work focuses on the development of a novel nickel catalyst for CO2 photoreduction. NiN2S2, designed with thiol and pyridine ligands, exhibited remarkable activity and selectivity in converting CO2 to CO. Control experiments confirmed the necessity of light, the catalyst, and sacrificial electron donors. Acidic co-substrates such as phenol further enhanced the reaction's efficiency without compromising selectivity. This study establishes NiN2S2 as a promising candidate for sustainable CO2 reduction under visible light.

==== Additional remarks ====

* The combination of sulfur and nitrogen ligands in NiN2S2 enhances its stability and catalytic efficiency.
* Acid additives, particularly phenol, significantly improve reaction rates, indicating a key role in CO2 stabilization and protonation steps.
* Further research is proposed to optimize ligand coordination and investigate intermediate reaction mechanisms.

=== Content of the published article in detail ===

* The synthesis and characterization of NiN2S2 using advanced analytical techniques like LC-HRMS and X-ray crystallography.
* The photocatalytic performance of NiN2S2 in reducing CO2 to CO under visible light, achieving high selectivity and efficiency.
* Mechanistic insights into the electron transfer process facilitated by the catalyst and photosensitizer.

=== Catalysts tested in this study ===
<chemform smiles="C1C2CS3[Ni](Cl)(Cl)45S(CC6N4=C(C3)C=CC=6)CC(N=25)=CC=1" inchi="1S/C14H14N2S2.2ClH.Ni/c1-3-11-7-17-9-13-5-2-6-14(16-13)10-18-8-12(4-1)15-11;;;/h1-6H,7-10H2;2*1H;/q;;;+2/p-2" inchikey="XRUWRFIGSFNAGZ-UHFFFAOYSA-L" height="100px" width="150px" float="none">
-INDIGO-12122410452D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 21 26 0 0 0
M V30 BEGIN ATOM
M V30 1 C -2.07786 -0.497932 0.0 0
M V30 2 C -2.07786 -1.32293 0.0 0
M V30 3 C -1.36339 -1.73543 0.0 0
M V30 4 C -0.648917 -1.32293 0.0 0
M V30 5 N -0.648917 -0.497932 0.0 0
M V30 6 C -1.36339 -0.085432 0.0 0
M V30 7 C -1.36339 0.739568 0.0 0
M V30 8 C 0.065554 -1.73543 0.0 0
M V30 9 S -0.648917 1.15207 0.0 0
M V30 10 S 0.780025 -1.32293 0.0 0
M V30 11 C 1.36339 -0.739568 0.0 0
M V30 12 C 1.36339 0.085432 0.0 0
M V30 13 C 2.07786 0.497932 0.0 0
M V30 14 C 2.07786 1.32293 0.0 0
M V30 15 C 1.36339 1.73543 0.0 0
M V30 16 C 0.648917 1.32293 0.0 0
M V30 17 N 0.648917 0.497932 0.0 0
M V30 18 C 0.065554 1.56457 0.0 0
M V30 19 Ni 0.072112 -0.019432 0.0 0
M V30 20 Cl -0.752888 0.327068 0.0 0
M V30 21 Cl 0.897112 -0.316431 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 1 4 8
M V30 9 1 7 9
M V30 10 1 8 10
M V30 11 1 10 11
M V30 12 1 11 12
M V30 13 2 12 13
M V30 14 1 13 14
M V30 15 2 14 15
M V30 16 1 15 16
M V30 17 2 16 17
M V30 18 1 17 12
M V30 19 1 9 18
M V30 20 1 18 16
M V30 21 10 5 19
M V30 22 10 17 19
M V30 23 10 9 19
M V30 24 10 19 10
M V30 25 1 20 19
M V30 26 1 19 21
M V30 END BOND
M V30 END CTAB
M END
</chemform>

([Ni(N2S2)]Cl2): A bioinspired nickel molecular catalyst.

=== Photosensitizer ===
<chemform smiles="N12[Ru](Cl)(Cl)3(N4C=CC=CC=4C4C=CC=CN=43)(N3C=CC=CC=3C=1C=CC=C2)1N2C=CC=CC=2C2C=CC=CN=21" inchi="1S/3C10H8N2.2ClH.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2" inchikey="SJFYGUKHUNLZTK-UHFFFAOYSA-L" height="200px" width="300px" float="none">
-INDIGO-12122410462D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 39 47 0 0 0
M V30 BEGIN ATOM
M V30 1 N 1.30208 0.731914 0.0 0
M V30 2 C 2.02503 0.334465 0.0 0
M V30 3 C 2.73071 0.761834 0.0 0
M V30 4 C 2.71343 1.58665 0.0 0
M V30 5 C 1.99048 1.9841 0.0 0
M V30 6 C 1.28481 1.55673 0.0 0
M V30 7 C 2.04231 -0.490355 0.0 0
M V30 8 N 1.33663 -0.917725 0.0 0
M V30 9 C 1.3539 -1.74254 0.0 0
M V30 10 C 2.07685 -2.13999 0.0 0
M V30 11 C 2.78253 -1.71262 0.0 0
M V30 12 C 2.76526 -0.887804 0.0 0
M V30 13 N 0.125472 -1.63593 0.0 0
M V30 14 C -0.558829 -2.09676 0.0 0
M V30 15 C -0.501895 -2.91979 0.0 0
M V30 16 C 0.23934 -3.282 0.0 0
M V30 17 C 0.92364 -2.82118 0.0 0
M V30 18 C 0.866706 -1.99814 0.0 0
M V30 19 C -1.30006 -1.73454 0.0 0
M V30 20 N -1.357 -0.911512 0.0 0
M V30 21 C -2.09823 -0.549301 0.0 0
M V30 22 C -2.78253 -1.01012 0.0 0
M V30 23 C -2.7256 -1.83316 0.0 0
M V30 24 C -1.98436 -2.19537 0.0 0
M V30 25 N -1.22265 0.708208 0.0 0
M V30 26 C -1.28359 1.53095 0.0 0
M V30 27 C -2.02658 1.88955 0.0 0
M V30 28 C -2.70863 1.4254 0.0 0
M V30 29 C -2.64769 0.602657 0.0 0
M V30 30 C -1.9047 0.24406 0.0 0
M V30 31 C -0.601539 1.9951 0.0 0
M V30 32 N 0.14145 1.63651 0.0 0
M V30 33 C 0.8235 2.10066 0.0 0
M V30 34 C 0.762559 2.9234 0.0 0
M V30 35 C 0.01957 3.282 0.0 0
M V30 36 C -0.662479 2.81785 0.0 0
M V30 37 Ru 0.028919 -0.177739 0.0 0
M V30 38 Cl 1.08492 -0.111739 0.0 0
M V30 39 Cl -0.961081 -0.210738 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 2 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 7
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 17
M V30 18 2 17 18
M V30 19 1 18 13
M V30 20 1 14 19
M V30 21 2 19 20
M V30 22 1 20 21
M V30 23 2 21 22
M V30 24 1 22 23
M V30 25 2 23 24
M V30 26 1 24 19
M V30 27 2 25 26
M V30 28 1 26 27
M V30 29 2 27 28
M V30 30 1 28 29
M V30 31 2 29 30
M V30 32 1 30 25
M V30 33 1 26 31
M V30 34 2 31 32
M V30 35 1 32 33
M V30 36 2 33 34
M V30 37 1 34 35
M V30 38 2 35 36
M V30 39 1 36 31
M V30 40 1 37 25 CFG=3
M V30 41 1 32 37
M V30 42 1 37 20 CFG=1
M V30 43 1 37 8 CFG=1
M V30 44 1 37 13
M V30 45 1 37 1 CFG=3
M V30 46 1 39 37
M V30 47 1 37 38
M V30 END BOND
M V30 END CTAB
M END
</chemform><chemform smiles="C1C=C2P(~[Cu+](~P(C3C=CC=CC=3)(C3C=CC=CC=3)C3C4OC2=C(C(C)(C)C=4C=CC=3)C=1)1~N2=C(C)C=C(C3C=CC=CC=3)C3C=CC4C(C5C=CC=CC=5)=CC(C)=N~1C=4C=32)(C1C=CC=CC=1)C1C=CC=CC=1.[P-](F)(F)(F)(F)(F)F" inchikey="CSSGIEBQRQRBLV-UHFFFAOYSA-P" inchi="1S/C39H32OP2.C26H20N2.Cu.F6P/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17;;1-7(2,3,4,5)6/h3-28H,1-2H3;3-16H,1-2H3;;/q;;2*-1/p+2" float="none" width="200" height="200">
-INDIGO-12162417082D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 78 90 0 0 0
M V30 BEGIN ATOM
M V30 1 C -3.79376 2.14341 0.0 0
M V30 2 C -4.20626 1.42894 0.0 0
M V30 3 C -3.79376 0.714471 0.0 0
M V30 4 C -2.96876 0.714471 0.0 0
M V30 5 C -2.55626 1.42894 0.0 0
M V30 6 C -2.96876 2.14341 0.0 0
M V30 7 C -4.20626 0.0 0.0 0
M V30 8 C -3.79376 -0.714471 0.0 0
M V30 9 C -2.96876 -0.714471 0.0 0
M V30 10 O -2.55626 0.0 0.0 0
M V30 11 C -4.20626 -1.42894 0.0 0
M V30 12 C -3.79376 -2.14341 0.0 0
M V30 13 C -2.96876 -2.14341 0.0 0
M V30 14 C -2.55626 -1.42894 0.0 0
M V30 15 C -4.78962 0.583363 0.0 0
M V30 16 C -4.78962 -0.583363 0.0 0
M V30 17 Cu 0.68774 -0.185058 0.0 0 CHG=1
M V30 18 C 2.74227 1.50444 0.0 0
M V30 19 N 2.74227 0.679442 0.0 0
M V30 20 C 3.45674 0.266942 0.0 0
M V30 21 C 4.17121 0.679442 0.0 0
M V30 22 C 4.17121 1.50444 0.0 0
M V30 23 C 3.45674 1.91694 0.0 0
M V30 24 C 3.45674 -0.558058 0.0 0
M V30 25 C 4.17121 -0.970558 0.0 0
M V30 26 C 4.88568 -0.558058 0.0 0
M V30 27 C 4.88568 0.266942 0.0 0
M V30 28 N 2.74227 -0.970558 0.0 0
M V30 29 C 2.74227 -1.79556 0.0 0
M V30 30 C 3.45674 -2.20806 0.0 0
M V30 31 C 4.17121 -1.79556 0.0 0
M V30 32 C 4.88568 1.91694 0.0 0
M V30 33 C 4.88568 -2.20806 0.0 0
M V30 34 C 5.60015 1.50444 0.0 0
M V30 35 C 6.31462 1.91694 0.0 0
M V30 36 C 6.31462 2.74194 0.0 0
M V30 37 C 5.60015 3.15444 0.0 0
M V30 38 C 4.88568 2.74194 0.0 0
M V30 39 C 4.88568 -3.03306 0.0 0
M V30 40 C 5.60015 -3.44556 0.0 0
M V30 41 C 6.31462 -3.03306 0.0 0
M V30 42 C 6.31462 -2.20806 0.0 0
M V30 43 C 5.60015 -1.79556 0.0 0
M V30 44 C 2.0278 1.91694 0.0 0
M V30 45 C 2.0278 -2.20806 0.0 0
M V30 46 P -1.55626 1.42894 0.0 0
M V30 47 P -1.55626 -1.42894 0.0 0
M V30 48 C -1.81508 -2.39487 0.0 0
M V30 49 C -1.36565 -4.06578 0.0 0
M V30 50 C -1.1072 -3.10221 0.0 0
M V30 51 C -2.33232 -4.3255 0.0 0
M V30 52 C -2.78561 -2.65562 0.0 0
M V30 53 C -3.0382 -3.62327 0.0 0
M V30 54 C -0.690235 -1.92894 0.0 0
M V30 55 C 1.04007 -1.9273 0.0 0
M V30 56 C 0.176218 -1.42825 0.0 0
M V30 57 C 1.04074 -2.92824 0.0 0
M V30 58 C -0.689561 -2.93389 0.0 0
M V30 59 C 0.179743 -3.42832 0.0 0
M V30 60 C -1.81508 2.39487 0.0 0
M V30 61 C -3.03975 3.61721 0.0 0
M V30 62 C -2.78179 2.6535 0.0 0
M V30 63 C -2.33245 4.32546 0.0 0
M V30 64 C -1.10495 3.10595 0.0 0
M V30 65 C -1.37003 4.07025 0.0 0
M V30 66 C -0.690235 1.92894 0.0 0
M V30 67 C 0.173491 3.42825 0.0 0
M V30 68 C -0.690617 2.92966 0.0 0
M V30 69 C 1.04067 2.92836 0.0 0
M V30 70 C 0.18041 1.42705 0.0 0
M V30 71 C 1.04325 1.93268 0.0 0
M V30 72 P 7.55 0.2 0.0 0 CHG=-1
M V30 73 F 8.08382 1.01593 0.0 0
M V30 74 F 8.51593 -0.058819 0.0 0
M V30 75 F 7.80882 -0.765926 0.0 0
M V30 76 F 6.84289 -0.507107 0.0 0
M V30 77 F 6.55 0.2 0.0 0
M V30 78 F 7.05 1.06603 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 3 7
M V30 8 2 8 9
M V30 9 1 10 4
M V30 10 1 8 11
M V30 11 2 11 12
M V30 12 1 12 13
M V30 13 2 13 14
M V30 14 1 14 9
M V30 15 1 7 8
M V30 16 1 10 9
M V30 17 1 7 15
M V30 18 1 7 16
M V30 19 2 18 19
M V30 20 1 19 20
M V30 21 2 20 21
M V30 22 1 21 22
M V30 23 2 22 23
M V30 24 1 23 18
M V30 25 1 20 24
M V30 26 2 24 25
M V30 27 1 25 26
M V30 28 2 26 27
M V30 29 1 27 21
M V30 30 1 24 28
M V30 31 2 28 29
M V30 32 1 29 30
M V30 33 2 30 31
M V30 34 1 31 25
M V30 35 1 22 32
M V30 36 1 31 33
M V30 37 2 32 34
M V30 38 1 34 35
M V30 39 2 35 36
M V30 40 1 36 37
M V30 41 2 37 38
M V30 42 1 38 32
M V30 43 2 33 39
M V30 44 1 39 40
M V30 45 2 40 41
M V30 46 1 41 42
M V30 47 2 42 43
M V30 48 1 43 33
M V30 49 1 18 44
M V30 50 1 29 45
M V30 51 8 17 19
M V30 52 8 17 28
M V30 53 1 5 46
M V30 54 1 14 47
M V30 55 1 47 48
M V30 56 2 50 48
M V30 57 2 51 49
M V30 58 1 48 52
M V30 59 1 49 50
M V30 60 2 52 53
M V30 61 1 53 51
M V30 62 1 47 54
M V30 63 2 56 54
M V30 64 2 57 55
M V30 65 1 54 58
M V30 66 1 55 56
M V30 67 2 58 59
M V30 68 1 59 57
M V30 69 1 46 60
M V30 70 2 62 60
M V30 71 2 63 61
M V30 72 1 60 64
M V30 73 1 61 62
M V30 74 2 64 65
M V30 75 1 65 63
M V30 76 1 46 66
M V30 77 2 68 66
M V30 78 2 69 67
M V30 79 1 66 70
M V30 80 1 67 68
M V30 81 2 70 71
M V30 82 1 71 69
M V30 83 8 46 17
M V30 84 8 47 17
M V30 85 1 72 73
M V30 86 1 72 74
M V30 87 1 72 75
M V30 88 1 72 76
M V30 89 1 72 77
M V30 90 1 72 78
M V30 END BOND
M V30 END CTAB
M END
</chemform><chemform smiles="C1(C(=C(C(=C(C=1N(C1C=CC=CC=1)C1C=CC=CC=1)N(C1C=CC=CC=1)C1C=CC=CC=1)N(C1C=CC=CC=1)C1=CC=CC=C1)C#N)N(C1C=CC=CC=1)C1C=CC=CC=1)C#N" inchi="1S/C56H40N6/c57-41-51-53(59(43-25-9-1-10-26-43)44-27-11-2-12-28-44)52(42-58)55(61(47-33-17-5-18-34-47)48-35-19-6-20-36-48)56(62(49-37-21-7-22-38-49)50-39-23-8-24-40-50)54(51)60(45-29-13-3-14-30-45)46-31-15-4-16-32-46/h1-40H" inchikey="ZOMQCVKHGOMNER-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12122411272D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 62 70 5 0 0
M V30 BEGIN ATOM
M V30 1 C -0.714471 0.4125 0.0 0
M V30 2 C -0.714471 -0.4125 0.0 0
M V30 3 C 0.0 -0.825 0.0 0
M V30 4 C 0.714471 -0.4125 0.0 0
M V30 5 C 0.714471 0.4125 0.0 0
M V30 6 C 0.0 0.825 0.0 0
M V30 7 C -1.42894 0.825 0.0 0
M V30 8 N -2.14341 1.2375 0.0 0
M V30 9 C 1.42894 0.825 0.0 0
M V30 10 N 2.14341 1.2375 0.0 0
M V30 11 N 0.05 2.925 0.0 0
M V30 12 C 0.764471 3.3375 0.0 0
M V30 13 C 1.47894 2.925 0.0 0
M V30 14 C 2.19341 3.3375 0.0 0
M V30 15 C 2.19341 4.1625 0.0 0
M V30 16 C 1.47894 4.575 0.0 0
M V30 17 C 0.764471 4.1625 0.0 0
M V30 18 C -0.664471 3.3375 0.0 0
M V30 19 C -0.664471 4.1625 0.0 0
M V30 20 C -1.37894 4.575 0.0 0
M V30 21 C -2.09341 4.1625 0.0 0
M V30 22 C -2.09341 3.3375 0.0 0
M V30 23 C -1.37894 2.925 0.0 0
M V30 24 N -3.20394 -1.95 0.0 0
M V30 25 C -3.91841 -1.5375 0.0 0
M V30 26 C -3.91841 -0.7125 0.0 0
M V30 27 C -4.63288 -0.3 0.0 0
M V30 28 C -5.34736 -0.7125 0.0 0
M V30 29 C -5.34736 -1.5375 0.0 0
M V30 30 C -4.63288 -1.95 0.0 0
M V30 31 C -3.20394 -2.775 0.0 0
M V30 32 C -3.91841 -3.1875 0.0 0
M V30 33 C -3.91841 -4.0125 0.0 0
M V30 34 C -3.20394 -4.425 0.0 0
M V30 35 C -2.48947 -4.0125 0.0 0
M V30 36 C -2.48947 -3.1875 0.0 0
M V30 37 N 0.025 -3.8 0.0 0
M V30 38 C -1.40394 -3.8 0.0 0
M V30 39 C -2.11841 -5.0375 0.0 0
M V30 40 C -1.40394 -5.45 0.0 0
M V30 41 C -0.689471 -5.0375 0.0 0
M V30 42 C 0.739471 -4.2125 0.0 0
M V30 43 C 0.739471 -5.0375 0.0 0
M V30 44 C 1.45394 -5.45 0.0 0
M V30 45 C 2.16841 -4.2125 0.0 0
M V30 46 C 1.45394 -3.8 0.0 0
M V30 47 N 3.52894 -1.825 0.0 0
M V30 48 C 3.52894 -2.65 0.0 0
M V30 49 C 2.81447 -3.8875 0.0 0
M V30 50 C 3.52894 -4.3 0.0 0
M V30 51 C 4.24341 -3.8875 0.0 0
M V30 52 C 4.24341 -3.0625 0.0 0
M V30 53 C 4.24341 -1.4125 0.0 0
M V30 54 C 4.95788 -1.825 0.0 0
M V30 55 C 5.67236 -1.4125 0.0 0
M V30 56 C 5.67236 -0.5875 0.0 0
M V30 57 C 4.95788 -0.175 0.0 0
M V30 58 C 4.24341 -0.5875 0.0 0
M V30 59 C 2.16841 -5.0375 0.0 0
M V30 60 C -2.11841 -4.2125 0.0 0
M V30 61 C -0.689471 -4.2125 0.0 0
M V30 62 C 2.81447 -3.0625 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 7 8
M V30 2 1 1 7
M V30 3 3 9 10
M V30 4 1 5 9
M V30 5 2 22 23
M V30 6 1 21 22
M V30 7 2 20 21
M V30 8 1 19 20
M V30 9 2 18 19
M V30 10 1 18 23
M V30 11 2 16 17
M V30 12 1 15 16
M V30 13 2 14 15
M V30 14 1 13 14
M V30 15 2 12 13
M V30 16 1 12 17
M V30 17 1 11 12
M V30 18 1 11 18
M V30 19 1 6 11
M V30 20 2 35 36
M V30 21 1 34 35
M V30 22 2 33 34
M V30 23 1 32 33
M V30 24 2 31 32
M V30 25 1 31 36
M V30 26 2 29 30
M V30 27 1 28 29
M V30 28 2 27 28
M V30 29 1 26 27
M V30 30 2 25 26
M V30 31 1 25 30
M V30 32 1 24 25
M V30 33 1 24 31
M V30 34 1 2 24
M V30 35 2 45 46
M V30 36 1 43 44
M V30 37 2 42 43
M V30 38 1 42 46
M V30 39 2 40 41
M V30 40 1 39 40
M V30 41 1 37 42
M V30 42 1 3 37
M V30 43 2 57 58
M V30 44 1 56 57
M V30 45 2 55 56
M V30 46 1 54 55
M V30 47 2 53 54
M V30 48 1 53 58
M V30 49 2 51 52
M V30 50 1 50 51
M V30 51 2 49 50
M V30 52 1 48 52
M V30 53 1 47 48
M V30 54 1 47 53
M V30 55 1 4 47
M V30 56 2 1 2
M V30 57 1 2 3
M V30 58 2 3 4
M V30 59 1 4 5
M V30 60 2 5 6
M V30 61 1 6 1
M V30 62 1 59 45
M V30 63 2 44 59
M V30 64 1 38 60
M V30 65 2 60 39
M V30 66 2 61 38
M V30 67 1 37 61
M V30 68 1 61 41
M V30 69 2 48 62
M V30 70 1 62 49
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 7 8) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.00000-
M V30 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LABE-
M V30 L=CN
M V30 2 SUP 2 ATOMS=(2 9 10) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0-
M V30 .000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LAB-
M V30 EL=CN
M V30 3 SUP 3 ATOMS=(13 11 12 13 14 15 16 17 18 19 20 21 22 23) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 4 SUP 4 ATOMS=(13 37 38 39 40 41 42 43 44 45 46 59 60 61) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 5 SUP 5 ATOMS=(13 47 48 49 50 51 52 53 54 55 56 57 58 62) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Investigation ===
Key aspects investigated include:

* Catalyst stability and reusability.
* Impact of photosensitizer and electron donor concentrations on performance.
* Role of acidic co-substrates in improving CO2 reduction rates.
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 01|importFile=Template CO2 reduction_v1.0.xlsx|description=Table 01}}

=== Further Information ===

* Control experiments demonstrated that light, the catalyst, and BIH were essential for activity.
* The reaction follows a reductive quenching pathway with efficient electron transfer from BIH to the photosensitizer and subsequently to the catalyst.

==== Sacrificial electron donor ====
In this Study, the experiments were done with the sacrificial electron donor [[Molecule:100508|BIH]].
[[Category:Photocatalytic CO2 conversion to CO]]

Efficient Visible-Light-Driven Carbon Dioxide Reduction using a Bioinspired Nickel Molecular Catalyst

2024-12-16T16:05:50Z

ChemUser:

{{DOI|doi=10.1002/cssc.202301892}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== Abstract[edit | edit source] ===
The study introduces a bioinspired nickel-based molecular catalyst, [Ni(N2S2)]Cl2 (NiN2S2), for photochemical catalytic reduction of CO2 under visible light. Combining the catalyst with [Ru(bpy)3]Cl2 as a photosensitizer and BIH as a sacrificial electron donor, the system achieved an 89% selectivity towards CO, with a turnover number (TON) of 7991 during 8 hours of irradiation. The process demonstrated high catalytic efficiency with a turnover frequency (TOF) of 1079 h⁻¹ and an apparent quantum yield (AQY) of 1.08%.

==== Summary[edit | edit source] ====
Inspired by natural enzymes, this work focuses on the development of a novel nickel catalyst for CO2 photoreduction. NiN2S2, designed with thiol and pyridine ligands, exhibited remarkable activity and selectivity in converting CO2 to CO. Control experiments confirmed the necessity of light, the catalyst, and sacrificial electron donors. Acidic co-substrates such as phenol further enhanced the reaction's efficiency without compromising selectivity. This study establishes NiN2S2 as a promising candidate for sustainable CO2 reduction under visible light.

==== Additional remarks[edit | edit source] ====

* The combination of sulfur and nitrogen ligands in NiN2S2 enhances its stability and catalytic efficiency.
* Acid additives, particularly phenol, significantly improve reaction rates, indicating a key role in CO2 stabilization and protonation steps.
* Further research is proposed to optimize ligand coordination and investigate intermediate reaction mechanisms.

=== Content of the published article in detail[edit | edit source] ===

* The synthesis and characterization of NiN2S2 using advanced analytical techniques like LC-HRMS and X-ray crystallography.
* The photocatalytic performance of NiN2S2 in reducing CO2 to CO under visible light, achieving high selectivity and efficiency.
* Mechanistic insights into the electron transfer process facilitated by the catalyst and photosensitizer.

=== Catalysts tested in this study[edit | edit source] ===
<chemform smiles="C1C2CS3[Ni](Cl)(Cl)45S(CC6N4=C(C3)C=CC=6)CC(N=25)=CC=1" inchi="1S/C14H14N2S2.2ClH.Ni/c1-3-11-7-17-9-13-5-2-6-14(16-13)10-18-8-12(4-1)15-11;;;/h1-6H,7-10H2;2*1H;/q;;;+2/p-2" inchikey="XRUWRFIGSFNAGZ-UHFFFAOYSA-L" height="100px" width="150px" float="none">
-INDIGO-12122410452D

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M V30 BEGIN ATOM
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M V30 3 C -1.36339 -1.73543 0.0 0
M V30 4 C -0.648917 -1.32293 0.0 0
M V30 5 N -0.648917 -0.497932 0.0 0
M V30 6 C -1.36339 -0.085432 0.0 0
M V30 7 C -1.36339 0.739568 0.0 0
M V30 8 C 0.065554 -1.73543 0.0 0
M V30 9 S -0.648917 1.15207 0.0 0
M V30 10 S 0.780025 -1.32293 0.0 0
M V30 11 C 1.36339 -0.739568 0.0 0
M V30 12 C 1.36339 0.085432 0.0 0
M V30 13 C 2.07786 0.497932 0.0 0
M V30 14 C 2.07786 1.32293 0.0 0
M V30 15 C 1.36339 1.73543 0.0 0
M V30 16 C 0.648917 1.32293 0.0 0
M V30 17 N 0.648917 0.497932 0.0 0
M V30 18 C 0.065554 1.56457 0.0 0
M V30 19 Ni 0.072112 -0.019432 0.0 0
M V30 20 Cl -0.752888 0.327068 0.0 0
M V30 21 Cl 0.897112 -0.316431 0.0 0
M V30 END ATOM
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M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 6 7
M V30 8 1 4 8
M V30 9 1 7 9
M V30 10 1 8 10
M V30 11 1 10 11
M V30 12 1 11 12
M V30 13 2 12 13
M V30 14 1 13 14
M V30 15 2 14 15
M V30 16 1 15 16
M V30 17 2 16 17
M V30 18 1 17 12
M V30 19 1 9 18
M V30 20 1 18 16
M V30 21 10 5 19
M V30 22 10 17 19
M V30 23 10 9 19
M V30 24 10 19 10
M V30 25 1 20 19
M V30 26 1 19 21
M V30 END BOND
M V30 END CTAB
M END
</chemform>

([Ni(N2S2)]Cl2): A bioinspired nickel molecular catalyst.

=== Photosensitizer[edit | edit source] ===
<chemform smiles="N12[Ru](Cl)(Cl)3(N4C=CC=CC=4C4C=CC=CN=43)(N3C=CC=CC=3C=1C=CC=C2)1N2C=CC=CC=2C2C=CC=CN=21" inchi="1S/3C10H8N2.2ClH.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2" inchikey="SJFYGUKHUNLZTK-UHFFFAOYSA-L" height="200px" width="300px" float="none">
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M V30 BEGIN ATOM
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M V30 3 C 2.73071 0.761834 0.0 0
M V30 4 C 2.71343 1.58665 0.0 0
M V30 5 C 1.99048 1.9841 0.0 0
M V30 6 C 1.28481 1.55673 0.0 0
M V30 7 C 2.04231 -0.490355 0.0 0
M V30 8 N 1.33663 -0.917725 0.0 0
M V30 9 C 1.3539 -1.74254 0.0 0
M V30 10 C 2.07685 -2.13999 0.0 0
M V30 11 C 2.78253 -1.71262 0.0 0
M V30 12 C 2.76526 -0.887804 0.0 0
M V30 13 N 0.125472 -1.63593 0.0 0
M V30 14 C -0.558829 -2.09676 0.0 0
M V30 15 C -0.501895 -2.91979 0.0 0
M V30 16 C 0.23934 -3.282 0.0 0
M V30 17 C 0.92364 -2.82118 0.0 0
M V30 18 C 0.866706 -1.99814 0.0 0
M V30 19 C -1.30006 -1.73454 0.0 0
M V30 20 N -1.357 -0.911512 0.0 0
M V30 21 C -2.09823 -0.549301 0.0 0
M V30 22 C -2.78253 -1.01012 0.0 0
M V30 23 C -2.7256 -1.83316 0.0 0
M V30 24 C -1.98436 -2.19537 0.0 0
M V30 25 N -1.22265 0.708208 0.0 0
M V30 26 C -1.28359 1.53095 0.0 0
M V30 27 C -2.02658 1.88955 0.0 0
M V30 28 C -2.70863 1.4254 0.0 0
M V30 29 C -2.64769 0.602657 0.0 0
M V30 30 C -1.9047 0.24406 0.0 0
M V30 31 C -0.601539 1.9951 0.0 0
M V30 32 N 0.14145 1.63651 0.0 0
M V30 33 C 0.8235 2.10066 0.0 0
M V30 34 C 0.762559 2.9234 0.0 0
M V30 35 C 0.01957 3.282 0.0 0
M V30 36 C -0.662479 2.81785 0.0 0
M V30 37 Ru 0.028919 -0.177739 0.0 0
M V30 38 Cl 1.08492 -0.111739 0.0 0
M V30 39 Cl -0.961081 -0.210738 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 2 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 11
M V30 12 2 11 12
M V30 13 1 12 7
M V30 14 2 13 14
M V30 15 1 14 15
M V30 16 2 15 16
M V30 17 1 16 17
M V30 18 2 17 18
M V30 19 1 18 13
M V30 20 1 14 19
M V30 21 2 19 20
M V30 22 1 20 21
M V30 23 2 21 22
M V30 24 1 22 23
M V30 25 2 23 24
M V30 26 1 24 19
M V30 27 2 25 26
M V30 28 1 26 27
M V30 29 2 27 28
M V30 30 1 28 29
M V30 31 2 29 30
M V30 32 1 30 25
M V30 33 1 26 31
M V30 34 2 31 32
M V30 35 1 32 33
M V30 36 2 33 34
M V30 37 1 34 35
M V30 38 2 35 36
M V30 39 1 36 31
M V30 40 1 37 25 CFG=3
M V30 41 1 32 37
M V30 42 1 37 20 CFG=1
M V30 43 1 37 8 CFG=1
M V30 44 1 37 13
M V30 45 1 37 1 CFG=3
M V30 46 1 39 37
M V30 47 1 37 38
M V30 END BOND
M V30 END CTAB
M END
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-INDIGO-12122411182D

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M V30 BEGIN CTAB
M V30 COUNTS 85 96 0 0 0
M V30 BEGIN ATOM
M V30 1 C -3.79376 2.14341 0.0 0
M V30 2 C -4.20626 1.42894 0.0 0
M V30 3 C -3.79376 0.714471 0.0 0
M V30 4 C -2.96876 0.714471 0.0 0
M V30 5 C -2.55626 1.42894 0.0 0
M V30 6 C -2.96876 2.14341 0.0 0
M V30 7 C -4.20626 0.0 0.0 0
M V30 8 C -3.79376 -0.714471 0.0 0
M V30 9 C -2.96876 -0.714471 0.0 0
M V30 10 O -2.55626 0.0 0.0 0
M V30 11 C -4.20626 -1.42894 0.0 0
M V30 12 C -3.79376 -2.14341 0.0 0
M V30 13 C -2.96876 -2.14341 0.0 0
M V30 14 C -2.55626 -1.42894 0.0 0
M V30 15 C -4.78962 0.583363 0.0 0
M V30 16 C -4.78962 -0.583363 0.0 0
M V30 17 Cu 1.21274 -0.360058 0.0 0 CHG=2
M V30 18 C 2.74227 1.50444 0.0 0
M V30 19 N 2.74227 0.679442 0.0 0
M V30 20 C 3.45674 0.266942 0.0 0
M V30 21 C 4.17121 0.679442 0.0 0
M V30 22 C 4.17121 1.50444 0.0 0
M V30 23 C 3.45674 1.91694 0.0 0
M V30 24 C 3.45674 -0.558058 0.0 0
M V30 25 C 4.17121 -0.970558 0.0 0
M V30 26 C 4.88568 -0.558058 0.0 0
M V30 27 C 4.88568 0.266942 0.0 0
M V30 28 N 2.74227 -0.970558 0.0 0
M V30 29 C 2.74227 -1.79556 0.0 0
M V30 30 C 3.45674 -2.20806 0.0 0
M V30 31 C 4.17121 -1.79556 0.0 0
M V30 32 C 4.88568 1.91694 0.0 0
M V30 33 C 4.88568 -2.20806 0.0 0
M V30 34 C 5.60015 1.50444 0.0 0
M V30 35 C 6.31462 1.91694 0.0 0
M V30 36 C 6.31462 2.74194 0.0 0
M V30 37 C 5.60015 3.15444 0.0 0
M V30 38 C 4.88568 2.74194 0.0 0
M V30 39 C 4.88568 -3.03306 0.0 0
M V30 40 C 5.60015 -3.44556 0.0 0
M V30 41 C 6.31462 -3.03306 0.0 0
M V30 42 C 6.31462 -2.20806 0.0 0
M V30 43 C 5.60015 -1.79556 0.0 0
M V30 44 C 2.0278 1.91694 0.0 0
M V30 45 C 2.0278 -2.20806 0.0 0
M V30 46 P -1.55626 1.42894 0.0 0
M V30 47 P -1.55626 -1.42894 0.0 0
M V30 48 C -1.81508 -2.39487 0.0 0
M V30 49 C -1.36565 -4.06578 0.0 0
M V30 50 C -1.1072 -3.10221 0.0 0
M V30 51 C -2.33232 -4.3255 0.0 0
M V30 52 C -2.78561 -2.65562 0.0 0
M V30 53 C -3.0382 -3.62327 0.0 0
M V30 54 C -0.690235 -1.92894 0.0 0
M V30 55 C 1.04007 -1.9273 0.0 0
M V30 56 C 0.176218 -1.42825 0.0 0
M V30 57 C 1.04074 -2.92824 0.0 0
M V30 58 C -0.689561 -2.93389 0.0 0
M V30 59 C 0.179743 -3.42832 0.0 0
M V30 60 C -1.81508 2.39487 0.0 0
M V30 61 C -3.03975 3.61721 0.0 0
M V30 62 C -2.78179 2.6535 0.0 0
M V30 63 C -2.33245 4.32546 0.0 0
M V30 64 C -1.10495 3.10595 0.0 0
M V30 65 C -1.37003 4.07025 0.0 0
M V30 66 C -0.690235 1.92894 0.0 0
M V30 67 C 0.173491 3.42825 0.0 0
M V30 68 C -0.690617 2.92966 0.0 0
M V30 69 C 1.04067 2.92836 0.0 0
M V30 70 C 0.18041 1.42705 0.0 0
M V30 71 C 1.04325 1.93268 0.0 0
M V30 72 P 8.025 1.225 0.0 0 CHG=-1
M V30 73 F 8.28382 2.19093 0.0 0
M V30 74 F 8.99093 0.966181 0.0 0
M V30 75 F 8.28382 0.259074 0.0 0
M V30 76 F 7.31789 0.517893 0.0 0
M V30 77 F 7.025 1.225 0.0 0
M V30 78 F 7.525 2.09103 0.0 0
M V30 79 P 8.26704 -1.9 0.0 0 CHG=-1
M V30 80 F 8.52586 -0.934074 0.0 0
M V30 81 F 9.23296 -2.15882 0.0 0
M V30 82 F 8.52586 -2.86593 0.0 0
M V30 83 F 7.55993 -2.60711 0.0 0
M V30 84 F 7.26704 -1.9 0.0 0
M V30 85 F 7.76704 -1.03397 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 3 7
M V30 8 2 8 9
M V30 9 1 10 4
M V30 10 1 8 11
M V30 11 2 11 12
M V30 12 1 12 13
M V30 13 2 13 14
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M V30 15 1 7 8
M V30 16 1 10 9
M V30 17 1 7 15
M V30 18 1 7 16
M V30 19 2 18 19
M V30 20 1 19 20
M V30 21 2 20 21
M V30 22 1 21 22
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M V30 24 1 23 18
M V30 25 1 20 24
M V30 26 2 24 25
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M V30 29 1 27 21
M V30 30 1 24 28
M V30 31 2 28 29
M V30 32 1 29 30
M V30 33 2 30 31
M V30 34 1 31 25
M V30 35 1 22 32
M V30 36 1 31 33
M V30 37 2 32 34
M V30 38 1 34 35
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M V30 48 1 43 33
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M V30 50 1 29 45
M V30 51 10 17 19
M V30 52 10 17 28
M V30 53 1 5 46
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M V30 55 1 47 48
M V30 56 2 50 48
M V30 57 2 51 49
M V30 58 1 48 52
M V30 59 1 49 50
M V30 60 2 52 53
M V30 61 1 53 51
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M V30 73 1 61 62
M V30 74 2 64 65
M V30 75 1 65 63
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M V30 77 2 68 66
M V30 78 2 69 67
M V30 79 1 66 70
M V30 80 1 67 68
M V30 81 2 70 71
M V30 82 1 71 69
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M V30 84 8 47 17
M V30 85 1 72 73
M V30 86 1 72 74
M V30 87 1 72 75
M V30 88 1 72 76
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M V30 94 1 79 83
M V30 95 1 79 84
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M V30 END BOND
M V30 END CTAB
M END
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M V30 BEGIN CTAB
M V30 COUNTS 62 70 5 0 0
M V30 BEGIN ATOM
M V30 1 C -0.714471 0.4125 0.0 0
M V30 2 C -0.714471 -0.4125 0.0 0
M V30 3 C 0.0 -0.825 0.0 0
M V30 4 C 0.714471 -0.4125 0.0 0
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M V30 9 C 1.42894 0.825 0.0 0
M V30 10 N 2.14341 1.2375 0.0 0
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M V30 12 C 0.764471 3.3375 0.0 0
M V30 13 C 1.47894 2.925 0.0 0
M V30 14 C 2.19341 3.3375 0.0 0
M V30 15 C 2.19341 4.1625 0.0 0
M V30 16 C 1.47894 4.575 0.0 0
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M V30 36 C -2.48947 -3.1875 0.0 0
M V30 37 N 0.025 -3.8 0.0 0
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M V30 54 C 4.95788 -1.825 0.0 0
M V30 55 C 5.67236 -1.4125 0.0 0
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M V30 57 C 4.95788 -0.175 0.0 0
M V30 58 C 4.24341 -0.5875 0.0 0
M V30 59 C 2.16841 -5.0375 0.0 0
M V30 60 C -2.11841 -4.2125 0.0 0
M V30 61 C -0.689471 -4.2125 0.0 0
M V30 62 C 2.81447 -3.0625 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 7 8
M V30 2 1 1 7
M V30 3 3 9 10
M V30 4 1 5 9
M V30 5 2 22 23
M V30 6 1 21 22
M V30 7 2 20 21
M V30 8 1 19 20
M V30 9 2 18 19
M V30 10 1 18 23
M V30 11 2 16 17
M V30 12 1 15 16
M V30 13 2 14 15
M V30 14 1 13 14
M V30 15 2 12 13
M V30 16 1 12 17
M V30 17 1 11 12
M V30 18 1 11 18
M V30 19 1 6 11
M V30 20 2 35 36
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M V30 23 1 32 33
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M V30 25 1 31 36
M V30 26 2 29 30
M V30 27 1 28 29
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M V30 29 1 26 27
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M V30 31 1 25 30
M V30 32 1 24 25
M V30 33 1 24 31
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M V30 36 1 43 44
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M V30 39 2 40 41
M V30 40 1 39 40
M V30 41 1 37 42
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M V30 43 2 57 58
M V30 44 1 56 57
M V30 45 2 55 56
M V30 46 1 54 55
M V30 47 2 53 54
M V30 48 1 53 58
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M V30 50 1 50 51
M V30 51 2 49 50
M V30 52 1 48 52
M V30 53 1 47 48
M V30 54 1 47 53
M V30 55 1 4 47
M V30 56 2 1 2
M V30 57 1 2 3
M V30 58 2 3 4
M V30 59 1 4 5
M V30 60 2 5 6
M V30 61 1 6 1
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M V30 63 2 44 59
M V30 64 1 38 60
M V30 65 2 60 39
M V30 66 2 61 38
M V30 67 1 37 61
M V30 68 1 61 41
M V30 69 2 48 62
M V30 70 1 62 49
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 7 8) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.-
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M V30 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LABE-
M V30 L=CN
M V30 2 SUP 2 ATOMS=(2 9 10) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0-
M V30 .000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LAB-
M V30 EL=CN
M V30 3 SUP 3 ATOMS=(13 11 12 13 14 15 16 17 18 19 20 21 22 23) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 4 SUP 4 ATOMS=(13 37 38 39 40 41 42 43 44 45 46 59 60 61) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 5 SUP 5 ATOMS=(13 47 48 49 50 51 52 53 54 55 56 57 58 62) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000) LABEL=NPh2
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Investigation[edit | edit source] ===
Key aspects investigated include:

* Catalyst stability and reusability.
* Impact of photosensitizer and electron donor concentrations on performance.
* Role of acidic co-substrates in improving CO2 reduction rates.
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 01|importFile=Template CO2 reduction_v1.0.xlsx|description=Table 01}}

=== Further Information[edit | edit source] ===

* Control experiments demonstrated that light, the catalyst, and BIH were essential for activity.
* The reaction follows a reductive quenching pathway with efficient electron transfer from BIH to the photosensitizer and subsequently to the catalyst.

==== Sacrificial electron donor[edit | edit source] ====
In this Study, the experiments were done with the sacrificial electron donor [[Molecule:100508|BIH]].
[[Category:Photocatalytic CO2 conversion to CO]]

Photochemical CO2 Reduction Driven by Water-Soluble Copper(I) Photosensitizer with the Catalysis Accelerated by Multi-Electron Chargeable Cobalt Porphyrin

2024-12-16T16:02:11Z

ChemUser:

{{DOI|doi=10.1021/acscatal.9b04023}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

=== Abstract ===
This study introduces a fully aqueous photochemical CO₂ reduction system that uses a water-soluble copper(I) photosensitizer (CuPS){{#moleculelink:|link=PDVCFPPNDZGLBQ-UHFFFAOYSA-L|image=false|width=300|height=200}} and a cobalt porphyrin catalyst (CoTMPyP). The system achieves high turnover numbers and selectivity for CO₂-to-CO conversion, outperforming other aqueous systems. The multi-electron chargeable property of CoTMPyP is key to its catalytic efficiency and selectivity.
[[Category:Publication]]
=== Summary ===
A cop
[[Category:Publication]]
per(I) diimine complex serves as an efficient, water-soluble photosensitizer, enabling visible-light-driven CO₂-to-CO conversion in aqueous media. This system incorporates CoTMPyP, a cobalt porphyrin catalyst, achieving unprecedented catalytic performance. Key advances include a high turnover number (TON) and fast catalytic rates due to the multi-electron redox properties of CoTMPyP. The study demonstrates the potential of combining earth-abundant materials for sustainable photochemical CO₂ reduction.

=== Additional Remarks ===
The research underscores the importance of designing water-compatible, earth-abundant photocatalytic systems. CoTMPyP's multi-electron storage capability enables rapid intramolecular electron transfer, improving CO release. The CuPS-CoTMPyP system provides insights into addressing challenges like H₂ competition in aqueous CO₂ reduction systems.

=== Content of the Published Article in Detail ===

* Design and preparation of the copper(I) photosensitizer CuPS.
* Photochemical studies demonstrating the CO₂ reduction mechanism in aqueous systems.
* Role of the multi-electron chargeable CoTMPyP in accelerating catalysis.
* Experimental results showing high TON and TOF under optimized conditions.
* Discussion of reaction selectivity, including negligible formation of undesired byproducts such as HCOOH.

=== Catalysts Tested in This Study ===

* '''CoTMPyP:''' A cobalt porphyrin catalyst with high catalytic efficiency (right).
* '''CoTPPS:''' Another cobalt porphyrin derivative used for comparison, with lower activity and selectivity compared to CoTMPyP (left) {{#moleculelink:|link=OIPFTFWKVIYBSF-UHFFFAOYSA-N|image=false|width=300|height=200}}.

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-INDIGO-12112414552D

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M V30 END ATOM
M V30 BEGIN BOND
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M V30 48 1 12 39
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M V30 END BOND
M V30 END CTAB
M END
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-INDIGO-12112414562D

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M V30 BEGIN BOND
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M V30 19 2 6 5
M V30 20 2 8 7
M V30 21 1 13 1
M V30 22 2 13 9
M V30 23 1 14 2
M V30 24 2 14 10
M V30 25 2 15 3
M V30 26 1 15 9
M V30 27 1 16 5
M V30 28 1 16 10
M V30 29 2 17 4
M V30 30 1 17 11
M V30 31 1 18 6
M V30 32 2 18 12
M V30 33 1 19 7
M V30 34 2 19 11
M V30 35 1 20 8
M V30 36 1 20 12
M V30 37 1 21 13
M V30 38 1 21 14
M V30 39 1 22 15
M V30 40 1 22 17
M V30 41 2 23 16
M V30 42 1 23 18
M V30 43 1 24 19
M V30 44 2 24 20
M V30 45 1 24 25
M V30 46 1 21 25
M V30 47 1 22 25
M V30 48 1 23 25
M V30 49 1 11 26
M V30 50 1 9 27
M V30 51 2 26 28
M V30 52 1 28 29
M V30 53 2 29 30
M V30 54 1 30 31
M V30 55 2 31 32
M V30 56 1 32 26
M V30 57 2 27 33
M V30 58 1 33 34
M V30 59 2 34 35
M V30 60 1 35 36
M V30 61 2 36 37
M V30 62 1 37 27
M V30 63 1 10 38
M V30 64 1 12 39
M V30 65 2 39 40
M V30 66 1 40 41
M V30 67 2 41 42
M V30 68 1 42 43
M V30 69 2 43 44
M V30 70 1 44 39
M V30 71 2 38 45
M V30 72 1 45 46
M V30 73 2 46 47
M V30 74 1 47 48
M V30 75 2 48 49
M V30 76 1 49 38
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(4 50 51 52 53) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 2 SUP 2 ATOMS=(4 54 55 56 57) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 3 SUP 3 ATOMS=(4 58 59 60 61) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 4 SUP 4 ATOMS=(4 62 63 64 65) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===
The copper(I) photosensitizer CuPS ([Cu(L1)(L2)]BF4), where L1 and L2 are ligands, features long-lived excited states, making it highly efficient in driving photochemical CO₂ reduction in aqueous media.

<chemform smiles="C1(C=C(C)N2~[Cu](~N3C4C=2C=1C(=C(C=4C(=CC=3C)C1C=CC=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)1~P(C2C=C(C=C3C(C)(C)C4=CC(=CC(P~1(C1C=CC=CC=1)C1C=CC=CC=1)=C4OC3=2)S([O-])(=O)=O)S([O-])(=O)=O)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1" inchi="1S/C39H32O7P2S2.C26H20N2O6S2.Cu/c1-39(2)33-23-31(49(40,41)42)25-35(47(27-15-7-3-8-16-27)28-17-9-4-10-18-28)37(33)46-38-34(39)24-32(50(43,44)45)26-36(38)48(29-19-11-5-12-20-29)30-21-13-6-14-22-30;1-15-13-19(17-9-5-3-6-10-17)21-23(27-15)24-22(26(36(32,33)34)25(21)35(29,30)31)20(14-16(2)28-24)18-11-7-4-8-12-18;/h3-26H,1-2H3,(H,40,41,42)(H,43,44,45);3-14H,1-2H3,(H,29,30,31)(H,32,33,34);/q;;-2/p-2" inchikey="PDVCFPPNDZGLBQ-UHFFFAOYSA-L" height="200px" width="300px" float="none">
-INDIGO-12112415042D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 87 100 10 0 0
M V30 BEGIN ATOM
M V30 1 C -2.56114 1.6625 0.0 0
M V30 2 C -2.56114 0.8345 0.0 0
M V30 3 C -1.84469 0.4205 0.0 0
M V30 4 N -1.12754 0.8345 0.0 0
M V30 5 C -1.12754 1.6625 0.0 0
M V30 6 C -1.84469 2.07581 0.0 0
M V30 7 C -3.27829 0.4205 0.0 0
M V30 8 C -3.27829 -0.407499 0.0 0
M V30 9 C -2.56114 -0.821498 0.0 0
M V30 10 C -1.84469 -0.407499 0.0 0
M V30 11 C -2.56114 -1.6495 0.0 0
M V30 12 C -1.84469 -2.0635 0.0 0
M V30 13 C -1.12754 -1.6495 0.0 0
M V30 14 N -1.12754 -0.821498 0.0 0
M V30 15 C -0.410401 2.07581 0.0 0
M V30 16 C -0.410401 -2.0635 0.0 0
M V30 17 Cu 1.45104 -0.076391 0.0 0
M V30 18 C 6.5811 0.015442 0.0 0
M V30 19 C 6.1671 0.458868 0.0 0
M V30 20 C 5.3391 0.458868 0.0 0
M V30 21 O 4.9251 0.015442 0.0 0
M V30 22 C 5.3391 -0.427296 0.0 0
M V30 23 C 6.1671 -0.427296 0.0 0
M V30 24 C 6.5811 0.902292 0.0 0
M V30 25 C 6.1671 1.34503 0.0 0
M V30 26 C 5.3391 1.34503 0.0 0
M V30 27 C 4.9251 0.902292 0.0 0
M V30 28 C 4.9251 -0.870721 0.0 0
M V30 29 C 5.3391 -1.31346 0.0 0
M V30 30 C 6.1671 -1.31346 0.0 0
M V30 31 C 6.5811 -0.870721 0.0 0
M V30 32 C 7.16617 -0.345865 0.0 0
M V30 33 C 7.29824 0.27137 0.0 0
M V30 34 P 4.0971 0.902292 0.0 0
M V30 35 P 4.0971 -0.870721 0.0 0
M V30 36 C -3.27829 2.07581 0.0 0
M V30 37 C -3.27829 2.90039 0.0 0
M V30 38 C -3.99269 3.31302 0.0 0
M V30 39 C -4.70641 2.90039 0.0 0
M V30 40 C -4.70641 2.07581 0.0 0
M V30 41 C -3.99269 1.66387 0.0 0
M V30 42 C -3.27829 -2.0635 0.0 0
M V30 43 C -3.99269 -1.65155 0.0 0
M V30 44 C -4.70641 -2.0635 0.0 0
M V30 45 C -4.70641 -2.88807 0.0 0
M V30 46 C -3.99269 -3.3007 0.0 0
M V30 47 C -3.27829 -2.88807 0.0 0
M V30 48 C 3.51134 1.48737 0.0 0
M V30 49 C 3.72484 2.28389 0.0 0
M V30 50 C 3.14182 2.86691 0.0 0
M V30 51 C 2.3453 2.65341 0.0 0
M V30 52 C 2.1318 1.85689 0.0 0
M V30 53 C 2.71482 1.27387 0.0 0
M V30 54 C 4.5111 1.61944 0.0 0
M V30 55 C 5.33568 1.61944 0.0 0
M V30 56 C 5.74762 2.33315 0.0 0
M V30 57 C 5.33568 3.04756 0.0 0
M V30 58 C 4.5111 3.04756 0.0 0
M V30 59 C 4.09847 2.33315 0.0 0
M V30 60 C 3.51134 -1.45579 0.0 0
M V30 61 C 2.71482 -1.24229 0.0 0
M V30 62 C 2.1318 -1.826 0.0 0
M V30 63 C 2.3453 -2.62183 0.0 0
M V30 64 C 3.14182 -2.83534 0.0 0
M V30 65 C 3.72484 -2.25232 0.0 0
M V30 66 C 4.31128 -1.67066 0.0 0
M V30 67 C 3.72826 -2.25368 0.0 0
M V30 68 C 3.94176 -3.05021 0.0 0
M V30 69 C 4.73829 -3.26302 0.0 0
M V30 70 C 5.32131 -2.68 0.0 0
M V30 71 C 5.10781 -1.88348 0.0 0
M V30 72 S 6.75046 1.92839 0.0 0
M V30 73 O 6.16951 2.50935 0.0 0
M V30 74 O 7.33141 1.34744 0.0 0
M V30 75 O 7.33141 2.50935 0.0 0 CHG=-1
M V30 76 S 6.75046 -1.89682 0.0 0
M V30 77 O 7.33141 -1.31587 0.0 0
M V30 78 O 6.16951 -2.47778 0.0 0
M V30 79 O 7.33141 -2.47778 0.0 0 CHG=-1
M V30 80 S -3.99275 0.833017 0.0 0
M V30 81 O -4.40356 0.121507 0.0 0
M V30 82 O -3.58194 1.54453 0.0 0
M V30 83 O -4.70426 1.24383 0.0 0 CHG=-1
M V30 84 S -3.99275 -0.820015 0.0 0
M V30 85 O -3.58194 -1.53153 0.0 0
M V30 86 O -4.40356 -0.108505 0.0 0
M V30 87 O -4.70426 -1.23083 0.0 0 CHG=-1
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 40 41
M V30 2 1 39 40
M V30 3 2 38 39
M V30 4 1 37 38
M V30 5 2 36 37
M V30 6 1 36 41
M V30 7 1 1 36
M V30 8 2 46 47
M V30 9 1 45 46
M V30 10 2 44 45
M V30 11 1 43 44
M V30 12 2 42 43
M V30 13 1 42 47
M V30 14 1 11 42
M V30 15 2 52 53
M V30 16 1 51 52
M V30 17 2 50 51
M V30 18 1 49 50
M V30 19 2 48 49
M V30 20 1 48 53
M V30 21 1 34 48
M V30 22 2 58 59
M V30 23 1 57 58
M V30 24 2 56 57
M V30 25 1 55 56
M V30 26 2 54 55
M V30 27 1 54 59
M V30 28 1 34 54
M V30 29 2 64 65
M V30 30 1 63 64
M V30 31 2 62 63
M V30 32 1 61 62
M V30 33 2 60 61
M V30 34 1 60 65
M V30 35 1 35 60
M V30 36 2 70 71
M V30 37 1 69 70
M V30 38 2 68 69
M V30 39 1 67 68
M V30 40 2 66 67
M V30 41 1 66 71
M V30 42 1 35 66
M V30 43 2 72 73
M V30 44 2 72 74
M V30 45 1 72 75
M V30 46 1 25 72
M V30 47 2 76 77
M V30 48 2 76 78
M V30 49 1 76 79
M V30 50 1 30 76
M V30 51 2 80 81
M V30 52 2 80 82
M V30 53 1 80 83
M V30 54 1 7 80
M V30 55 2 84 85
M V30 56 2 84 86
M V30 57 1 84 87
M V30 58 1 8 84
M V30 59 2 1 2
M V30 60 1 2 3
M V30 61 2 3 4
M V30 62 1 4 5
M V30 63 2 5 6
M V30 64 1 6 1
M V30 65 1 2 7
M V30 66 2 7 8
M V30 67 1 8 9
M V30 68 2 9 10
M V30 69 1 10 3
M V30 70 1 9 11
M V30 71 2 11 12
M V30 72 1 12 13
M V30 73 2 13 14
M V30 74 1 14 10
M V30 75 1 5 15
M V30 76 1 13 16
M V30 77 1 18 19
M V30 78 1 19 20
M V30 79 1 20 21
M V30 80 1 21 22
M V30 81 1 22 23
M V30 82 1 23 18
M V30 83 2 19 24
M V30 84 1 24 25
M V30 85 2 25 26
M V30 86 1 26 27
M V30 87 2 27 20
M V30 88 2 22 28
M V30 89 1 28 29
M V30 90 2 29 30
M V30 91 1 30 31
M V30 92 2 31 23
M V30 93 1 18 32
M V30 94 1 18 33
M V30 95 1 27 34
M V30 96 1 28 35
M V30 97 8 34 17
M V30 98 8 35 17
M V30 99 8 4 17
M V30 100 8 14 17
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(6 36 37 38 39 40 41) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 2 SUP 2 ATOMS=(6 42 43 44 45 46 47) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 3 SUP 3 ATOMS=(6 48 49 50 51 52 53) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 4 SUP 4 ATOMS=(6 54 55 56 57 58 59) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 5 SUP 5 ATOMS=(6 60 61 62 63 64 65) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 6 SUP 6 ATOMS=(6 66 67 68 69 70 71) BRKXYZ=(9 0.000000 0.000000 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000) LABEL=Ph
M V30 7 SUP 7 ATOMS=(4 72 73 74 75) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 8 SUP 8 ATOMS=(4 76 77 78 79) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 9 SUP 9 ATOMS=(4 80 81 82 83) BRKXYZ=(9 0.000000 0.000000 0.000000 0.0-
M V30 00000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000-
M V30 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.0000-
M V30 00) LABEL="SO3-"
M V30 10 SUP 10 ATOMS=(4 84 85 86 87) BRKXYZ=(9 0.000000 0.000000 0.000000 0-
M V30 .000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.0000-
M V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.00-
M V30 0000) LABEL="SO3-"
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Investigation ===
The study involved kinetic analysis of CO and H₂ production under various conditions. Control experiments confirmed the roles of CuPS, CoTMPyP, and ascorbate. The performance was evaluated by quantum yield and CO selectivity metrics, with additional insights provided by structural characterization of intermediates.

{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Tabel 1|importFile=Photocatalytic_CO2_conversion_Template_New.xlsx|description=}}

=== Further Information ===
The findings highlight the influence of ligand design in CuPS and the impact of peripheral groups in CoTMPyP. Future applications might involve integrating such catalysts into hybrid systems or scaling them for industrial CO₂ reduction.

=== Sacrificial Electron Donor ===
In this study, the sacrificial electron donor was sodium ascorbate (AscHNa), which facilitated efficient electron transfer to drive the CO₂ reduction reaction.

=== Additives ===
Additives such as bicarbonate buffer were used to maintain the pH and reaction environment, ensuring stability and efficiency of the photocatalytic system.
[[Category:Photocatalytic CO2 conversion]]

Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO2-to-CO Conversion/Table 1

2024-12-16T15:35:51Z

ChemUser:

{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100993
|cat conc=0.025
|PS=Molecule:100777
|PS conc=0.4
|e-D=Molecule:100507
|e-D conc=0.3
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|feedstock gas=CO2
|intensity=1
|Temperature=25
|λexc=450
|irr time=10
|TON CO=65000
|TOF CO=108
|details=in 5 mL solvent
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100776
|cat conc=0.025
|PS=Molecule:100777
|PS conc=0.4
|e-D=Molecule:100507
|e-D conc=0.3
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|feedstock gas=CO2
|intensity=1
|Temperature=25
|λexc=450
|irr time=10
|TON CO=17000
|TOF CO=28.2
|details=in 5 mL solvent
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100995
|cat conc=0.025
|PS=Molecule:100777
|PS conc=0.4
|e-D=Molecule:100507
|e-D conc=0.3
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|feedstock gas=CO2
|intensity=1
|Temperature=25
|λexc=450
|irr time=10
|TON CO=3400
|TOF CO=5.58
|details=in 5 mL solvent
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100994
|cat conc=0.025
|PS=Molecule:100777
|PS conc=0.4
|e-D=Molecule:100507
|e-D conc=0.3
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|feedstock gas=CO2
|intensity=1
|Temperature=25
|λexc=450
|irr time=10
|TON CO=1500
|TOF CO=2.4
|details=in 5 mL solvent
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100996
|cat conc=0.025
|PS=Molecule:100777
|PS conc=0.4
|e-D=Molecule:100507
|e-D conc=0.3
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=4:1
|feedstock gas=CO2
|intensity=1
|Temperature=25
|λexc=450
|irr time=10
|TON CO=0
|TOF CO=0
|details=in 5 mL solvent
|include=No
}}
}}

Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4/Results for different electron donors and proton donors

2024-12-11T15:27:50Z

ChemUser:

{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=108000
|TON CH4=4000
|TON H2=278000
|details=test
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA, H2O
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=31000
|TON H2=320000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100505
|solvent A=Molecule:100530
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=130000
|TON CH4=29000
|TON H2=4900000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100830
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=310000
|TON H2=33000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100830
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA, H2O
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=175000
|TON CH4=19000
|TON H2=29000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100830
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100505
|solvent A=Molecule:100530
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=9000
|TON H2=36000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100831
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=76000
|TON H2=17000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100831
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA, H2O
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=8000
|TON CH4=5000
|TON H2=34000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100831
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100505
|solvent A=Molecule:100530
|feedstock gas=CO2
|λexc=solar spectrum
|irr time=72
|TON CO=5000
|TON CH4=1000
|TON H2=15000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA, H2O
|λexc=solar spectrum
|irr time=72
|TON CO=51000
|TON CH4=12000
|details=Atmosphere of 1:1 CO2/H2
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA 5% (v/v), H2O 2% (v/v)
|feedstock gas=CO
|λexc=solar spectrum
|irr time=72
|TON CH4=10000
|TON H2=58000
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100829
|cat conc=2
|PS=Molecule:100843
|PS conc=0.1
|e-D=Molecule:100508
|e-D conc=0.01
|solvent A=Molecule:100530
|additives=TEA 5% (v/v), H2O 2% (v/v)
|λexc=solar spectrum
|irr time=72
|TON CH4=570000
|details=Atmosphere of 1:1 CO/H2
|include=Yes
}}
}}

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-08T00:01:29Z

ChemUser: /* Sacrificial electron donor */

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===Abstract===
[[Category:Publication]]
[[Category:Publication]]
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
<chemform smiles="C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N" inchi="1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;" inchikey="OQUHWQGBTQCWJI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===

<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Investigation ===

{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1|importFile=Import File_v2.xlsx|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}.
====Additives====

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-07T23:56:34Z

ChemUser:

Test-Page for Authors

2024-12-07T23:56:09Z

ChemUser: /* A bs tract */

{{DOI|doi=}}
[[Category:Homogeneous photocatalytic CO2 conversion]][[Category:Publication]]
{{BaseTemplate}}

===Abstract===
[[Category:Publication]]
[[Category:Publication]]
====Summary====
====Additional remarks====

===Content of the published article in detail===

===Catalysts tested in this study===
===Photosensitizer===
===Investigation===
===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donors {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}.
====Additives====

Test-Page for Authors

2024-12-07T23:55:52Z

ChemUser:

{{DOI|doi=}}
[[Category:Homogeneous photocatalytic CO2 conversion]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====

===Content of the published article in detail===

===Catalysts tested in this study===
===Photosensitizer===
===Investigation===
===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donors {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}.
====Additives====

Test-Page for Authors

2024-12-07T23:52:40Z

ChemUser: auto-generated

{{DOI|doi=}}
[[Category:Homogeneous photocatalytic CO2 conversion]][[Category:Publication]]
{{BaseTemplate}}

Molecule:100984

2024-12-07T23:39:36Z

ChemUser:

{{Molecule
|abbrev=[Ru(phen)3](PF6)2
|molecular_role=photosensitizer
|molecularFormula=C36H24F14N6P2Ru
|molecularMass=970.035762408
|moleculeKey=YYWPACUPCNICHF-UHFFFAOYSA-N
|molOrRxn=-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
|smiles=C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F
|inchi=1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2
|inchikey=YYWPACUPCNICHF-UHFFFAOYSA-N
|width=300px
|height=200px
|float=none
}}

Molecule:100983

2024-12-07T23:39:09Z

ChemUser:

{{Molecule
|abbrev=Co(phen)2(CN)2
|molecular_role=catalyst
|molecularFormula=C26H16CoN6
|molecularMass=471.076839512
|moleculeKey=OQUHWQGBTQCWJI-UHFFFAOYSA-N
|molOrRxn=-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
|smiles=C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N
|inchi=1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;
|inchikey=OQUHWQGBTQCWJI-UHFFFAOYSA-N
|width=300px
|height=200px
|float=none
}}

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity/Table 1

2024-12-07T23:30:37Z

ChemUser:

{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=0
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=1130
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=5
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=730
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=25
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=154
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|TON CO=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=0
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=nitrogen
|λexc=469
|irr time=10
|TON CO=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|PS=Molecule:100984
|PS conc=0.40
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|PS=Molecule:100984
|PS conc=0.40
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=720
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100983
|cat conc=2.5
|e-D=Molecule:100507
|e-D conc=0.4
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|solvent-ratio=9:1
|feedstock gas=CO2
|λexc=469
|irr time=10
|TON CO=0
|include=No
}}
}}

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-07T23:29:04Z

ChemUser: /* Investigation */

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
<chemform smiles="C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N" inchi="1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;" inchikey="OQUHWQGBTQCWJI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===

<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Investigation ===

{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1|importFile=Import File_v2.xlsx|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor .
====Additives====

File:Import File v2.xlsx

2024-12-07T23:27:09Z

ChemUser: uploaded by user

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-07T23:11:07Z

ChemUser: /* Investigation */

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
<chemform smiles="C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N" inchi="1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;" inchikey="OQUHWQGBTQCWJI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===

<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Investigation ===
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1|importFile=|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor .
====Additives====

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-07T23:06:08Z

ChemUser: /* Investigation */

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
<chemform smiles="C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N" inchi="1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;" inchikey="OQUHWQGBTQCWJI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===

<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Investigation ===
{{#experimentlist:|form=Cyclic_Voltammetry_experiments|name=Table1|importFile=Import File.xlsx|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor .
====Additives====

File:Import File.xlsx

2024-12-07T23:03:13Z

ChemUser: ChemUser uploaded a new version of File:Import File.xlsx

Property:Turnover number MeOH

2024-12-07T22:27:58Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of the product MeOH of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

Property:Turnover number HCOOH

2024-12-07T22:27:21Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of the product HCOOH of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

Property:Turnover number H2

2024-12-07T22:26:49Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of the product H2 of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

Property:Turnover number CO

2024-12-07T22:26:03Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of the product CO of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

Property:Turnover number CH4

2024-12-07T22:25:39Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of the product CH4 of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

Property:Turnover number

2024-12-07T22:25:17Z

ChemUser:

; Purpose
* [[Property description::Contains the turnover number of an experiment or molecular process.@en]]

; Datatype
* [[Has type::Number]].

; Values
* Input fields should be restricted to positive numbers (<nowiki>regexp=/^([0-9]*\.)?[0-9]*$/</nowiki>).

; Unit
* [[Unit::TON]]

A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity

2024-12-07T22:09:34Z

ChemUser: /* Investigation */

{{DOI|doi=10.1007/s10562-021-03782-7}}
[[Category:Topic]][[Category:Publication]]
{{BaseTemplate}}

===A [[Category:Publication]] bs [[Category:Publication]] tract===
====Summary====
====Additional remarks====
===Content of the published article in detail===

===Catalysts tested in this study===
<chemform smiles="C1C2C=CC3C=CC=N4[Co]5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)(N(C=2C=34)=CC=1)(C#N)C#N" inchi="1S/2C12H8N2.2CN.Co/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-2;/h2*1-8H;;;" inchikey="OQUHWQGBTQCWJI-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422132D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 33 40 2 0 0
M V30 BEGIN ATOM
M V30 1 C -3.13722 -0.831344 0.0 0
M V30 2 C -2.71343 -1.53918 0.0 0
M V30 3 C -1.88853 -1.52608 0.0 0
M V30 4 N -1.48743 -0.805155 0.0 0
M V30 5 C -1.91121 -0.097321 0.0 0
M V30 6 C -2.73611 -0.110416 0.0 0
M V30 7 C -1.51011 0.623607 0.0 0
M V30 8 C -1.93389 1.33144 0.0 0
M V30 9 C -2.75879 1.31835 0.0 0
M V30 10 C -3.1599 0.597418 0.0 0
M V30 11 N -0.685211 0.636701 0.0 0
M V30 12 C -0.284103 1.35763 0.0 0
M V30 13 C -0.707891 2.06546 0.0 0
M V30 14 C -1.53279 2.05237 0.0 0
M V30 15 C 1.52227 2.09226 0.0 0
M V30 16 C 0.697304 2.09937 0.0 0
M V30 17 C 0.278662 1.38848 0.0 0
M V30 18 N 0.684991 0.670483 0.0 0
M V30 19 C 1.50996 0.663375 0.0 0
M V30 20 C 1.9286 1.37426 0.0 0
M V30 21 C 1.91629 -0.054624 0.0 0
M V30 22 C 2.74126 -0.061733 0.0 0
M V30 23 C 3.1599 0.649157 0.0 0
M V30 24 C 2.75357 1.36716 0.0 0
M V30 25 N 1.49765 -0.765515 0.0 0
M V30 26 C 1.90398 -1.48351 0.0 0
M V30 27 C 2.72895 -1.49062 0.0 0
M V30 28 C 3.14759 -0.779732 0.0 0
M V30 29 Co 0.008948 -0.207104 0.0 0
M V30 30 C -0.575828 -1.33399 0.0 0
M V30 31 N -0.955826 -2.06627 0.0 0
M V30 32 C 0.462698 -1.33407 0.0 0
M V30 33 N 0.770828 -2.09937 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 3 30 31
M V30 2 1 29 30
M V30 3 3 32 33
M V30 4 1 29 32
M V30 5 2 1 2
M V30 6 1 2 3
M V30 7 2 3 4
M V30 8 1 4 5
M V30 9 2 5 6
M V30 10 1 6 1
M V30 11 1 5 7
M V30 12 2 7 8
M V30 13 1 8 9
M V30 14 2 9 10
M V30 15 1 10 6
M V30 16 1 7 11
M V30 17 2 11 12
M V30 18 1 12 13
M V30 19 2 13 14
M V30 20 1 14 8
M V30 21 2 15 16
M V30 22 1 16 17
M V30 23 2 17 18
M V30 24 1 18 19
M V30 25 2 19 20
M V30 26 1 20 15
M V30 27 1 19 21
M V30 28 2 21 22
M V30 29 1 22 23
M V30 30 2 23 24
M V30 31 1 24 20
M V30 32 1 21 25
M V30 33 2 25 26
M V30 34 1 26 27
M V30 35 2 27 28
M V30 36 1 28 22
M V30 37 10 11 29
M V30 38 10 18 29
M V30 39 10 4 29
M V30 40 10 25 29
M V30 END BOND
M V30 BEGIN SGROUP
M V30 1 SUP 1 ATOMS=(2 30 31) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 2 SUP 2 ATOMS=(2 32 33) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) LA-
M V30 BEL=CN
M V30 END SGROUP
M V30 END CTAB
M END
</chemform>

=== Photosensitizer ===

<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none">
-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
</chemform>

=== Investigation ===

{{#experimentlist:|form=Cyclic_Voltammetry_experiments|name=Table CO2 reduction|importFile=Import File.xlsx|description=}}

===Further Information===
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor .
====Additives====

File:Import File.xlsx

2024-12-07T22:06:03Z

ChemUser: uploaded by user

Molecule:100984

2024-12-07T21:20:42Z

ChemUser:

{{Molecule
|abbrev=[Ru(phen)3](PF6)2
|molecular_role=catalyst
|molecularFormula=C36H24F14N6P2Ru
|molecularMass=970.035762408
|moleculeKey=YYWPACUPCNICHF-UHFFFAOYSA-N
|molOrRxn=-INDIGO-12072422152D

0 0 0 0 0 0 0 0 0 0 0 V3000
M V30 BEGIN CTAB
M V30 COUNTS 59 68 0 0 0
M V30 BEGIN ATOM
M V30 1 C -4.49166 0.079824 0.0 0
M V30 2 C -4.06787 -0.62801 0.0 0
M V30 3 C -3.24298 -0.614915 0.0 0
M V30 4 N -2.84187 0.106013 0.0 0
M V30 5 C -3.26566 0.813846 0.0 0
M V30 6 C -4.09055 0.800752 0.0 0
M V30 7 C -2.86455 1.53478 0.0 0
M V30 8 C -3.28834 2.24261 0.0 0
M V30 9 C -4.11323 2.22951 0.0 0
M V30 10 C -4.51434 1.50859 0.0 0
M V30 11 N -2.03965 1.54787 0.0 0
M V30 12 C -1.63855 2.2688 0.0 0
M V30 13 C -2.06233 2.97663 0.0 0
M V30 14 C -2.88723 2.96354 0.0 0
M V30 15 C 0.250331 2.98281 0.0 0
M V30 16 C -0.574639 2.98991 0.0 0
M V30 17 C -0.99328 2.27903 0.0 0
M V30 18 N -0.586952 1.56103 0.0 0
M V30 19 C 0.238017 1.55392 0.0 0
M V30 20 C 0.656658 2.26481 0.0 0
M V30 21 C 0.644346 0.835919 0.0 0
M V30 22 C 1.46932 0.828809 0.0 0
M V30 23 C 1.88796 1.5397 0.0 0
M V30 24 C 1.48163 2.2577 0.0 0
M V30 25 N 0.225704 0.125028 0.0 0
M V30 26 C 0.632033 -0.59297 0.0 0
M V30 27 C 1.457 -0.600079 0.0 0
M V30 28 C 1.87564 0.110811 0.0 0
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2
M V30 30 C 0.325773 -2.28096 0.0 0
M V30 31 C 0.741449 -1.56833 0.0 0
M V30 32 C 0.332132 -0.852031 0.0 0
M V30 33 N -0.49286 -0.848359 0.0 0
M V30 34 C -0.908535 -1.56099 0.0 0
M V30 35 C -0.499218 -2.27729 0.0 0
M V30 36 C -1.73353 -1.55732 0.0 0
M V30 37 C -2.1492 -2.26994 0.0 0
M V30 38 C -1.73989 -2.98624 0.0 0
M V30 39 C -0.914894 -2.98991 0.0 0
M V30 40 N -2.14284 -0.841017 0.0 0
M V30 41 C -2.96783 -0.837345 0.0 0
M V30 42 C -3.38351 -1.54997 0.0 0
M V30 43 C -2.97419 -2.26627 0.0 0
M V30 44 P 3.56559 0.765939 0.0 0
M V30 45 F 3.35207 -0.030949 0.0 0
M V30 46 F 2.85112 1.17844 0.0 0
M V30 47 F 4.14895 1.3493 0.0 0
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1
M V30 49 F 4.39059 0.765939 0.0 0
M V30 50 F 2.7687 0.552413 0.0 0
M V30 51 F 4.14895 0.182576 0.0 0
M V30 52 P 3.68934 -1.58531 0.0 0
M V30 53 F 3.47582 -2.3822 0.0 0
M V30 54 F 2.97487 -1.17281 0.0 0
M V30 55 F 4.27271 -1.00195 0.0 0
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1
M V30 57 F 4.51434 -1.58531 0.0 0
M V30 58 F 2.89245 -1.79884 0.0 0
M V30 59 F 4.27271 -2.16867 0.0 0
M V30 END ATOM
M V30 BEGIN BOND
M V30 1 2 1 2
M V30 2 1 2 3
M V30 3 2 3 4
M V30 4 1 4 5
M V30 5 2 5 6
M V30 6 1 6 1
M V30 7 1 5 7
M V30 8 2 7 8
M V30 9 1 8 9
M V30 10 2 9 10
M V30 11 1 10 6
M V30 12 1 7 11
M V30 13 2 11 12
M V30 14 1 12 13
M V30 15 2 13 14
M V30 16 1 14 8
M V30 17 2 15 16
M V30 18 1 16 17
M V30 19 2 17 18
M V30 20 1 18 19
M V30 21 2 19 20
M V30 22 1 20 15
M V30 23 1 19 21
M V30 24 2 21 22
M V30 25 1 22 23
M V30 26 2 23 24
M V30 27 1 24 20
M V30 28 1 21 25
M V30 29 2 25 26
M V30 30 1 26 27
M V30 31 2 27 28
M V30 32 1 28 22
M V30 33 10 11 29
M V30 34 10 18 29
M V30 35 10 4 29
M V30 36 10 25 29
M V30 37 2 30 31
M V30 38 1 31 32
M V30 39 2 32 33
M V30 40 1 33 34
M V30 41 2 34 35
M V30 42 1 35 30
M V30 43 1 34 36
M V30 44 2 36 37
M V30 45 1 37 38
M V30 46 2 38 39
M V30 47 1 39 35
M V30 48 1 36 40
M V30 49 2 40 41
M V30 50 1 41 42
M V30 51 2 42 43
M V30 52 1 43 37
M V30 53 10 40 29
M V30 54 10 33 29
M V30 55 1 44 45
M V30 56 1 44 46
M V30 57 1 44 47
M V30 58 1 44 48
M V30 59 1 44 49
M V30 60 1 44 50
M V30 61 1 44 51
M V30 62 1 52 53
M V30 63 1 52 54
M V30 64 1 52 55
M V30 65 1 52 56
M V30 66 1 52 57
M V30 67 1 52 58
M V30 68 1 52 59
M V30 END BOND
M V30 END CTAB
M END
|smiles=C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F
|inchi=1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2
|inchikey=YYWPACUPCNICHF-UHFFFAOYSA-N
|width=300px
|height=200px
|float=none
}}